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On the Generation of Phonons and Electronic Excitations by a Channeled Particle in Crystals 论晶体中通道粒子产生的声子和电子激发
IF 0.4 Q4 Materials Science Pub Date : 2024-05-07 DOI: 10.1134/s1027451024020083
E. A. Mazur

Abstract

The processes of generating phonons and electronic excitations by an oriented quantum particle in a crystal are considered. The probabilities of the excitation of phonons and plasmons are calculated. A theory of crystal excitation by a channeled particle with simultaneous photon emission is developed. The probability of a process with the fast particle transitioning into a virtual state after emitting a plasmon, followed by photon emission, is determined. The probability of the process involving photon and plasmon emission is of the same order of magnitude as the probability of the standard process with photon emission alone. The possibility of experimentally detecting the effect is assessed. It is demonstrated that all features of electronic and phonon excitations manifest as components of the radiation spectrum from a fast oriented charged particle in a crystal.

摘要 研究了晶体中定向量子粒子产生声子和电子激发的过程。计算了声子和质子激发的概率。建立了晶体受定向粒子激发并同时发射光子的理论。确定了快速粒子在发射等离子体后过渡到虚态,然后再发射光子的过程概率。涉及光子和等离子体发射的过程的概率与仅有光子发射的标准过程的概率处于同一数量级。对实验检测该效应的可能性进行了评估。实验证明,电子和声子激发的所有特征都表现为晶体中快速定向带电粒子辐射光谱的组成部分。
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引用次数: 0
Electromagnetic Radiation of Accelerated Electron Beams During Sliding Interaction with a Dielectric Surface 加速电子束与介质表面滑动相互作用时的电磁辐射
IF 0.4 Q4 Materials Science Pub Date : 2024-05-07 DOI: 10.1134/s102745102402040x
L. A. Zhilyakov, V. S. Kulikauskas

Abstract

The work is aimed at studying the properties of the “guiding” effect, namely the possibility of generating electromagnetic radiation when guiding beams of accelerated electrons. In this paper, we discuss a model of motion for the case of electron guiding during the interaction of electron beams with a dielectric surface. It is noted that when an electron beam is pressed against the surface of a dielectric by an external transverse electric field, in this case, due to the guiding effect, the electrons experience transverse vibrations when moving along the surface. Consequently, the movement of electrons in the transverse direction is accelerated and, accordingly, electron beams in the case of guiding should be a source of electromagnetic radiation, similar to the radiation of undulators and wigglers. The numerical estimates carried out in the work using the Larmor formula show that the power of this radiation should have a value sufficient for its experimental detection. This radiation should be of a pulsed nature against the background of continuous radiation. The power of the pulsed radiation must be several orders of magnitude greater than the power of the continuous background radiation.

摘要 这项工作旨在研究 "导引 "效应的特性,即在导引加速电子束时产生电磁辐射的可能性。本文讨论了电子束与电介质表面相互作用时电子导向的运动模型。我们注意到,当电子束被外部横向电场压向电介质表面时,在这种情况下,由于导向效应,电子在沿表面运动时会产生横向振动。因此,电子在横向方向上的运动被加速,相应地,电子束在导向情况下应成为电磁辐射源,类似于起伏器和摇摆器的辐射。工作中使用拉莫尔公式进行的数值估算表明,这种辐射的功率值应足以进行实验检测。在连续辐射的背景下,这种辐射应该是脉冲性质的。脉冲辐射的功率必须比连续背景辐射的功率大几个数量级。
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引用次数: 0
Electron Distribution Near the Fast-Ion Track in Silicon 硅中快离子轨道附近的电子分布
IF 0.4 Q4 Materials Science Pub Date : 2024-05-07 DOI: 10.1134/s1027451024020150
N. V. Novikov, N. G. Chechenin, A. A. Shirokova

Abstract

In this paper, we propose a model to describe the distribution of electrons near the track of a fast ion. The dependence of the fast-electron flux on time, layer depth, and radial variable is modeled taking into account the statistical weight of each trajectory. The pulse duration in the electron-flux distribution was found to be fractions of ps while the radial size of the cylindrical region, where the transport of fast electrons occurs, reaches tens of angstroms.

