Multiple-angle incidence resolution spectrometry (MAIRS): applications in nanoarchitectonics and applied physics

Nobutaka Shioya, Taizo Mori, K. Ariga, Takeshi Hasegawa
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Abstract

The cutting-edge thin film studies using the multiple-angle incidence resolution spectrometry (MAIRS) are introduced from the principle to forefront applications in a wide variety of research fields covering semiconductor material with respect to nanoarchitectonics. MAIRS basically reveals quantitatively optical anisotropy in thin films, which is mostly used for quantitative molecular orientation analysis of each chemical group for chemistry purposes. This works powerfully especially when the material has poor crystallinity that cannot be analyzed by X-ray diffraction analysis. As a matter of fact, MAIRS works as a role that compensates for the diffraction techniques, and the combination of MAIRS and the diffraction techniques has already established as the most powerful technique not to miss the molecular aggregation structure in thin films. In this review, in addition, another application for physics purposes is also introduced where phonon in thin films is discriminated from normal infrared absorption bands by using the MAIRS technique.
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多角入射分辨光谱仪(MAIRS):在纳米建筑学和应用物理学中的应用
本书介绍了利用多角入射分辨光谱仪(MAIRS)进行的尖端薄膜研究,从原理到前沿应用,涉及纳米结构半导体材料等多个研究领域。多入射分辨光谱法基本上能定量揭示薄膜中的光学各向异性,主要用于对化学目的中每个化学基团的分子取向进行定量分析。尤其是当材料的结晶度较低,无法用 X 射线衍射分析法进行分析时,这种方法就更有效了。事实上,MAIRS 起到了弥补衍射技术的作用,而且 MAIRS 和衍射技术的结合已经成为不遗漏薄膜中分子聚集结构的最强大技术。此外,本综述还介绍了另一项物理学应用,即利用 MAIRS 技术将薄膜中的声子与普通红外吸收带区分开来。
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