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Methods for the fluorescence sensing of thiamine (vitamin B1)-by copper metal organic framework and rhodamine b on graphene oxide with cucurbit[7]uril 利用铜金属有机框架和罗丹明 b 在石墨烯氧化物上与葫芦[7]脲进行硫胺素(维生素 B1)荧光传感的方法
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-11-10 DOI: 10.1007/s13738-024-03133-4
Pavitra Rajendran, Sudha Sankaran, Lakshminarayanan Piramuthu, Cheng Yang, E. R. Nagarajan, Narayanan Selvapalam

Thiamine detection has been developed using Copper-Metal Organic Frameworks (CuMOF) and Rhodamine B-complexed Graphene Oxide (RhGO), facilitating both direct and indirect fluorescence-based sensing of thiamine. Both these methods are less cumbersome and sensitive fluorometric methods which are developed from less expensive materials. CuMOF offered the oxidation route of thiamine to thiochrome, which is a fluorescence compound; through which thiamine was detected conveniently by measuring thiochrome. On the other hand, rhodamine B bound graphene oxide–RhGO, released rhodamine B upon interaction with the thiamine through the competitive binding against the rhodamine B located on the graphene oxide, which allowed us to develop a facile sensor for thiamine in DMF. Moreover, the sensitivity of the sensor was improved through the encapsulation effect with cucurbit[7]uril (CB[7]). The limits of detection (LOD) for CuMOF and RhGO with CB[7] were determined to be 48.39 × 10–8 M and 68.33 × 10–8 M, respectively. The sensing ability of RhGO was effectively utilized in commercially available thiamine drugs, and its performance was evaluated against other hydrochloride drugs such as metformin, ciprofloxacin, and cetirizine demonstrating its suitability for real-time sample analysis. This approach provides a practical solution for both analytical and pharmaceutical laboratories. Overall, two different detection methods for thiamine have been developed with good selectivity and sensitivity.

Graphical Abstract

利用铜-金属有机框架(CuMOF)和罗丹明 B-络合石墨烯氧化物(RhGO)开发了硫胺素检测方法,从而促进了硫胺素的直接和间接荧光传感。这两种方法都是利用价格较低的材料开发出来的简便灵敏的荧光测定法。CuMOF 提供了硫胺素氧化为硫代铬的途径,硫代铬是一种荧光化合物,通过测量硫代铬可以方便地检测硫胺素。另一方面,与罗丹明 B 结合的氧化石墨烯-RhGO 在与硫胺素作用时,会通过与位于氧化石墨烯上的罗丹明 B 的竞争性结合释放罗丹明 B,这使我们能够开发出一种在 DMF 中检测硫胺素的简便传感器。此外,通过葫芦[7]脲(CB[7])的封装效应,传感器的灵敏度也得到了提高。CuMOF 和含有 CB[7] 的 RhGO 的检出限(LOD)分别为 48.39 × 10-8 M 和 68.33 × 10-8 M。RhGO 的传感能力在市售硫胺素药物中得到了有效利用,其性能还针对二甲双胍、环丙沙星和西替利嗪等其他盐酸药物进行了评估,证明其适用于实时样品分析。这种方法为分析和制药实验室提供了一种实用的解决方案。总之,已开发出两种不同的硫胺素检测方法,具有良好的选择性和灵敏度。
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引用次数: 0
Method for analyzing nitrogen trifluoride impurities in high-purity carbon tetrafluoride by gas chromatography 利用气相色谱法分析高纯度四氟化碳中三氟化氮杂质的方法
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-11-10 DOI: 10.1007/s13738-024-03134-3
Mengdan Wang, Zhenquan Han, Jianyue Li, Yinhai Zhou, Jinlong Wang

A method for the analysis of trace nitrogen trifluoride impurities in high-purity carbon tetrafluoride (≥ 99.999%) by gas chromatography equipped with a flame ionization detector is described. A 10-port valve and three columns have been used in this instrument system, which can completely separate nitrogen trifluoride and carbon tetrafluoride. In the best analytical conditions, the quantification limit was estimated at 16.62 ppb for an injected sample volume of 1 mL. Furthermore, this method can be completed by one sample injection without the need to vent some of the main component-high-purity carbon tetrafluoride through the valve switch, which is more accurate and simple.

