Electrodes from carbonized grass clippings for bioelectrochemical systems

Alexander Langsdorf , Michael Halim , Marianne Volkmar , Markus Stöckl , Ralf Harnisch , Peter Hahn , Roland Ulber , Dirk Holtmann
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Abstract

One major obstacle to the commercialization of electrobiotechnological systems is the cost of materials, including expensive electrodes. Smart recycling as well as the use of renewable resources can contribute to producing electrodes more ecologically and economically. Green waste is a biogenic residual material that occurs mainly in urban areas and is currently not recycled to a sufficient extent. Here we show the fabrication of electrodes from carbonized grass clippings and their application in microbial electrosynthesis as well as microbial fuel cells. While the electrodes cannot compete with established metal competitors for water electrolysis in microbial electrosynthesis, they perform comparably to commercial graphite electrodes in microbial fuel cells. With Geobacter sulfurreducens, a current response can be recorded for more than six weeks. To the best of our knowledge, this is the first time that carbonized green waste has been used as an electrode material for bioelectrochemical systems. This demonstrates the potential of carbonized biological materials as a raw material for electrodes and presents a recycling alternative for green waste.

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用于生物电化学系统的碳化草屑电极
电生物技术系统商业化的一个主要障碍是材料成本,包括昂贵的电极。巧妙的回收利用以及可再生资源的使用有助于生产出更生态、更经济的电极。绿色垃圾是一种生物残留材料,主要出现在城市地区,目前还没有得到充分的回收利用。在这里,我们展示了利用碳化草屑制造电极及其在微生物电合成和微生物燃料电池中的应用。在微生物电合成中,这些电极在电解水方面无法与现有的金属竞争者相比,但在微生物燃料电池中,它们的性能可与商用石墨电极媲美。利用硫化还原 Geobacter,可以记录超过六周的电流响应。据我们所知,这是碳化绿色废物首次被用作生物电化学系统的电极材料。这证明了碳化生物材料作为电极原材料的潜力,并为绿色废物的回收利用提供了一种替代方案。
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