Four-channel catalytic micro-reactor based on alumina hollow fiber membrane for efficient catalytic oxidation of CO

IF 3.7 3区 工程技术 Q2 ENGINEERING, CHEMICAL Chinese Journal of Chemical Engineering Pub Date : 2024-07-01 DOI:10.1016/j.cjche.2024.03.024
Baichuan Xu, Bin Wang, Tao Li
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Abstract

The traditional automotive catalytic converter using commercial ceramic honeycomb carriers has many problems such as high back pressure, low engine efficiency, and high usage of precious metals. This study proposes a four-channel catalytic micro-reactor based on alumina hollow fiber membrane, which uses phase inversion method for structural molding and regulation. Due to the advantages of its carrier, it can achieve lower ignition temperature under low noble metal loading. With Pd/CeO2 at a loading rate of 2.3% (mass), the result showed that the reaction ignition temperature is even less than 160 °C, which is more than 90 °C lower than the data of commercial ceramic substrates under similar catalyst loading and airspeed conditions. The technology in turn significantly reduces the energy consumption of the reaction. And stability tests were conducted under constant conditions for 1000 h, which proved that this catalytic converter has high catalytic efficiency and stability, providing prospects for the design of innovative catalytic converters in the future.

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基于氧化铝中空纤维膜的四通道催化微反应器用于高效催化氧化 CO
传统的汽车催化转化器采用商用陶瓷蜂窝载体,存在背压高、发动机效率低、贵金属用量大等诸多问题。本研究提出了一种基于氧化铝中空纤维膜的四通道催化微反应器,采用相位反转法进行结构成型和调控。由于其载体的优势,它可以在低贵金属负载下实现较低的点火温度。在 Pd/CeO2 加载率为 2.3%(质量)的情况下,结果表明反应点火温度甚至低于 160 ℃,比商用陶瓷基底在类似催化剂加载和空速条件下的数据低 90 ℃ 以上。该技术反过来又大大降低了反应能耗。同时,在恒定条件下进行了 1000 小时的稳定性测试,证明该催化转换器具有较高的催化效率和稳定性,为未来设计创新型催化转换器提供了前景。
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来源期刊
Chinese Journal of Chemical Engineering
Chinese Journal of Chemical Engineering 工程技术-工程:化工
CiteScore
6.60
自引率
5.30%
发文量
4309
审稿时长
31 days
期刊介绍: The Chinese Journal of Chemical Engineering (Monthly, started in 1982) is the official journal of the Chemical Industry and Engineering Society of China and published by the Chemical Industry Press Co. Ltd. The aim of the journal is to develop the international exchange of scientific and technical information in the field of chemical engineering. It publishes original research papers that cover the major advancements and achievements in chemical engineering in China as well as some articles from overseas contributors. The topics of journal include chemical engineering, chemical technology, biochemical engineering, energy and environmental engineering and other relevant fields. Papers are published on the basis of their relevance to theoretical research, practical application or potential uses in the industry as Research Papers, Communications, Reviews and Perspectives. Prominent domestic and overseas chemical experts and scholars have been invited to form an International Advisory Board and the Editorial Committee. It enjoys recognition among Chinese academia and industry as a reliable source of information of what is going on in chemical engineering research, both domestic and abroad.
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