介绍了一种配备火焰离子化检测器的气相色谱法分析高纯度四氟化碳(≥ 99.999%)中痕量三氟化氮杂质的方法。该仪器系统采用了一个 10 口阀和三根色谱柱,可以完全分离三氟化氮和四氟化碳。在最佳分析条件下,进样量为 1 mL 时,定量限估计为 16.62 ppb。此外,该方法只需一次进样即可完成,无需通过阀门开关排出部分主要成分--高纯度四氟化碳,更加准确简便。
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引用次数: 0
Efficient and selective oxidation of alcohols and hydrocarbons catalyzed by oxovanadium(IV) unsymmetrical salophen complex supported on silica-coated CoFe2O4 magnetic nanoparticles 二氧化硅包覆的 CoFe2O4 磁性纳米粒子上支持的氧钒(IV)不对称盐基络合物催化的醇类和碳氢化合物的高效和选择性氧化作用
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-11-08 DOI: 10.1007/s13738-024-03128-1
Mehdi Hatefi Ardakani, Atena Naeimi, Zeynab Mohammadabadi

In this study, the catalytic activity of an oxovanadium(IV) unsymmetrical salophen complex immobilized on chloro-functionalized silica-coated CoFe2O4 magnetic nanoparticles CoFe2O4@SiO2@CPTMS@VO(salophen-OH), in which salophen-OH = 4-[(E)-{(2-[(E)-2-hydroxybenzylidene)amino]phenyl}imino)methyl]benzene-1,3-diol was explored in the oxidation of alcohols and hydrocarbons. This heterogeneous nanocatalyst showed high activity and selectivity in oxidizing various primary and secondary alcohols to the equivalent aldehydes and ketones with 30% H2O2 as a green oxidant in polyethylene glycol (PEG) as an eco-friendly solvent at 80 °C. Furthermore, the above catalyst demonstrated significant catalytic efficiency in the alkene epoxidation and alkane hydroxylation using tert-butyl hydroperoxide (tert-BuOOH), and the corresponding products were achieved in good to excellent yields in acetonitrile at ambient temperature. This magnetic nanocatalyst can be easily separated from the reaction mixture utilizing an external magnet and reused up to five times without significant activity loss. Moreover, the recovered catalyst’s structure was scrutinized using Fourier transform infrared (FT-IR), vibrating sample magnetometry (VSM), and X-ray diffraction (XRD) techniques, which confirmed that the structure of the catalyst remained unaltered post-recovery.

在这项研究中,固定在氯功能化二氧化硅包覆 CoFe2O4 磁性纳米粒子 CoFe2O4@SiO2@CPTMS@VO(salophen-OH) 上的氧钒(IV)不对称盐吩络合剂具有催化活性、其中 salophen-OH = 4-[(E)-{(2-[(E)-2-羟基亚苄基)氨基]苯基}亚氨基)甲基]苯-1,3-二醇。在以聚乙二醇(PEG)为环保溶剂、温度为 80 °C 的条件下,以 30% 的 H2O2 为绿色氧化剂,这种异相纳米催化剂在将各种伯醇和仲醇氧化成等效的醛和酮时表现出了高活性和高选择性。此外,上述催化剂在使用叔丁基过氧化氢(tert-BuOOH)进行烯烃环氧化和烷烃羟基化时表现出显著的催化效率,并在乙腈中于常温下以良好至极佳的收率获得相应的产物。这种磁性纳米催化剂可利用外部磁铁轻松从反应混合物中分离出来,并可重复使用多达五次,而不会有明显的活性损失。此外,利用傅立叶变换红外(FT-IR)、振动样品磁力计(VSM)和 X 射线衍射(XRD)技术对回收催化剂的结构进行了仔细研究,结果证实催化剂的结构在回收后未发生变化。
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引用次数: 0
New luminescent Eu(III) and Er(III) Schiff base complexes: synthesis, characterization and luminescence properties 新的发光 Eu(III) 和 Er(III) 席夫碱配合物:合成、表征和发光特性
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-11-05 DOI: 10.1007/s13738-024-03117-4
Aziza Sarwar, Mustaffa Shamsuddin, Karimah Kassim, Ehsanullah Kakar, Hamid Ullah, Shazia Iqbal

