High efficient step graded Inx Ga1−x N/GaN superlattice solar cell

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-04-01 DOI:10.1117/1.jnp.18.026002
Dickson Warepam, Khomdram Jolson Singh, Rudra Sankar Dhar
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Abstract

The band-gap of InxGa1−xN can cover a wide range of electromagnetic radiation of the solar spectrum and offers a method for using it in photovoltaic solar cells. A solar cell structure consisting of InxGa1−xN/GaN superlattice (SL) piled up between p-GaN and n-GaN is modeled and simulated. The impact of variations in the indium mole fraction and step graded SL having different quantum well thicknesses are analyzed. The results indicate that high indium content leads to lattice mismatch, decrement of fill factor, and development of strain in the quantum wells that reduce the overall efficiency. To increase the efficiency of the solar cell, a step graded 20 SL with a 5 nm quantum well thickness is introduced, and the highest efficiency of 22.6% is obtained. The use of a step graded SL InGaN cell allows for constructing real structures with the possibility of obtaining the enhanced power conversion efficiency compared with a conventional quantum well solar cell using SILVACO TCAD.
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高效阶跃梯度 Inx Ga1-x N/GaN 超晶格太阳能电池
InxGa1-xN 的带隙可覆盖太阳光谱的广泛电磁辐射范围,这为将其用于光伏太阳能电池提供了一种方法。本文对一种由堆积在 p-GaN 和 n-GaN 之间的 InxGa1-xN/GaN 超晶格(SL)组成的太阳能电池结构进行了建模和模拟。分析了铟摩尔分数变化和具有不同量子阱厚度的阶梯分级 SL 的影响。结果表明,铟含量高会导致晶格失配、填充因子降低以及量子阱应变的产生,从而降低整体效率。为了提高太阳能电池的效率,引入了量子阱厚度为 5 nm 的阶梯分级 20 SL,获得了 22.6% 的最高效率。与传统的量子阱太阳能电池相比,使用 SILVACO TCAD 构建真实结构的阶跃分级 SL InGaN 电池有可能获得更高的功率转换效率。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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