摘要 在本文中,我们提出了一个描述快离子轨道附近电子分布的模型。考虑到每条轨迹的统计权重,建立了快速电子通量对时间、层深度和径向变量的依赖关系模型。研究发现,电子通量分布中的脉冲持续时间为几分之一秒,而发生快速电子传输的圆柱形区域的径向尺寸达到几十埃。
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引用次数: 0
Simulation of Silicon Irradiation with C60 Ions: Unveiling the Role of the Interaction Potential 模拟 C60 离子对硅的辐照:揭示相互作用势的作用
IF 0.4 Q4 Materials Science Pub Date : 2024-05-07 DOI: 10.1134/s1027451024020319
K. P. Karasev, D. A. Strizhkin, A. I. Titov, P. A. Karaseov

Abstract

Molecular dynamic simulation was used to study the processes of molecular 2 to 14 keV C60 ion impact on the (100) Si surface at 0 to 1000 K. Tersoff-ZBL and Airebo interaction potentials were used, and electronic energy loss were taken into account as quasifriction force for fast particles. It is shown that, when single impact events are simulated, the target temperature does not affect the development of the displacement cascade but affects its thermalization and the formation of the crater on the surface. As the energy increases, the carbon penetration depth, the size of the formed crater, and the size of the rim increase. The sputtering coefficient of silicon atoms in this case increases linearly with energy, while for carbon atoms it reaches a steady-state value at 10 keV. A higher number of atomized carbon atoms in single impact events is found using the Tersoff potential compared to the Airebo potential. In the event of cumulative events, the formation of an etch pit is observed at the initial stage followed by carbon film growth. In the case of cumulative ion accumulation, the use of the Airebo potential yields a higher sputtering coefficient than the use of the Tersoff potential. The formation of carbide bonds in the crystal and the increase in their concentration with ion fluence slightly reduce the number of sputtered particles. Therefore, for the correct comparison of simulation results with experiment it is not enough to use the results of single impact event analysis. It is necessary to perform cumulative fluence accumulation simulation.

摘要 采用 Tersoff-ZBL 和 Airebo 作用势,并将电子能量损耗作为快速粒子的准摩擦力加以考虑,利用分子动力学模拟研究了 0 至 1000 K 时 2 至 14 keV C60 离子对 (100) Si 表面的分子撞击过程。结果表明,在模拟单次撞击事件时,目标温度不会影响位移级联的发展,但会影响其热化和表面凹坑的形成。随着能量的增加,碳穿透深度、形成的凹坑大小和边缘大小都会增加。在这种情况下,硅原子的溅射系数随能量线性增加,而碳原子的溅射系数在 10 keV 时达到稳定值。与艾雷波电势相比,使用特尔索夫电势时,单次撞击事件中雾化的碳原子数量更多。在累积事件中,初始阶段会观察到蚀刻坑的形成,随后碳膜开始生长。在离子累积的情况下,使用 Airebo 电位比使用 Tersoff 电位产生更高的溅射系数。晶体中碳化物键的形成及其浓度随离子通量的增加而增加,略微减少了溅射粒子的数量。因此,要正确比较模拟结果和实验结果,仅使用单次冲击事件分析结果是不够的。有必要进行累积通量累积模拟。
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引用次数: 0
Comparison of Optical Properties and Radiation Stability of Gd2O3 Micro- and Nanopowders Gd2O3 微粉和纳米粉体的光学特性和辐射稳定性比较
IF 0.4 Q4 Materials Science Pub Date : 2024-05-07 DOI: 10.1134/s1027451024020101
M. M. Mikhailov, V. A. Goronchko, D. S. Fedosov, A. N. Lapin, S. A. Yuryev

Abstract

The results of comparative studies of the phase composition, diffuse reflectance spectra, radiation-induced absorption spectra, and the integral absorption coefficient of solar radiation upon irradiation of micro- and nanopowders of gadolinium oxide are presented. To assess the radiation stability of optical properties, the samples were placed in a chamber of an installation simulating space conditions, where diffuse reflection spectra were recorded in the range of 0.2–2.5 μm in a vacuum of 2 × 10–6 Torr before and after each period of electron irradiation (E = 30 keV, Φ = (1–3) × 1016 cm–2). Micropowders of rare earth elements are used to increase the radiation stability of materials by absorbing free electrons formed in them during irradiation during their transitions from the d- to f-shell. Nanopowders of rare earth elements added to micropowders of various compounds provide an additional mechanism for increasing radiation stability due to the annihilation of primary defects formed during irradiation on nanoparticles. The result obtained in this work is opposite to these mechanisms—the radiation stability of a micropowder is significantly (more than 4 times) higher compared to a nanopowder due to more intense absorption in the ultraviolet region for the nanopowder caused by their own defects. The paper gives an explanation of the results obtained.

