Micropatterning MXene/TiO2 Nanocomposite Ink for Gas Sensing

Jinhong Liu, Chen Chen, 胜辉 夏, Kyle Leatt, Ajit Khosla, Thomas Thundat
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Abstract

This work describes the preparation, characterization, and micropatterning of MXene(Ti3C2)/TiO2 nanocomposite inks. MXene nanopowder was oxidized to form MXene/TiO2 nanocomposite powder using an air-aging method. The MXene/TiO2 inks were prepared using deionized water (H2O) as the solvent/dispersant and polyvinylpyrrolidone (PVP) as the surfactant. Various techniques were utilized to characterize the MXene/TiO2 nanocomposite material, and the BET results showed the preferential adsorption of butane of the MXene/TiO2 coating. Utilizing an ultrasonic dispersion printer in conjunction with a stencil mask, the MXene/TiO2 nanocomposite ink was successfully printed onto a 10mm*10mm gold-plated silicon substrate. This process achieved millimeter-level precision control, enabling the printing of fine lines with a width of 1μm and a spacing of 0.05mm. Furthermore, this technique demonstrated the ability to render various complex patterns, thus exemplifying the potential of MXene/TiO2 nanocomposite ink in the field of micro- and nano-manufacturing.
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用于气体传感的微图案化 MXene/TiO2 纳米复合油墨
这项工作描述了 MXene(Ti3C2)/TiO2 纳米复合油墨的制备、表征和微图案化。采用空气老化法将 MXene 纳米粉体氧化成 MXene/TiO2 纳米复合粉体。制备 MXene/TiO2 油墨时使用去离子水(H2O)作为溶剂/分散剂,聚乙烯吡咯烷酮(PVP)作为表面活性剂。利用各种技术对 MXene/TiO2 纳米复合材料进行了表征,BET 结果显示 MXene/TiO2 涂层优先吸附丁烷。利用超声波分散打印机和模板掩模,成功地将 MXene/TiO2 纳米复合墨水打印到了 10mm*10mm 的镀金硅基板上。这一工艺实现了毫米级的精度控制,能够打印出宽度为 1 微米、间距为 0.05 毫米的精细线条。此外,这项技术还展示了呈现各种复杂图案的能力,从而体现了 MXene/TiO2 纳米复合油墨在微米和纳米制造领域的潜力。
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