Separation of Lactic Acid and Acetic Acid through Supported Ionic Liquid Membranes Containing Cyphos IL 101

Michiaki MATSUMOTO, Hiroto FUKADA, Yoshiro TAHARA
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Abstract

Lactic acid is the raw material for polylactic acid, a biodegradable plastic, which is produced by fermentation. Development of a cost-effective separation technique is still required to extract and purify lactic acid from the broth. We conducted permeation of lactic acid and acetic acid through supported ionic liquid membrane containing Cyphos IL 101 as a carrier. Lactic acid successfully permeated through the membranes against its concentration gradient. By using a feed phase of pH 5 and a receiving phase of 0.01 mol/dm3 NaCl solution prepared at pH 3 with HCl, a higher permeation rate of lactic acid and a higher separation of lactic acid and acetic acid could be achieved than when the receiving phase was a HCl solution.

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通过含有 Cyphos IL 101 的支撑离子液体膜分离乳酸和醋酸
乳酸是聚乳酸的原料,聚乳酸是一种生物可降解塑料,由发酵产生。要从发酵液中提取和纯化乳酸,仍需开发一种经济有效的分离技术。我们通过以 Cyphos IL 101 为载体的支撑离子液体膜进行了乳酸和醋酸的渗透。乳酸成功地逆浓度梯度渗透过膜。与接收相为盐酸溶液时相比,通过使用 pH 值为 5 的进料相和 pH 值为 3 的 0.01 mol/dm3 NaCl 溶液接收相,乳酸的渗透率更高,乳酸和醋酸的分离率也更高。
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