Catalytic Combustion Enhancement In-Situ for Heavy Oil Recovery

IF 0.6 4区 工程技术 Q4 ENERGY & FUELS Chemistry and Technology of Fuels and Oils Pub Date : 2024-05-13 DOI:10.1007/s10553-024-01682-1
O. V. Ostolopovskaya, L. A. Akhmetzyanova, Mohammed A. Khelkhal, A. A. Eskin, A. V. Vakhin
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Abstract

It is common knowledge that in-situ combustion is highly promising method for improving heavy oil recovery. The present research explores the effects of Cobalt-ligated catalysts derived from sunflower oil (CoSFO) and tall oil (CoTO) on heavy oil oxidation, aiming to enhance in-situ combustion process. Through differential scanning calorimetry (DSC) we assessed the oxidation kinetics of heavy oil in the presence and absence of these catalysts. Our findings indicate that both CoSFO and CoTO significantly improve the oxidation process, particularly in the high-temperature oxidation (HTO) phase crucial for combustion front stabilization. Notably, CoTO demonstrated superior efficacy in reducing oxidation times across all conversion levels, suggesting its potential to optimize the efficiency of EOR techniques. This research highlights the promise of Cobalt-ligated catalysts in advancing heavy oil recovery and suggests directions for future studies to further investigate their industrial applications.

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原位催化燃烧提高重油采收率
众所周知,原位燃烧是一种非常有前途的提高重油采收率的方法。本研究探讨了从葵花籽油(CoSFO)和妥尔油(CoTO)中提取的钴化催化剂对重油氧化的影响,旨在加强原位燃烧过程。通过差示扫描量热法(DSC),我们评估了重油在这些催化剂存在和不存在的情况下的氧化动力学。我们的研究结果表明,CoSFO 和 CoTO 都能显著改善氧化过程,尤其是对燃烧前沿稳定至关重要的高温氧化(HTO)阶段。值得注意的是,CoTO 在缩短所有转化水平的氧化时间方面都表现出卓越的功效,这表明它具有优化 EOR 技术效率的潜力。这项研究强调了钴化催化剂在推进重油采收方面的前景,并为今后进一步研究其工业应用指明了方向。
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来源期刊
Chemistry and Technology of Fuels and Oils
Chemistry and Technology of Fuels and Oils 工程技术-工程:化工
CiteScore
0.90
自引率
16.70%
发文量
119
审稿时长
1.0 months
期刊介绍: Chemistry and Technology of Fuels and Oils publishes reports on improvements in the processing of petroleum and natural gas and cracking and refining techniques for the production of high-quality fuels, oils, greases, specialty fluids, additives and synthetics. The journal includes timely articles on the demulsification, desalting, and desulfurizing of crude oil; new flow plans for refineries; platforming, isomerization, catalytic reforming, and alkylation processes for obtaining aromatic hydrocarbons and high-octane gasoline; methods of producing ethylene, acetylene, benzene, acids, alcohols, esters, and other compounds from petroleum, as well as hydrogen from natural gas and liquid products.
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