Layered Niobium-Cermet Composite Material

O. K. Kamynina, S. G. Vadchenko, I. D. Kovalev, D. V. Prokhorov, D. E. Andreev, A. N. Nekrasov
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Abstract

Layered composite materials based on niobium and cermet are produced via the self-propagating high-temperature synthesis of preliminarily structured samples using metal foils (Ti, Nb, Ta, Ni) and reaction tapes (Ti + 1.7B) and (5Ti + 3Si). The reaction tapes for synthesis are produced by rolling powder mixtures. The microstructure, and elemental and phase compositions of the synthesized multilayer composite materials are studied by scanning electron microscopy and X-ray phase analysis. Particular attention is paid to the formation of intermediate layers and surface modification occurring during combustion. The strength characteristics of the synthesized materials are determined according to the three-point loading scheme at temperatures of 1100°C. Analysis of the obtained materials shows that joining in the combustion mode of metal foils and reaction tapes is provided due to reaction diffusion, mutual impregnation, and chemical reactions occurring in the reaction tapes and on the surface of the metal foils. The formation of thin intermediate layers in the form of cermet and eutectic solutions provides the synthesized multilayer materials with good strength properties up to 87 MPa at 1100°C. These results are of interest for the development of structural materials operating under extreme conditions.

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层状铌-金属陶瓷复合材料
摘要通过使用金属箔(Ti、Nb、Ta、Ni)和反应带(Ti + 1.7B)和(5Ti + 3Si)对初步结构的样品进行自蔓延高温合成,制备出基于铌和金属陶瓷的层状复合材料。用于合成的反应带是通过轧制粉末混合物制成的。通过扫描电子显微镜和 X 射线相分析研究了合成多层复合材料的微观结构、元素和相组成。特别关注了中间层的形成和燃烧过程中发生的表面改性。在 1100°C 的温度下,根据三点加载方案测定了合成材料的强度特性。对所得材料的分析表明,金属箔和反应带在燃烧模式下的结合是由于反应扩散、相互浸渍以及反应带和金属箔表面发生的化学反应。金属陶瓷和共晶溶液形式的中间薄层的形成,使合成的多层材料在 1100°C 时具有良好的强度特性,最高可达 87 兆帕。这些结果对于开发在极端条件下工作的结构材料具有重要意义。
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来源期刊
CiteScore
0.90
自引率
25.00%
发文量
144
审稿时长
3-8 weeks
期刊介绍: Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques publishes original articles on the topical problems of solid-state physics, materials science, experimental techniques, condensed media, nanostructures, surfaces of thin films, and phase boundaries: geometric and energetical structures of surfaces, the methods of computer simulations; physical and chemical properties and their changes upon radiation and other treatments; the methods of studies of films and surface layers of crystals (XRD, XPS, synchrotron radiation, neutron and electron diffraction, electron microscopic, scanning tunneling microscopic, atomic force microscopic studies, and other methods that provide data on the surfaces and thin films). Articles related to the methods and technics of structure studies are the focus of the journal. The journal accepts manuscripts of regular articles and reviews in English or Russian language from authors of all countries. All manuscripts are peer-reviewed.
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