Inhibiting Composition Against Steel Corrosion in Model Formation Waters of Oil and Gas Fields

Q4 Materials Science Steel in Translation Pub Date : 2024-02-29 DOI:10.3103/s0967091223110335
L. E. Tsygankova, A. E. Abramov, A. A. Uryadnikov, N. V. Shel’
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Abstract

In this paper, we study the protective effectiveness of the inhibitory composition (25–200 mg/L) against carbon steel corrosion in model formation waters NACE and M1 containing 400 mg/L of H2S individually and together with CO2 using gravimetry, potentiodynamic polarization, and impedance spectroscopy. Its ability to affect the diffusion of hydrogen into the metal and the development of sulfate-reducing bacteria is also estimated. Under static conditions, the protective effect is 73% in the NACE environment and 62% in the M1 environment at room temperature and 74 and 83% at 80°C, respectively. Under hydrodynamic conditions, the protective effect of the composition in the presence of a hydrocarbon phase (10%) reaches 90% in the NACE environment and 77% in the M1 environment. The inhibitory composition accelerates the diffusion of hydrogen into the metal and suppresses the growth of sulfate-reducing bacteria in the Postgate nutrient medium.

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油气田模型地层水中的钢腐蚀抑制成分
摘要 本文使用重力测量法、电位极化法和阻抗光谱法研究了抑制成分(25-200 mg/L)在单独和与 CO2 一起含有 400 mg/L H2S 的模型形成水 NACE 和 M1 中对碳钢腐蚀的保护效果。此外,还估算了其影响氢向金属扩散和硫酸盐还原菌发展的能力。在静态条件下,室温下的保护效果在 NACE 环境中为 73%,在 M1 环境中为 62%,在 80°C 时分别为 74% 和 83%。在流体动力条件下,当存在碳氢化合物相(10%)时,组合物的保护效果在 NACE 环境中达到 90%,在 M1 环境中达到 77%。抑制性组合物加速了氢向金属中的扩散,并抑制了 Postgate 营养培养基中硫酸盐还原菌的生长。
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Steel in Translation
Steel in Translation Materials Science-Materials Science (all)
CiteScore
0.60
自引率
0.00%
发文量
81
期刊介绍: Steel in Translation  is a journal that represents a selection of translated articles from two Russian metallurgical journals: Stal’  and Izvestiya Vysshikh Uchebnykh Zavedenii. Chernaya Metallurgiya . Steel in Translation  covers new developments in blast furnaces, steelmaking, rolled products, tubes, and metal manufacturing as well as unconventional methods of metallurgy and conservation of resources. Papers in materials science and relevant commercial applications make up a considerable portion of the journal’s contents. There is an emphasis on metal quality and cost effectiveness of metal production and treatment.
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