Application Prospect of Carbon Dioxide Hydrogenation to Methanol Technology in the New Electric Power Systems

Xin Nie
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Abstract

The new electric power systems based on new energy is a power system that is supported by source-grid-load-storage interaction and multi-energy complementarity, in order to reduce the carbon emission level of the new electric power systems, it is necessary to change the existing energy structure of the system through different energy carriers. Through technology comparison and analysis, seawater in-situ electrolysis hydrogen production technology can make full use of offshore renewable energy, which can effectively reduce the production cost of hydrogen production by electrolysis. With the development and industrial application of the third-generation low-energy phase change absorber, the technology of carbon dioxide capture by phase change solvent has great application prospects. The industrial application of carbon dioxide hydrogenation to methanol can rely on the existing mature C1 chemical system, and the new carbon dioxide hydrogenation to methanol device can improve the effective utilization rate of carbon dioxide and reduce the emission of tail gas. On this basis, the application scheme of carbon dioxide hydrogenation to methanol technology in the new power system is proposed: centered on the power grid, renewable energy is used to generate electricity, and part of the electricity is sent to the grid; part of the electricity is sent to the seawater in-situ electrolysis hydrogen production unit to produce hydrogen; the main product hydrogen is stored in the hydrogen storage equipment, and the by-product oxygen is used comprehensively; the carbon dioxide generated in the process of fossil fuel power generation is captured by phase change solvent, and then the new carbon dioxide hydrogenation to methanol device is used to synthesize carbon dioxide and hydrogen into methanol under the action of catalyst, part of the methanol is converted into hydrogen by cracking and stored, and the other part of methanol is directly used as the fuel of internal combustion power locomotives, when the power output of the grid is insufficient, methanol can be used as fuel for internal combustion generators, which are used to generate electricity and sent to the grid, and the stored hydrogen can also be used as fuel for hydrogen fuel cells, which are used to generate electricity and sent to the grid.
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二氧化碳加氢制甲醇技术在新型电力系统中的应用前景
基于新能源的新型电力系统是以源-网-荷-储互动、多能互补为支撑的电力系统,为了降低新型电力系统的碳排放水平,需要通过不同的能源载体改变系统现有的能源结构。通过技术对比分析,海水原位电解制氢技术可充分利用海上可再生能源,有效降低电解制氢的生产成本。随着第三代低能耗相变吸收剂的开发和工业应用,相变溶剂捕集二氧化碳技术具有广阔的应用前景。二氧化碳加氢制甲醇的工业应用可依托现有成熟的 C1 化学体系,新型二氧化碳加氢制甲醇装置可提高二氧化碳的有效利用率,减少尾气排放。在此基础上,提出了二氧化碳加氢制甲醇技术在新电力系统中的应用方案:以电网为中心,利用可再生能源发电,部分电量送入电网;部分电量送入海水原位电解制氢装置制氢;主产品氢气储存在储氢设备中,副产品氧气综合利用;化石燃料发电过程中产生的二氧化碳经相变溶剂捕集后,利用新型二氧化碳加氢制甲醇装置,在催化剂作用下将二氧化碳和氢气合成甲醇,部分甲醇经裂解转化为氢气储存起来、当电网电力输出不足时,甲醇可用作内燃发电机的燃料,用来发电并送入电网,储存的氢气也可用作氢燃料电池的燃料,用来发电并送入电网。
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Application Prospect of Carbon Dioxide Hydrogenation to Methanol Technology in the New Electric Power Systems
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