Hydrothermal formation of novel SrCeO3/RGO nanocomposite as supercapacitor electrode material

IF 2.3 4区 材料科学 Q2 MATERIALS SCIENCE, CERAMICS Journal of Sol-Gel Science and Technology Pub Date : 2024-05-10 DOI:10.1007/s10971-024-06401-0
Tamoor Ahmad, Albandari W. Alrowaily, B. M. Alotaibi, Haifa A. Alyousef, A. Dahshan, A. M. A. Henaish
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Abstract

Growing populations and development led to a higher utilization of fossil fuels and more CO2 emissions; which prompted researchers to look for pollution-free energy sources and improved energy-storage technologies. Supercapacitors (SCs) are thought to be the most advanced available energy-storage technology and are improving day by day via modifying the electrode composition. In this work, we described the hydrothermal production of SrCeO3/RGO nanocomposite as an effective and high-performance electrode material for SCs. Different approaches were adopted to look at the structural features along with the electrochemical behaviors of the prepared nanocomposite. X-ray structural analysis data and surface analysis showed that the nanocomposite had a pure crystalline phase and enhanced surface area. SrCeO3/RGO nanocomposite possessed a specific capacitance of 1359.9 F/g at 1 A/g, while it was 653.1 F/g for pure SrCeO3 electrode. The nanocomposite showed a small decrease in its polarization curve area following the 6000th cycle of the stability test. Additionally, SrCeO3 and SrCeO3/RGO nanocomposite exhibited specific energy of 28.7 and 63.5 Wh/kg at 1 A/g value with specific power of 281.5 and 290.1 W/kg, respectively. Numerous findings demonstrated that the enhanced ion/electron mobility and electric conductivity of nanocomposite lead to a rapid charge-storing approach and significantly boost electrochemical performance. The exceptional functionality of the SrCeO3/RGO nanocomposite demonstrated its favorable potential for the future generation of energy storage by reducing reliance on materials with a spinel-like structure.

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水热法形成新型 SrCeO3/RGO 纳米复合材料作为超级电容器电极材料
人口的增长和发展导致化石燃料的利用率提高,二氧化碳排放量增加;这促使研究人员寻找无污染的能源和改进的储能技术。超级电容器(SC)被认为是目前最先进的储能技术,并通过改变电极成分而日臻完善。在这项工作中,我们介绍了水热法生产 SrCeO3/RGO 纳米复合材料作为 SCs 的有效和高性能电极材料。我们采用不同的方法研究了所制备纳米复合材料的结构特征和电化学行为。X 射线结构分析数据和表面分析表明,纳米复合材料具有纯晶相和更大的比表面积。SrCeO3/RGO 纳米复合材料在 1 A/g 时的比电容为 1359.9 F/g,而纯 SrCeO3 电极的比电容为 653.1 F/g。在稳定性测试的第 6000 个循环后,纳米复合材料的极化曲线面积略有下降。此外,在 1 A/g 值下,SrCeO3 和 SrCeO3/RGO 纳米复合材料的比能量分别为 28.7 和 63.5 Wh/kg,比功率分别为 281.5 和 290.1 W/kg。大量研究结果表明,纳米复合材料的离子/电子迁移率和导电性增强,可快速存储电荷,显著提高电化学性能。SrCeO3/RGO 纳米复合材料的卓越功能表明,它可以减少对类尖晶石结构材料的依赖,从而为未来的储能技术带来巨大潜力。
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来源期刊
Journal of Sol-Gel Science and Technology
Journal of Sol-Gel Science and Technology 工程技术-材料科学:硅酸盐
CiteScore
4.70
自引率
4.00%
发文量
280
审稿时长
2.1 months
期刊介绍: The primary objective of the Journal of Sol-Gel Science and Technology (JSST), the official journal of the International Sol-Gel Society, is to provide an international forum for the dissemination of scientific, technological, and general knowledge about materials processed by chemical nanotechnologies known as the "sol-gel" process. The materials of interest include gels, gel-derived glasses, ceramics in form of nano- and micro-powders, bulk, fibres, thin films and coatings as well as more recent materials such as hybrid organic-inorganic materials and composites. Such materials exhibit a wide range of optical, electronic, magnetic, chemical, environmental, and biomedical properties and functionalities. Methods for producing sol-gel-derived materials and the industrial uses of these materials are also of great interest.
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