Two new complexes of europium (III) and erbium (III) were synthesized from diaminodiphenylether bridged spacer in 1:1 molar ratio of ligand and metal salt, whereas the ligand was synthesized in 1:2 molar ratio of diaminodiphenylether and aldehyde. The synthesized complexes were structurally analyzed through nuclear magnetic resonance (NMR), Fourier transform infrared (FTIR), energy-dispersive X-ray diffraction (EDX), UV–visible and photoluminescence spectroscopy. In both synthesized complexes, the metals were found in coordination to nitrogen and oxygen atoms of the azomethine (HC = N) and hydroxyl (–OH) groups as evident by FTIR and NMR spectral results in both synthesized complexes. Molar conductivity data for Eu(III) and Er(III) observed in the range of 129–135.5 Ω−1cm2 mol−1 determined that both complexes were 1:2 electrolytes. The presence of characteristic peaks for Eu, C, O and N was clearly identified in energy-dispersive X-ray diffraction, which confirmed its successful synthesis. Furthermore, the luminescence behavior of the complexes was investigated in the solution state with dichloromethane (DCM). Upon excitation at 274 nm, both complexes exhibited two emission bands centered at 379 nm to 399 nm and 519 nm for Eu(III) and Er(III). Consequently, the good emission properties illustrated that the synthesized complexes featured their potential as promising cost-effective luminescent materials.

Graphical abstract

配体和金属盐的摩尔比为 1:1,配体和二氨基二苯醚的摩尔比为 1:2。合成的配合物通过核磁共振(NMR)、傅立叶变换红外(FTIR)、能量色散 X 射线衍射(EDX)、紫外可见光和光致发光光谱进行了结构分析。傅立叶变换红外光谱和核磁共振光谱结果表明,在这两种合成的配合物中,金属都与偶氮甲基(HC = N)和羟基(-OH)的氮原子和氧原子配位。在 129-135.5 Ω-1cm2 mol-1 范围内观察到的 Eu(III) 和 Er(III) 摩尔电导率数据表明,这两种复合物都是 1:2 电解质。在能量色散 X 射线衍射中,清楚地发现了 Eu、C、O 和 N 的特征峰,这证实了它的成功合成。此外,还研究了这些复合物在二氯甲烷(DCM)溶液状态下的发光行为。在 274 纳米波长的激发下,Eu(III) 和 Er(III)的两个配合物均显示出以 379 纳米波长至 399 纳米波长和 519 纳米波长为中心的两条发射带。因此,良好的发射特性说明合成的配合物具有作为具有成本效益的发光材料的潜力。
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引用次数: 0
Regioselective ROH-epoxystyrene-opening over MWCNTs-[N4] macrocycle comprising Cu(II), Fe(III) or Cr(III) 在包含铜(II)、铁(III)或铬(III)的 MWCNTs-[N4]大环上进行区域选择性 ROH 环氧苯乙烯开环
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-11-05 DOI: 10.1007/s13738-024-03123-6
Sommayyeh Golsanamlou, Aliakbar Tarlani, Khashayar Narimani, Ehsan Hassani, Kioumars Aghapoor

By considering the importance of heterogeneous catalysts with separation and recycling ability from the reaction environment and ring opening of epoxide as a regularly essential conversion in organic synthesis, tetraaza macrocyclic complexes of Cu(П), Fe(IП) and Cr(Ш) were grafted on the acylated multiwalled carbon nanotubes (MWCNTs) to produce new nanocomposites as heterogeneous catalysts. Then the nanocomposites were applied in the regioselective ring-opening reaction of epoxystyrene with different alcohols to obtain β-alkoxy compounds. For the characterization of tetraazamacrocycle and nanocomposites, FT-IR, TGA, XRD, FE-SEM and Raman were employed. Results showed that the complexes were successfully grafted on the functionalized MWCNTs. Ring-opening reactions took place at high yield and favorite time, especially for the shorter chain alcohols. In the best case, nanocomposite containing Fe(Ш) (MWCNTs-C (=O)–TAM·FeIII) accomplished the ring opening of epoxystyrene by methanol (100%) within 15 min at 50 °C, and after 3 recycling test, there are negligible changes in its catalytic performance.

