{"title":"Complexes of Alkali Metal and the Ammonium Ion with the Cyclodimethylsiloxane ligands D7 and D8 (D = Me2SiO)","authors":"Carsten von Hänisch, Roman-Malte Richter","doi":"10.1002/zaac.202400036","DOIUrl":null,"url":null,"abstract":"We present complexes of alkali metal ions and the ammonium ion with the large cyclodimethylsiloxanes D7 and D8 (D = Me2SiO). The formation of such complexes is accompanied by rearrangements of the ligands to form complexes with a suitable ring size for the metal used. These rearrangements could be suppressed by suitable reaction conditions and rapid work‐up of the reaction mixtures. This enabled the isolation of [Li(D7)][GaI4] (1), [Li(D8)][GaI4] (2), [Na(D8)][GaI4] (3), [K(D8)][GaI4] (4) and [NH4(D8)][GaI4] (5). All of the prepared compounds were analysed using single‐crystal X‐ray diffraction as well as multinuclear NMR spectroscopy. This reveals very different coordination modes in the compounds obtained.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"90 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Zeitschrift für anorganische und allgemeine Chemie","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/zaac.202400036","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
We present complexes of alkali metal ions and the ammonium ion with the large cyclodimethylsiloxanes D7 and D8 (D = Me2SiO). The formation of such complexes is accompanied by rearrangements of the ligands to form complexes with a suitable ring size for the metal used. These rearrangements could be suppressed by suitable reaction conditions and rapid work‐up of the reaction mixtures. This enabled the isolation of [Li(D7)][GaI4] (1), [Li(D8)][GaI4] (2), [Na(D8)][GaI4] (3), [K(D8)][GaI4] (4) and [NH4(D8)][GaI4] (5). All of the prepared compounds were analysed using single‐crystal X‐ray diffraction as well as multinuclear NMR spectroscopy. This reveals very different coordination modes in the compounds obtained.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
