Effect of carbon quantum dots doping on structural, optical, and antibacterial properties of barium tungstate nanocomposite material

Abstract

Local bacterial infection remains an increasingly severe threat to human health worldwide, and infection control is still a challenging task. Carbon Quantum Dots (CQSs) and barium tungstate show antibacterial properties. CQDs doped Barium Tungstate (BaWO₄) are synthesized by using a hydrothermal route and their optical and antimicrobial activities against the Gram-positive bacteria staphylococcus aureus and optical properties were investigated. The UV–Vis reveals a shift in the bandgap from 3.62 eV to 2.93 eV due to doping of CQDs in BaWO₄. The structure of the CQDs/BaWO₄ were studied by XRD, which shows CQDs doped BaWO₄ samples possess tetragona4 werelite structure with the preferred orientation of (1 1 2) identified by XRD at 26° having crystallite size ∼ 31 nm. Nanocomposite BaWO₄/CQDs exhibit a spherical-like shape and are composed of Ba, O, W and C according to the design of the experiment. Zeta sizer of CQDs by DLS shows the size of CQDs is 7.65 nm. The FT-IR shows the presence of functional groups in doped material like CC, CO, and COOH bonds which indicate that the C-dots are functionalized with epoxy, carbonyl, hydroxyl, and carboxylic acid groups. Their elemental composition and surface morphology were studied by EDS which shows the percentage variation of CQDs in BaWO₄, SEM results show the change in shape of the sample by adding CQDs to BaWO₄. The TEM image proves the presence of doped material in the BaWO₄. The PL spectra reveals the emission spectra shift towards a higher wavelength and absorption increases. The qualitative analysis shows the antimicrobial activity and enlargement of the inhibition zone and quantitative analysis confirms it.