考虑到具有与反应环境分离和回收能力的异相催化剂的重要性,以及环氧化物开环是有机合成中经常发生的重要转化,研究人员在酰化多壁碳纳米管(MWCNTs)上接枝了铜(П)、铁(ⅠП)和铬(Ш)的四氮杂大环配合物,制备出新型纳米复合材料作为异相催化剂。然后,将纳米复合材料应用于环氧苯乙烯与不同醇类的区域选择性开环反应,得到β-烷氧基化合物。四氮杂环己烷和纳米复合材料的表征采用了傅立叶变换红外光谱、热重分析、X射线衍射、FE-SEM和拉曼光谱。结果表明,复合物成功地接枝到了功能化的 MWCNT 上。开环反应以较高的产率和最短的时间进行,尤其是较短链的醇。在最佳情况下,含有 Fe(Ш) (MWCNTs-C (=O)-TAM-FeIII )的纳米复合材料在 50 °C 下 15 分钟内完成了甲醇(100%)对环氧苯乙烯的开环反应,并且经过 3 次循环测试后,其催化性能变化微乎其微。
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引用次数: 0
Colorimetric assay of NO2− and Hg2+ through on–off strategy of the Cu, Mo-CDs nanozyme 通过 Cu、Mo-CDs 纳米酶的开关策略对 NO2- 和 Hg2+ 进行比色分析
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-11-05 DOI: 10.1007/s13738-024-03119-2
Hongmei Pu, Yifan Cui, Haidan Wang, Lijuan Yu, Dezhi Yang, Yaling Yang, Hong Li

Until now, there have been many reports on the regulation of inorganic metal ions on the catalytic activity of nanozymes, but few reports on the regulation of anions (such as NO2) on enzyme activity. In this work, a copper-molybdenum doped carbon dots (Cu, Mo-CDs) with peroxidase-like (POD) activity was synthesized by simple one-step microwave digestion method. The Cu, Mo-CDs + NO2 system can promote 3,3′,5,5′-tetramethylbenzidine (TMB) oxidizing to blue oxidative product (oxTMB) due to the formation of ∙NO2 free radical. While Hg2+ was introduced into the system, the POD-like activity of Cu, Mo-CDs + NO2 system was inhibited due to the strong interaction and the electron transfer between Cu, Mo-CDs and Hg2+. The formation of ∙NO2 and the electron transfer capability of Cu, Mo-CDs + Hg2+ were confirmed through ESR spectra and FMN experiments. The bioenzyme-free colorimetric assay based on Cu, Mo-CDs nanozyme is used for detection of NO2 and Hg2+, showing lower detection limit (LOD) of 1.63 µg/L for NO2, 0.13 µg/L for Hg2+, respectively and good recovery from 90.79 to 108.90%. The work paves a new way to design a nanozyme-based colorimetric protocol for traces NO2 and Hg2+ residues in food analysis.

