Electrodeposition behaviour of samarium in 1,3-dimethyl-2-imidazolidone solvent

IF 2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pure and Applied Chemistry Pub Date : 2024-05-13 DOI:10.1515/pac-2024-0110
Chrysanthus Andrew, Jayakumar Mani
{"title":"Electrodeposition behaviour of samarium in 1,3-dimethyl-2-imidazolidone solvent","authors":"Chrysanthus Andrew, Jayakumar Mani","doi":"10.1515/pac-2024-0110","DOIUrl":null,"url":null,"abstract":"The present study investigates the electrochemistry spectroscopy of Sm(III), and electrodeposition of samarium metal in neutral ligand-based ionic liquid (solvate ionic liquid). Mixture consisted of a samarium precursor (either samarium triflate or samarium nitrate hexahydrate) in the solvate ionic liquid, 1.3-dimethyl-2-imidazolidone (DMI). FT-IR analysis of Sm(III)-DMI electrolytes indicates that Sm<jats:sup>3+</jats:sup> ion coordinates with DMI through carbonyl group (C=O); the band splits into two with emergence of new peak at 1630 cm<jats:sup>−1</jats:sup> and 1649 cm<jats:sup>−1</jats:sup> for the triflate and nitrate solutions, respectively. Raman spectroscopy also confirms the solvation of Sm(III) with DMI through oxygen atom of the carbonyl group. Voltametric behaviour of Sm(III) ion indicates two-step reduction mechanism <jats:italic>via</jats:italic> Sm(III)/Sm(II) at <jats:italic>ca.</jats:italic> −2.0 V and Sm(II)/Sm(0) at <jats:italic>ca.</jats:italic> −3.0 V vs. Ag/Ag<jats:sup>+</jats:sup> for both samarium(III)-containing electrolytes. Diffusion coefficient value of Sm(III) was determined to be 2.185 × 10<jats:sup>−6</jats:sup> cm<jats:sup>2</jats:sup>/s and 2.418 × 10<jats:sup>−8</jats:sup> cm<jats:sup>2</jats:sup>/s for triflate and nitrate electrolytes, respectively. Electrodeposition of samarium was achieved through constant potential electrolysis using copper substrate as the working electrode which yielded compact deposits from triflate-DMI and non-uniform granular deposit from nitrate-DMI electrolyte. <jats:italic>Ex situ</jats:italic> X-ray photoelectron spectroscopy analysis of the as-deposited samples revealed the presence of metallic Sm (1081 eV) co-existing with its oxide form (1083 eV).","PeriodicalId":20911,"journal":{"name":"Pure and Applied Chemistry","volume":null,"pages":null},"PeriodicalIF":2.0000,"publicationDate":"2024-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Pure and Applied Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1515/pac-2024-0110","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

Abstract

The present study investigates the electrochemistry spectroscopy of Sm(III), and electrodeposition of samarium metal in neutral ligand-based ionic liquid (solvate ionic liquid). Mixture consisted of a samarium precursor (either samarium triflate or samarium nitrate hexahydrate) in the solvate ionic liquid, 1.3-dimethyl-2-imidazolidone (DMI). FT-IR analysis of Sm(III)-DMI electrolytes indicates that Sm3+ ion coordinates with DMI through carbonyl group (C=O); the band splits into two with emergence of new peak at 1630 cm−1 and 1649 cm−1 for the triflate and nitrate solutions, respectively. Raman spectroscopy also confirms the solvation of Sm(III) with DMI through oxygen atom of the carbonyl group. Voltametric behaviour of Sm(III) ion indicates two-step reduction mechanism via Sm(III)/Sm(II) at ca. −2.0 V and Sm(II)/Sm(0) at ca. −3.0 V vs. Ag/Ag+ for both samarium(III)-containing electrolytes. Diffusion coefficient value of Sm(III) was determined to be 2.185 × 10−6 cm2/s and 2.418 × 10−8 cm2/s for triflate and nitrate electrolytes, respectively. Electrodeposition of samarium was achieved through constant potential electrolysis using copper substrate as the working electrode which yielded compact deposits from triflate-DMI and non-uniform granular deposit from nitrate-DMI electrolyte. Ex situ X-ray photoelectron spectroscopy analysis of the as-deposited samples revealed the presence of metallic Sm (1081 eV) co-existing with its oxide form (1083 eV).
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
钐在 1,3-二甲基-2-咪唑烷酮溶剂中的电沉积特性
本研究探讨了 Sm(III) 的电化学光谱以及金属钐在中性配体离子液体(溶解离子液体)中的电沉积。混合物包括溶解离子液体 1.3-二甲基-2-咪唑烷酮(DMI)中的钐前体(三水合钐或六水合硝酸钐)。Sm(III)-DMI 电解质的傅立叶变换红外光谱分析表明,Sm3+ 离子通过羰基(C=O)与 DMI 配位;三盐酸盐溶液和硝酸盐溶液的光谱带一分为二,分别在 1630 cm-1 和 1649 cm-1 出现了新的峰值。拉曼光谱也证实了 Sm(III)通过羰基的氧原子与 DMI 溶合。Sm(III) 离子的伏安特性表明,Sm(III)/Sm(II) 在约 -2.0 V 和 Sm(II) 在约 -2.0 V 的电压下有两步还原机制。-与 Ag.对于两种含钐(III)的电解质,Sm(III)/Sm(II)和Sm(II)/Sm(0)分别在-3.0 V和-3.0 V与Ag/Ag+发生反应。在三盐酸盐和硝酸盐电解质中,Sm(III) 的扩散系数值分别为 2.185 × 10-6 cm2/s 和 2.418 × 10-8 cm2/s。使用铜基板作为工作电极,通过恒电位电解实现了钐的电沉积,在三盐酸盐-DMI 电解质中产生了紧凑的沉积物,而在硝酸盐-DMI 电解质中产生了不均匀的颗粒状沉积物。对沉积样品进行的原位 X 射线光电子能谱分析表明,金属钐(1081 eV)与其氧化物形式(1083 eV)共存。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Pure and Applied Chemistry
Pure and Applied Chemistry 化学-化学综合
CiteScore
4.00
自引率
0.00%
发文量
60
审稿时长
3-8 weeks
期刊介绍: Pure and Applied Chemistry is the official monthly Journal of IUPAC, with responsibility for publishing works arising from those international scientific events and projects that are sponsored and undertaken by the Union. The policy is to publish highly topical and credible works at the forefront of all aspects of pure and applied chemistry, and the attendant goal is to promote widespread acceptance of the Journal as an authoritative and indispensable holding in academic and institutional libraries.
期刊最新文献
Removal of acidic dyes; acid yellow 25 and acid red 4 from wastewater by degassed activated carbon Molecular approach to semiconductors: a shift towards ecofriendly manufacturing and neuroinspired interfaces The impact of nanofiller composition and nature on the enhancement of mechanical and rheological properties of poly(lactic acid) (PLA) nanobiocomposite films is achieved by regulating the spacing of organic fillers and PLA crystallinity Green chemistry for all: three principles of Inclusive Green and Sustainable Chemistry Education The case of the disappearing energy: potential energies in concentration gradients
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1