摘要 介绍了对氧化钆微粉和纳米粉体的相组成、漫反射光谱、辐射诱导吸收光谱以及太阳辐射辐照时的积分吸收系数进行比较研究的结果。为了评估光学特性的辐射稳定性,将样品放置在模拟空间条件的装置中,在 2 × 10-6 托的真空中记录了每一次电子辐照(E = 30 keV, Φ = (1-3) × 1016 cm-2)前后 0.2-2.5 μm 范围内的漫反射光谱。稀土元素微粉用于吸收从 d 壳到 f 壳转变过程中形成的自由电子,从而提高材料的辐射稳定性。添加到各种化合物微粉中的稀土元素纳米粉体,由于湮灭了纳米粒子在辐照过程中形成的原生缺陷,为提高辐射稳定性提供了另一种机制。这项研究获得的结果与这些机制相反--与纳米粉体相比,微粉的辐射稳定性显著提高(4 倍以上),这是因为纳米粉体自身的缺陷在紫外线区域产生了更强烈的吸收。本文对所获得的结果进行了解释。
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引用次数: 0
Computer Simulation of the Total Energy and the Screening Function of a Nitrogen Molecule in First-Order Perturbation Theory 一阶扰动理论中氮分子总能量和屏蔽功能的计算机模拟
IF 0.4 Q4 Materials Science Pub Date : 2024-05-07 DOI: 10.1134/s1027451024020332
V. P. Koshcheev, Yu. N. Shtanov

Abstract

Within the framework of a new approach to the problem of calculating the total energy of a diatomic molecule in first-order perturbation theory, it is shown that the potential-energy screening function is a solution to a diffusion-type equation in which the role of a time variable is played by the mean square of the amplitude of collective oscillations of electrons per degree of freedom. The total energy of a diatomic nitrogen molecule in the ground and excited states is calculated in first-order perturbation theory using tabulated eigenfunctions and eigenvalues of the energy of isolated atoms, which approximate solutions of the Hartree–Fock equation. The reliability of the numerical method for calculating the total energy of a diatomic nitrogen molecule in first-order perturbation theory is verified using an exact solution with an atomic form factor for the screened Coulomb potential. The new approach to the problem of calculating the total energy of a diatomic molecule in first-order perturbation theory does not contain free parameters, but is based on the numerical solution of a system of nonlinear equations.

摘要在一阶扰动理论计算二原子分子总能量问题的新方法框架内,证明了势能筛选函数是扩散型方程的解,其中时间变量的作用是每个自由度电子集体振荡振幅的均方。二原子氮分子在基态和激发态的总能量是通过一阶扰动理论,利用孤立原子能量的表征函数和特征值计算得出的,这近似于哈特里-福克方程的解。使用带原子形式因子的屏蔽库仑势精确解,验证了在一阶扰动理论中计算二原子氮分子总能量的数值方法的可靠性。在一阶扰动理论中计算二原子分子总能量的新方法不包含自由参数,而是基于非线性方程组的数值解。
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引用次数: 0
Structure and Properties of High-Speed Steel Surfaised Layer Irradiated by Pulsed Electron Beam 经脉冲电子束辐照的高速钢保护层的结构和特性
IF 0.4 Q4 Materials Science Pub Date : 2024-05-07 DOI: 10.1134/s102745102402006x
Yu. F. Ivanov, V. E. Gromov, T. P. Guseva, A. S. Chapaikin, E. S. Vashchuk, D. A. Romanov

Abstract

The methods of light, scanning, and transmission electron microscopy are used to study the structure, phase composition, and properties of multilayer plasma surfacings made of high-speed steel R18YU in a protective-alloying nitrogen medium, followed by a fourfold high-temperature tempering and additional electron beam processing. After tempering, the deposited layer on the 30KHGSA high-speed steel R18YU has a polycrystalline structure with a cell size of 7–22.5 µm with layers of the second phase along the boundaries and at the joints of the grains. It is shown that the irradiation of surfaised layers with a pulsed electron beam (energy density 30 J/cm2, pulse duration 50 µs, number of pulses 5, and pulse repetition rate 0.3 s–1) leads to the formation of a thin (30–50 µm) surface layer with a cellular crystallization structure. The volume of grains is formed by a solid solution based on α-Fe. Nanoscale (10–45 nm) particles of iron, chromium, and tungsten carbides of complex composition, such as M6C and M23C6, are located in the volume and along the boundaries of the crystallization cells. Fragmentation of the surface layer by a grid of microcracks is revealed, indicating relaxation of thermal stresses formed during high-speed cooling after electron beam processing. The particles have a faceted or globular shape. After irradiation with an electron beam, the wear resistance of the material increases by more than 3 times, while maintaining the microhardness of the modified layer (~5.3 GPa).