迄今为止,关于无机金属离子对纳米酶催化活性调控的报道很多,但阴离子(如 NO2-)对酶活性调控的报道却很少。本研究采用简单的一步微波消解法合成了具有过氧化物酶样(POD)活性的铜钼掺杂碳点(Cu, Mo-CDs)。Cu、Mo-CDs + NO2-体系能促进3,3′,5,5′-四甲基联苯胺(TMB)氧化成蓝色氧化产物(oxTMB),这是由于形成了∙NO2自由基。当引入 Hg2+ 时,由于 Cu、Mo-CDs 和 Hg2+ 之间强烈的相互作用和电子传递,Cu、Mo-CDs + NO2- 体系的 POD 类活性受到抑制。通过 ESR 光谱和 FMN 实验证实了 Cu、Mo-CDs + Hg2+ 的 NO2 生成和电子传递能力。基于 Cu, Mo-CDs 纳米酶的无生物酶比色法用于检测 NO2-和 Hg2+,结果表明 NO2-和 Hg2+的检测下限(LOD)分别为 1.63 µg/L和 0.13 µg/L,回收率为 90.79%至 108.90%。这项工作为设计一种基于纳米酶的比色方案来分析食品中的痕量 NO2- 和 Hg2+ 残留开辟了一条新途径。
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引用次数: 0
Retraction Note: Metal-ion-directed synthesis of two nanostructured coordination polymers: topological diversity and growth inhibition of human glioma cells 撤稿说明:金属离子定向合成两种纳米结构配位聚合物:拓扑多样性和对人类胶质瘤细胞的生长抑制作用
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-11-04 DOI: 10.1007/s13738-024-03126-3
Bo Wei, Chao Du, Le Wang, Da-Liang Kong, Rui Wang
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引用次数: 0
Synthesis, crystal structure, spectral, and DFT analysis of 2-(2,3,4-trimethoxyphenyl)-1H-phenanthro[9,10-d]imidazole as charge transport material 作为电荷传输材料的 2-(2,3,4-三甲氧基苯基)-1H-菲罗[9,10-d]咪唑的合成、晶体结构、光谱和 DFT 分析
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-11-04 DOI: 10.1007/s13738-024-03111-w
Peter Solo, M. Arockia doss

A novel 2-(2,3,4-trimethoxyphenyl)-1H-phenanthro[9,10-d]imidazole crystal has been reported and characterized by FT-IR, 1H NMR, and 13C NMR spectral techniques. Single-crystal XRD studies reveal that the compound crystallizes into orthorhombic crystal system with Pbcn space group, and crystallographic data have been deposited in the Cambridge crystallographic data centre with CCDC number: 2244532. Various computational analyses such as hydrogen bond analysis, molecular electrostatic potential analysis, natural population analysis, Hirshfeld surface, and Frontier molecular orbital analysis were performed to elucidate the structure of the crystal. The calculation of reorganization energy and coupling constant using DFT methods reveals that the compound could be investigated as a hole transport material.

报告了一种新型 2-(2,3,4-三甲氧基苯基)-1H-菲罗[9,10-d]咪唑晶体,并通过傅立叶变换红外光谱、1H NMR 和 13C NMR 光谱技术对其进行了表征。单晶 XRD 研究表明,该化合物结晶为 Pbcn 空间群的正方晶系,结晶数据已存入剑桥结晶数据中心,CCDC 编号为:2244532。为阐明该晶体的结构,进行了各种计算分析,如氢键分析、分子静电位分析、自然群体分析、Hirshfeld 表面和前沿分子轨道分析。利用 DFT 方法计算的重组能和耦合常数表明,该化合物可作为空穴传输材料进行研究。
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引用次数: 0
A modified approach for the determination of sulfate in cosmetics and personal care products by UV–Vis spectroscopy using response surface methodology 利用响应面方法通过紫外可见光谱测定化妆品和个人护理产品中硫酸盐含量的改进方法
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-11-04 DOI: 10.1007/s13738-024-03127-2
Prabhakaran Mathiyalagan, Stephen Alocius, Atul Jadhav

In recent years, “sulfate-free” products have become increasingly common for most cosmetics and personal care products. With a boom in the number of sulfate-free claims, an analytical method for determining sulfate is certainly needed. Analysis of sulfate in cosmetic products can be difficult due to matrix interference and the complex nature of the ingredients used in the formulation. A simple and novel modified method for the determination of sulfate was developed by using UV–Vis spectroscopy. The procedure involved the precipitation of sulfate as barium sulfate and the removal of interference under controlled conditions, using different reagents such as acid, glycerol and ethanol. The method was optimized for the best conditions using response surface methodology. According to the experimental design, nitric acid and glycerol at 2% concentration yielded the maximum absorbance and the optimized method was validated in terms of linearity, accuracy, precision, limit of detection and limit of quantification. Fifteen market samples belonging to the shampoo and conditioner product types were analyzed to evaluate the performance of the optimized method. The results obtained were found to be satisfactory, and the proposed method is linear (R2—0.9971), accurate (89 to 92%), precise (%RSD < 4) and robust (% deviation < 5) with limit of detection (4.2 mg/l), limit of quantification (12.59 mg/l) and can be employed for the analysis of sulfate in cosmetics and personal care products.

