Low Temperature n-Dodecane Droplet Combustion Experiments Aboard the International Space Station

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-05-13 DOI:10.1007/s12217-024-10115-x
Daniel Dietrich, Timmothy Krause, Vedha Nayagam, Tanvir Farouk, Frederick Dryer, Forman Williams
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Abstract

This paper presents data from large, isolated n-dodecane droplets burning in microgravity on the International Space Station, along with preliminary comparisons with numerical and analytic predictions indicating general agreement in trends. The tests involved were primarily in air (a few in reduced oxygen) at ambient pressures ranging from 0.50 to 5.0 atm. After ignition, the droplets burn with a hot flame that extinguishes when the radiant energy loss causes the flame temperature to drop below the hot-flame-required value. The total flame radiative loss at extinction is nearly independent of pressure, while the peak flame diameter prior to hot-flame extinction decreases with increasing pressure. The maximum hot-flame temperature, inferred from fiber-support radiative emisssions, decreases with increasing pressure, and the hot flames become dimmer with increasing pressure. At 1.0 atm and below there is a prolonged period of coolflame burning that ends with cool-flame extinction at a finite droplet size; the cool-flame-extinction droplet diameter increases and the cool-flame burning rate decreases with decreasing ambient pressure. Above 1.25 atm warm-flame burning and hot-flame re-ignitions become prevalent. At 5.0 atm, there is no abrupt hot-flame extinction with transition to a cool flame; the flame gradually gets dimmer, and the flame temperature decreases over a much longer time, the transition between hot-flame and warm-flame burning becoming almost undiscernible.

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国际空间站上的低温正十二烷液滴燃烧实验
本文介绍了在国际空间站上的微重力环境中燃烧的大型、孤立的正十二烷液滴的数据,以及与数值预测和分析预测的初步比较,结果表明两者的趋势基本一致。所涉及的测试主要在空气中进行(少数在还原氧中进行),环境压力从 0.50 到 5.0 atm 不等。点火后,液滴燃烧产生高温火焰,当辐射能损失导致火焰温度降至高温火焰要求值以下时,火焰熄灭。熄灭时的总火焰辐射损失几乎与压力无关,而热焰熄灭前的峰值火焰直径随着压力的增加而减小。根据纤维支撑辐射发射推断出的最大热焰温度随着压力的增加而降低,热焰随着压力的增加而变暗。在 1.0 atm 及以下,冷焰燃烧时间较长,最后以有限液滴大小的冷焰熄灭结束;冷焰熄灭液滴直径增大,冷焰燃烧速率随环境压力降低而降低。超过 1.25 atm 时,暖焰燃烧和热焰复燃变得普遍。在 5.0 atm 时,不会出现热焰突然熄灭并过渡到冷焰的情况;火焰会逐渐变暗,火焰温度会在更长的时间内下降,热焰燃烧和温焰燃烧之间的过渡几乎无法辨别。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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