Micropatternable Ink Composed of MAX Phase ZIF-8 for Gas Sensing Applications

Chen Chen, 胜辉 夏, Jinhong Liu, Kyle Leatt, Thomas Thundat, Ajit Khosla
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Abstract

This work provides a detailed introduction to the preparation methods, structural characteristics, and various performance tests of the Ti3C2/ZIF-8 composite material. Initially, the composite material is obtained through the synthesis, mixing, and subsequent processing of MXene solution and ZIF-8 nanoparticles. The coating structure and properties were comprehensively characterized using SEM, TEM, and XRD. These analyses revealed the material's layered structure, high crystallinity, and surface activity. BET analysis of Ti3C2/ZIF-8 also shows excellent gas adsorption-desorption performance, having an especially high-efficiency adsorption capacity for VOCs. TGA further demonstrates the thermal stability and chemical stability of Ti3C2/ZIF-8 and its printability was tested indicating widespread application potential in coating preparation through ultrasonic spray technology. Finally, we show methods to regulate and control coating thickness and roughness for precision manufacturing. These analyses together emphasize the application value of Ti3C2/ZIF-8 in fields such as gas-storage, gas-separation, and environmental monitoring.
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用于气体传感应用的 MAX 相 ZIF-8 微图案油墨
本研究详细介绍了 Ti3C2/ZIF-8 复合材料的制备方法、结构特征和各种性能测试。首先,通过 MXene 溶液和 ZIF-8 纳米粒子的合成、混合和后续加工得到复合材料。利用 SEM、TEM 和 XRD 对涂层结构和性能进行了全面表征。这些分析表明了材料的层状结构、高结晶度和表面活性。此外,Ti3C2/ZIF-8 的 BET 分析表明其具有优异的气体吸附-解吸性能,尤其是对挥发性有机化合物具有高效的吸附能力。TGA 进一步证明了 Ti3C2/ZIF-8 的热稳定性和化学稳定性,其可印刷性测试表明,通过超声波喷涂技术制备涂层具有广泛的应用潜力。最后,我们展示了用于精密制造的涂层厚度和粗糙度的调节和控制方法。这些分析共同强调了 Ti3C2/ZIF-8 在气体储存、气体分离和环境监测等领域的应用价值。
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