近年来,"无硫酸盐 "产品在大多数化妆品和个人护理产品中越来越常见。随着无硫酸盐声明数量的激增,肯定需要一种测定硫酸盐的分析方法。由于基质干扰和配方中所用成分的复杂性,分析化妆品中的硫酸盐可能比较困难。我们利用紫外可见分光光度法开发了一种简单而新颖的硫酸盐测定改良方法。该方法使用不同的试剂,如酸、甘油和乙醇,在可控条件下沉淀硫酸钡并去除干扰。采用响应面方法对该方法进行了优化,以获得最佳条件。根据实验设计,浓度为 2% 的硝酸和甘油可产生最大吸光度,优化后的方法在线性、准确度、精密度、检出限和定量限方面都得到了验证。对洗发水和护发素产品类型的 15 个市场样品进行了分析,以评估优化方法的性能。结果令人满意,该方法线性(R2-0.9971)、准确(89%-92%)、精密(%RSD < 4)、稳健(%偏差 < 5),检出限(4.2 mg/l)、定量限(12.59 mg/l),可用于化妆品和个人护理产品中硫酸盐的分析。
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引用次数: 0
Vitamin-catalyzed organic transformations: a green synthetic tool inspired by nature 维生素催化的有机转化:受大自然启发的绿色合成工具
IF 2.2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Pub Date : 2024-10-30 DOI: 10.1007/s13738-024-03124-5
Sanjay Paul

Vitamins are not only essential for normal cell function but also important in organic transformations, specifically in the field of organocatalysis. Due to the increasing importance of sustainable and ecofriendly organic reaction protocols, there has been growing attention in organocatalysis owing to easy access, biocompatibility, and excellent reactivity. As vitamins are environmentally benign, nontoxic, and economic organocatalyst, VB1, VB2, and VB12 have been employed successfully in variety of organic transformations. The catalysts exhibited very high efficacy in various C–C bond-forming reactions from multicomponent reaction to cross-coupling reactions. This review concisely demonstrates catalytic performance of natural organocatalyst VB1, VB2, and VB12 and also provides basic knowledge about this important synthetic tool for the preparation of organic compounds in a greener manner. The review explores the versatile application of vitamins where vitamins acted as the principal catalyst (Lewis acidic catalyst, photocatalyst), co-catalyst, organometallic catalyst, and ligand of metal ion catalysts. Utilization of vitamin-functionalized nanocatalysts in cross-coupling, A3-coupling, oxidation reaction, etc. has been demonstrated thoroughly. Additionally, the mechanistic details illuminating the roles of vitamins in important organic transformations are meticulously explained, providing insights into reaction pathways and empowering the described organcatalysis approaches.

维生素不仅是细胞正常功能所必需的,而且在有机转化,特别是在有机催化领域也很重要。由于可持续和生态友好型有机反应方案的重要性与日俱增,有机催化因其易得性、生物相容性和出色的反应性而日益受到关注。由于维生素是一种对环境无害、无毒且经济的有机催化剂,VB1、VB2 和 VB12 已被成功用于各种有机转化。从多组分反应到交叉偶联反应,这些催化剂在各种 C-C 键形成反应中都表现出极高的功效。这篇综述简明扼要地展示了天然有机催化剂 VB1、VB2 和 VB12 的催化性能,并提供了有关这一重要合成工具的基本知识,以便以更环保的方式制备有机化合物。综述探讨了维生素的多种应用,其中维生素可作为主催化剂(路易斯酸催化剂、光催化剂)、助催化剂、有机金属催化剂和金属离子催化剂的配体。维生素官能化纳米催化剂在交叉耦合、A3-耦合、氧化反应等方面的应用已得到充分证明。此外,还详细解释了维生素在重要有机转化中的作用的机理细节,提供了对反应途径的见解,并增强了所述有机催化方法的能力。
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引用次数: 0
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Journal of the Iranian Chemical Society
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