Explosive Boiling-up of Superheated Gas-Saturated Alkanes

IF 1 4区 物理与天体物理 Q4 PHYSICS, APPLIED High Temperature Pub Date : 2024-03-20 DOI:10.1134/s0018151x23040028
V. G. Baidakov, A. M. Kaverin, A. S. Pankov
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Abstract

The spontaneous boiling-up kinetics of liquid alkanes (methane, ethane, and propane) saturated with one of the following gases: helium, hydrogen, nitrogen, or methane is studied. The solution nucleation rate temperature, baric, and concentration dependences in the interval (104–108) m–3 s–1 are determined using the mean lifetime method. The measurements were carried out at pressures of 1–2 MPa and volatile component concentrations up to 6 mol %. The experimental results are compared with the classical nucleation theory in a macroscopic approximation. In contrast to pure liquid and liquid saturated with helium or hydrogen, the attainable superheating temperatures of solutions containing nitrogen or methane as a dissolved substance exceed their theoretically predicted values. The factors causing this mismatch are discussed.

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过热气体饱和烷烃的爆炸性沸腾
摘要 研究了液态烷烃(甲烷、乙烷和丙烷)饱和下列气体之一的自发沸腾动力学:氦气、氢气、氮气或甲烷。采用平均寿命法测定了溶液成核率在 (104-108) m-3 s-1 范围内的温度、巴里和浓度相关性。测量是在压力为 1-2 兆帕和挥发性成分浓度高达 6 摩尔%的条件下进行的。实验结果与宏观近似的经典成核理论进行了比较。与纯液体和氦或氢饱和液体相比,含有氮或甲烷溶解物的溶液可达到的过热温度超出了理论预测值。本文讨论了造成这种不匹配的因素。
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来源期刊
High Temperature
High Temperature 物理-物理:应用
CiteScore
1.50
自引率
40.00%
发文量
0
审稿时长
4-8 weeks
期刊介绍: High Temperature is an international peer reviewed journal that publishes original papers and reviews written by theoretical and experimental researchers. The journal deals with properties and processes in low-temperature plasma; thermophysical properties of substances including pure materials, mixtures and alloys; the properties in the vicinity of the critical point, equations of state; phase equilibrium; heat and mass transfer phenomena, in particular, by forced and free convections; processes of boiling and condensation, radiation, and complex heat transfer; experimental methods and apparatuses; high-temperature facilities for power engineering applications, etc. The journal reflects the current trends in thermophysical research. It presents the results of present-day experimental and theoretical studies in the processes of complex heat transfer, thermal, gas dynamic processes, and processes of heat and mass transfer, as well as the latest advances in the theoretical description of the properties of high-temperature media.
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