Wangnan Cui , Zishu Wang , Wei Feng , Chao Qin , Hong Liao , Yuhang Wang , Mingjie Xie
{"title":"Evaluating coarse PM composition and sources based on bulk and molecular speciation of PM2.5 and PM10 in Nanjing, East China","authors":"Wangnan Cui , Zishu Wang , Wei Feng , Chao Qin , Hong Liao , Yuhang Wang , Mingjie Xie","doi":"10.1016/j.jes.2024.04.038","DOIUrl":null,"url":null,"abstract":"<div><p>To understand the differences in the composition and sources of PM<sub>2.5</sub> and PM<sub>10</sub> caused by coarse particles, integrated PM<sub>2.5</sub> and PM<sub>10</sub> samples were synchronously collected in Nanjing, East China, in summer 2020 and winter 2020/2021. Bulk and molecular speciation and light absorption measurements of aerosol extracts were performed, followed by positive matrix factorization (PMF) based on the PM<sub>2.5</sub> and PM<sub>10</sub> data sets, respectively. The difference in average concentrations of total bulk species between PM<sub>2.5</sub> and PM<sub>10</sub> was mainly caused by the distribution of considerable NO<sub>3</sub><sup>–</sup>, SO<sub>4</sub><sup>2–</sup>, Ca<sup>2+</sup>, and organic carbon (OC) in coarse particles. Coarse PM influenced by abrasion products from tire wear and leaves contributed about half of the low-volatility <em>n-</em>alkanes in summer. The contribution of coarse PM to biomass burning tracers and water-soluble OC increased in winter when biomass combustion was excessively active. More than 70% of sugar polyols were attributable to coarse PM in summer, and biomass burning could be an important source in winter. The light-absorbing organic chromophores were almost entirely associated with PM<sub>2.5</sub>, but water-soluble organic carbon (WSOC) exhibited stronger light absorption in PM<sub>10</sub> extracts than in PM<sub>2.5</sub> extracts possibly due to the influence of coarse PM on pH. PMF analysis indicated that biomass burning, aqueous-phase reactions, and processed dust were the main contributors of organic matter and its light absorption in winter. Biogenic primary and secondary sources made discernable contributions only in summer. The differences between PM<sub>2.5</sub> and PM<sub>10</sub> were likely attributed to mixing of crustal dust, combustion particles, and surface reactions.</p></div>","PeriodicalId":15788,"journal":{"name":"Journal of Environmental Sciences-china","volume":"152 ","pages":"Pages 155-166"},"PeriodicalIF":5.9000,"publicationDate":"2024-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Environmental Sciences-china","FirstCategoryId":"93","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1001074224002237","RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
引用次数: 0
Abstract
To understand the differences in the composition and sources of PM2.5 and PM10 caused by coarse particles, integrated PM2.5 and PM10 samples were synchronously collected in Nanjing, East China, in summer 2020 and winter 2020/2021. Bulk and molecular speciation and light absorption measurements of aerosol extracts were performed, followed by positive matrix factorization (PMF) based on the PM2.5 and PM10 data sets, respectively. The difference in average concentrations of total bulk species between PM2.5 and PM10 was mainly caused by the distribution of considerable NO3–, SO42–, Ca2+, and organic carbon (OC) in coarse particles. Coarse PM influenced by abrasion products from tire wear and leaves contributed about half of the low-volatility n-alkanes in summer. The contribution of coarse PM to biomass burning tracers and water-soluble OC increased in winter when biomass combustion was excessively active. More than 70% of sugar polyols were attributable to coarse PM in summer, and biomass burning could be an important source in winter. The light-absorbing organic chromophores were almost entirely associated with PM2.5, but water-soluble organic carbon (WSOC) exhibited stronger light absorption in PM10 extracts than in PM2.5 extracts possibly due to the influence of coarse PM on pH. PMF analysis indicated that biomass burning, aqueous-phase reactions, and processed dust were the main contributors of organic matter and its light absorption in winter. Biogenic primary and secondary sources made discernable contributions only in summer. The differences between PM2.5 and PM10 were likely attributed to mixing of crustal dust, combustion particles, and surface reactions.
期刊介绍:
The Journal of Environmental Sciences is an international journal started in 1989. The journal is devoted to publish original, peer-reviewed research papers on main aspects of environmental sciences, such as environmental chemistry, environmental biology, ecology, geosciences and environmental physics. Appropriate subjects include basic and applied research on atmospheric, terrestrial and aquatic environments, pollution control and abatement technology, conservation of natural resources, environmental health and toxicology. Announcements of international environmental science meetings and other recent information are also included.