Synthesis, characterization, and implementation of BaNiO3 perovskite nanoparticles as thin film supercapacitor electrode

Abstract

This work is the first attempt to explore the supercapacitor applications of Barium nickelate (BaNiO₃) perovskite nanoparticles. The nanoparticles are synthesized using a simple combustion method and their morphology, elemental composition, and so forth are studied using standard characterization methods such as x-ray diffraction spectroscopy (XRD), field emission scanning electron microscopy (FESEM), and so forth. The nanoparticles were found to be hexagonal in shape, with an average particle size of 16 nm, and the elemental analysis confirms the successful synthesis of the BaNiO₃ perovskite nanoparticles. For electrochemical studies, the electrodes are fabricated over a wearable and flexible conductive fabric (CF) substrate. A slurry paste of the synthesized BaNiO₃ nanoparticles is applied over CF and dried overnight, thereby forming a thin film electrode. The fabricated electrode acts as a positive electrode with a high specific capacitance of 508.64 F g⁻¹ at 2.2 A g⁻¹ current density. Upon increasing the current density, the electrode maintains 60% of its specific capacitance and displays 97% cyclic stability over 5000 cycles. The electrochemical impedance spectroscopy (EIS) study indicates excellent conductivity of the electrode, with a bulk resistance of 3.2 Ohms. The electrochemical performance of the fabricated electrode is also compared with various previously reported works and the electrode displays higher specific capacitance and better cyclic stability. These findings suggest that the BaNiO₃ perovskite nanoparticles-based electrode holds promise for utilization as an anode material in supercapacitor applications.