{"title":"High‐Pressure Synthesis and Crystal Structure of the Inoborate Ni[B2O2(OH)4]","authors":"Leonard Conrad Pasqualini, Hubert Huppertz","doi":"10.1002/zaac.202400137","DOIUrl":null,"url":null,"abstract":"The novel inoborate Ni[B2O2(OH)4] was synthesized under high‐pressure/high‐temperature conditions of 9 GPa and 800 °C. Its structure was determined via single‐crystal X‐ray diffraction analysis. The single‐grain IR‐spectrum of Ni[B2O2(OH)4] supports the existence of O–H bonds. The structural similarities and differences with the mineral vimsite possessing the sum formula Ca[B2O2(OH)4], as well as with the phylloborate HP‐Ni(B2O4) is discussed. The title compound can be described as the structural hydrolysis product of the latter.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Zeitschrift für anorganische und allgemeine Chemie","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/zaac.202400137","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
The novel inoborate Ni[B2O2(OH)4] was synthesized under high‐pressure/high‐temperature conditions of 9 GPa and 800 °C. Its structure was determined via single‐crystal X‐ray diffraction analysis. The single‐grain IR‐spectrum of Ni[B2O2(OH)4] supports the existence of O–H bonds. The structural similarities and differences with the mineral vimsite possessing the sum formula Ca[B2O2(OH)4], as well as with the phylloborate HP‐Ni(B2O4) is discussed. The title compound can be described as the structural hydrolysis product of the latter.
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