摘要 采用光电子显微镜、扫描电子显微镜和透射电子显微镜方法,研究了高速钢 R18YU 在保护合金化氮介质中经过四次高温回火和附加电子束加工制成的多层等离子表面涂层的结构、相组成和性能。回火后,30KHGSA 高速钢 R18YU 上的沉积层具有多晶结构,晶胞尺寸为 7-22.5 µm,晶粒边界和接缝处有第二相层。实验表明,用脉冲电子束(能量密度 30 J/cm2,脉冲持续时间 50 µs,脉冲数 5,脉冲重复率 0.3 s-1)辐照表面化层,可形成具有蜂窝状结晶结构的薄表层(30-50 µm)。晶粒体积由基于 α-Fe 的固溶体形成。在结晶单元的体积内和边界上分布着成分复杂的铁、铬和碳化钨的纳米级(10-45 nm)颗粒,如 M6C 和 M23C6。表面层出现网格状的微裂纹,表明电子束加工后高速冷却过程中形成的热应力发生了松弛。颗粒的形状为面状或球状。经过电子束辐照后,材料的耐磨性提高了 3 倍以上,同时还保持了改性层的显微硬度(约 5.3 GPa)。
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引用次数: 0
Temperature Dependence of the Kinetics of Domain-Structure Transformation in Heterophase Co/Pt/Co Films 异相 Co/Pt/Co 薄膜中域-结构转变动力学的温度依赖性
IF 0.4 Q4 Materials Science Pub Date : 2024-05-07 DOI: 10.1134/s1027451024020277
V. S. Gornakov, I. V. Shashkov, Yu. P. Kabanov

Abstract

Using Kerr microscopy, the effect of temperature on the displacement of domain boundaries in ultrathin exchange-coupled ferromagnetic layers in heterophase Pt/Co/Pt/Co/Pt films with perpendicular magnetic anisotropy and a nonmagnetic wedge-shaped spacer layer is experimentally studied. The exchange interaction between the Co layers is investigated for spacer-layer thicknesses ranging from 5 to 6 nm within the temperature range of 200 to 300 K. The independent displacement of domain boundaries in the Co layers under the action of a perpendicular magnetic field applied to the sample surface occurs within the range of thicknesses d0 < d < dCR. Throughout the entire temperature range, the displacement of domain boundaries along the Pt wedge results in their stabilization in an equilibrium position. This position depends on the magnitude of the applied field, the thickness of the nonmagnetic spacer layer, and temperature. It is determined by the balance of forces acting on the boundary, including the external field, the effective exchange field between the Co layers, and the coercivity field. Upon the removal of the external field, the domain boundaries relax to the initial state with d = d0 due to the effect of the exchange field. The characteristics of this relaxation depend on the temperature. The study of the mechanism of domain-boundary stabilization near dCR reveal that the critical thickness of the nonmagnetic spacer layer dCR and the coercivity field exhibit oppositely directed dependences on temperature.

摘要 利用克尔显微镜,实验研究了温度对具有垂直磁各向异性和非磁性楔形间隔层的异相铂/钴/铂/钴/铂薄膜中超薄交换耦合铁磁层域界位移的影响。在厚度为 d0 < d < dCR 的范围内,在施加于样品表面的垂直磁场作用下,Co 层的畴界发生独立位移。在整个温度范围内,畴界沿铂楔的位移导致它们稳定在一个平衡位置。这个位置取决于外加磁场的大小、非磁性间隔层的厚度和温度。它是由作用在边界上的力的平衡决定的,包括外场、Co 层之间的有效交换场和矫顽力场。移除外场后,由于交换场的作用,畴界会松弛到 d = d0 的初始状态。这种弛豫的特征取决于温度。对 dCR 附近畴界稳定机制的研究表明,非磁性间隔层的临界厚度 dCR 和矫顽力场对温度的依赖性是相反的。
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引用次数: 0
Effect of Deformation Nanostructuring on the Ion-Beam Erosion of Copper 变形纳米结构对离子束侵蚀铜的影响
IF 0.4 Q4 Materials Science Pub Date : 2024-05-07 DOI: 10.1134/s1027451024020046
N. N. Andrianova, A. M. Borisov, M. A. Ovchinnikov, R. Kh. Khisamov, R. R. Mulyukov

