Changes in the Optical Properties of Coatings Based on Hollow ZnO/SiO2 Particles under Electron Irradiation

A. N. Dudin, V. Yu. Yurina, V. V. Neshchimenko, M. M. Mikhailov, S. A. Yuriev, A. N. Lapin
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Abstract

A comparative analysis of the diffuse reflectance spectra and their changes after irradiation with electrons with an energy of 30 keV of coatings based on polymethylphenylsiloxane resin and pigment powders of two-layer hollow ZnO/SiO2 particles is carried out. The analysis is performed in situ in the range of 250–2500 nm. The samples are irradiated using a Spectrum space-conditions simulator. The radiation resistance of the studied coatings based on two-layer hollow ZnO/SiO2 particles is estimated relative to coatings based on ZnO polycrystals by analyzing the difference diffuse reflectance spectra obtained by subtracting the spectra after irradiation from the spectra of the unirradiated samples. It is found that the intensity of the induced absorption bands in coatings based on hollow ZnO/SiO2 particles is less than in coatings based on ZnO microparticles, and the radiation resistance when estimating changes in the integral absorption coefficient of solar radiation (ΔαS) is twice as high. The increase in the radiation resistance is probably determined by the different nature of defect accumulation: in the case of solid microparticles, defects can accumulate inside grains; in hollow particles, the accumulation of defects can occur only within the thin shell of the sphere.

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基于空心氧化锌/二氧化硅粒子的涂层在电子辐照下的光学特性变化
摘要 对基于聚甲基苯基硅氧烷树脂和两层空心 ZnO/SiO2 颗粒颜料粉末的涂层进行 30 keV 能量电子辐照后的漫反射光谱及其变化进行了比较分析。分析在 250-2500 纳米范围内原位进行。使用光谱空间条件模拟器对样品进行辐照。通过分析从未遭辐照样品的光谱中减去辐照后的光谱所得到的差分漫反射光谱,估算出所研究的基于两层空心 ZnO/SiO2 颗粒的涂层相对于基于 ZnO 多晶体的涂层的抗辐射性。结果发现,在基于空心 ZnO/SiO2 颗粒的涂层中,诱导吸收带的强度低于基于 ZnO 微颗粒的涂层,而且在估算太阳辐射积分吸收系数(ΔαS)的变化时,辐射阻抗是后者的两倍。辐射阻力的增加可能是由缺陷积累的不同性质决定的:在实心微粒中,缺陷可以在晶粒内部积累;而在空心微粒中,缺陷的积累只能发生在球体的薄壳内。
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来源期刊
CiteScore
0.90
自引率
25.00%
发文量
144
审稿时长
3-8 weeks
期刊介绍: Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques publishes original articles on the topical problems of solid-state physics, materials science, experimental techniques, condensed media, nanostructures, surfaces of thin films, and phase boundaries: geometric and energetical structures of surfaces, the methods of computer simulations; physical and chemical properties and their changes upon radiation and other treatments; the methods of studies of films and surface layers of crystals (XRD, XPS, synchrotron radiation, neutron and electron diffraction, electron microscopic, scanning tunneling microscopic, atomic force microscopic studies, and other methods that provide data on the surfaces and thin films). Articles related to the methods and technics of structure studies are the focus of the journal. The journal accepts manuscripts of regular articles and reviews in English or Russian language from authors of all countries. All manuscripts are peer-reviewed.
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