Extraordinary synergy on 3D hierarchical porous Co-Cu nanocomposite for catalytic elimination of VOCs at low temperature and high space velocity

Abstract

It is still a challenge to develop hierarchically nanostructured catalysts with simple approaches to enhance the low-temperature catalytic activity. Herein, a set of mesoporous Co-Cu binary metal oxides with different morphologies were successfully prepared via a facile ammonium bicarbonate precipitation method without any templates or surfactants, which were further applied for catalytic removal of carcinogenic toluene. Among the catalysts with different ratios, the CoCu_0.2 composite oxide presented the best performance, where the temperature required for 90% conversion of toluene was only 237°C at the high weight hour space velocity (WHSV) of 240,000 mL/(g_cat·hr). Meanwhile, compared to the related Co-Cu composite oxides prepared by using different precipitants (NaOH and H₂C₂O₄), the NH₄HCO₃-derived CoCu_0.2 sample exhibited better catalytic efficiency in toluene oxidation, while the T₉₀ were 22 and 28°C lower than those samples prepared by NaOH and H₂C₂O₄ routes, respectively. Based on various characterizations, it could be deduced that the excellent performance was related to the small crystal size (6.7 nm), large specific surface area (77.0 m²/g), hollow hierarchical nanostructure with abundant high valence Co ions and adsorbed oxygen species. In situ DRIFTS further revealed that the possible reaction pathway for the toluene oxidation over CoCu_0.2 catalyst followed the route of absorbed toluene → benzyl alcohol → benzaldehyde → benzoic acid → carbonate → CO₂ and H₂O. In addition, CoCu_0.2 sample could keep stable with long-time operation and occur little inactivation under humid condition (5 vol.% water), which revealed that the NH₄HCO₃-derived CoCu_0.2 nanocatalyst possessed great potential in industrial applications for VOCs abatement.