Adsorptive performance of graphene oxide-activated carbon composite for simultaneous removal of diclofenac sodium and ibuprofen from aqueous solutions in batch mode

IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Journal of the Iranian Chemical Society Pub Date : 2024-05-13 DOI:10.1007/s13738-024-03029-3
Bentolhoda Chenarani, Mohammad Nader Lotfollahi
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Abstract

Graphene oxide-activated carbon (GO–AC) composite with different ratios of GO and AC (0.5/0.5, 0.3/0.7 and 0.1/0.9) were synthesized via direct chemical bonding of them using hydrogen peroxide as a chemical linker and used for selective removal of diclofenac sodium (DCF) and ibuprofen (IBP) from aqueous solutions. The adsorbents' surface morphology, composition, and physicochemical structure of the adsorbents were characterized by FE-SEM, FTIR, BET and XRD analysis. The synthesized composite with a ratio of GO and AC (0.1/0.9) was the most suitable among the synthesized adsorbents for both DCF and IBP adsorption. The optimal working conditions for DCF removal were at pH of 2, contact time of 40 min, initial concentration of 100 mg/L, and temperature of 293 K. For IBP removal, the optimal operating conditions were at pH of 2, contact time of 60 min, initial concentration of 20 mg/L, and temperature of 293 K. The highest adsorption capacities of 0.1/0.9 composite for DCF and IBP were 833.33 and 238.095 mg/g at 298 K, respectively. Isotherm, kinetic, and thermodynamic characteristics were assessed to analyze the adsorption process. The synthesized adsorbent displays high removal efficiency by simple recyclability with low-cost reagent and high selectivity for drug pollutants such as DCF and IBP in single and binary systems.

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批处理模式下氧化石墨烯活性炭复合材料同时去除水溶液中双氯芬酸钠和布洛芬的吸附性能
以过氧化氢为化学连接剂,通过直接化学键合的方法合成了不同比例的氧化石墨烯-活性炭(GO-AC)复合材料(GO 和 AC 的比例分别为 0.5/0.5、0.3/0.7 和 0.1/0.9),并将其用于选择性去除水溶液中的双氯芬酸钠(DCF)和布洛芬(IBP)。通过 FE-SEM、FTIR、BET 和 XRD 分析对吸附剂的表面形貌、组成和理化结构进行了表征。在已合成的吸附剂中,GO 和 AC 的比例(0.1/0.9)最适合吸附 DCF 和 IBP。去除 DCF 的最佳工作条件为:pH 值为 2,接触时间为 40 分钟,初始浓度为 100 mg/L,温度为 293 K;去除 IBP 的最佳工作条件为:pH 值为 2,接触时间为 60 分钟,初始浓度为 20 mg/L,温度为 293 K。对等温线、动力学和热力学特性进行了评估,以分析吸附过程。所合成的吸附剂具有简单的可回收性和低成本试剂的特点,在单一和二元体系中对 DCF 和 IBP 等药物污染物具有较高的选择性,因而具有较高的去除效率。
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来源期刊
CiteScore
4.40
自引率
8.30%
发文量
230
审稿时长
5.6 months
期刊介绍: JICS is an international journal covering general fields of chemistry. JICS welcomes high quality original papers in English dealing with experimental, theoretical and applied research related to all branches of chemistry. These include the fields of analytical, inorganic, organic and physical chemistry as well as the chemical biology area. Review articles discussing specific areas of chemistry of current chemical or biological importance are also published. JICS ensures visibility of your research results to a worldwide audience in science. You are kindly invited to submit your manuscript to the Editor-in-Chief or Regional Editor. All contributions in the form of original papers or short communications will be peer reviewed and published free of charge after acceptance.
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