Abstract

The effect of deformation nanostructuring on the ion-beam erosion of copper at a high fluence of irradiation with 30 keV argon ions is experimentally studied. To form an ultrafine-grained structure with a grain size of ~0.4 μm in copper samples with an initial grain size of about 2 μm, deformation nanostructuring by high-pressure torsion is used. It is found that when a layer with a thickness comparable to the grain size is sputtered, a steady-state cone-shaped relief is formed on the copper surface, the appearance of which does not change with increasing irradiation fluence. It is shown that the smaller the grain size in copper, the greater the concentration and the smaller the height of the cones on the surface. The cone inclination angles, close to 82°, as well as the sputtering yield of 9.6 at/ion, are practically independent of the grain size of copper, the thickness of the sputtered layer, and the irradiation fluence. Calculations using the SRIM program show that, when taking into account the redeposition of atoms from the walls of the cones, the sputtering yield of a cone-shaped copper relief Yc is 3.5 times less than the sputtering yield of a single cone, 1.2 times greater than the sputtering yield of a smooth surface, and the value of 9.25 at/ion is close to the experimentally measured one.

摘要 实验研究了在 30 keV 氩离子高通量辐照下,形变纳米结构对铜离子束侵蚀的影响。为了在初始晶粒大小约为 2 μm 的铜样品中形成晶粒大小约为 0.4 μm 的超细晶粒结构,采用了高压扭转变形纳米结构。研究发现,当溅射厚度与晶粒大小相当的层时,铜表面会形成稳态锥形浮雕,其外观不会随着辐照通量的增加而改变。研究表明,铜的晶粒尺寸越小,表面锥形的浓度越大,高度越小。锥体倾角接近 82°,溅射产量为 9.6 阿特/离子,实际上与铜的晶粒尺寸、溅射层厚度和辐照通量无关。使用 SRIM 程序进行的计算表明,如果考虑到锥体壁上原子的再沉积,锥形铜浮雕 Yc 的溅射产率比单个锥体的溅射产率低 3.5 倍,比光滑表面的溅射产率高 1.2 倍,而 9.25 阿特/离子的值接近实验测量值。
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引用次数: 0
Fractal Properties of the Nd100 – xFex Alloys Surface in the Fractal Thermodynamics Model 分形热力学模型中 Nd100 - xFex 合金表面的分形特性
IF 0.4 Q4 Materials Science Pub Date : 2024-05-07 DOI: 10.1134/s1027451024020113
S. A. Mikheev, E. M. Semenova, Yu. G. Pastushenkov, V. P. Tsvetkov, I. V. Tsvetkov

Abstract

The study of the fractal properties of the surface of Nd100 – xFex alloys in a wide range of concentrations х (х = 20–90) was carried out in the framework of the fractal thermodynamics model. To this end, we performed an analysis of scanning electron microscopy images of the surfaces of a series of Nd100 – xFex alloys synthesized by induction melting. A high degree of proximity of the surface structure of all the studied samples, both before and after etching, to fractals is shown. The values of the parameter δ characterizing the relative deviation of the studied samples from the fractal are in the range of 0.017–0.029. Three-dimensional diagrams of the fractal parameters Sf, Tf, Ef, and x and two-dimensional diagrams of the same parameters Sf, Tf, Ef, and x reflecting the nature of the state of the surfaces of Nd100 – xFex alloy samples before and after etching are constructed. For all investigated alloy samples, the values of the parameters of the fractal equations of state are calculated. The correlation of the maximum value of the coercive force Hc = 4.8 kE with the values of fractal entropy Sf = 39.86, fractal temperature Tf = 529, and fractal dimension D = 2.6530 of the Nd100 – xFex alloys at x = 20 has been established.

摘要 在分形热力学模型的框架内,研究了 Nd100 - xFex 合金表面在广泛的浓度 х(х = 20-90)范围内的分形特性。为此,我们对感应熔炼合成的一系列 Nd100 - xFex 合金的表面进行了扫描电子显微镜图像分析。结果表明,所有研究样品在蚀刻前后的表面结构都高度接近分形。表征所研究样品与分形相对偏差的参数 δ 值范围在 0.017-0.029 之间。绘制了分形参数 Sf、Tf、Ef 和 x 的三维图,以及相同参数 Sf、Tf、Ef 和 x 的二维图,反映了蚀刻前后 Nd100 - xFex 合金样品表面状态的性质。计算了所有研究合金样品的分形状态方程参数值。在 x = 20 时,Nd100 - xFex 合金的矫顽力最大值 Hc = 4.8 kE 与分形熵 Sf = 39.86、分形温度 Tf = 529 和分形维度 D = 2.6530 的值之间建立了相关性。
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引用次数: 0
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Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques
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