Evaluation of Jordanian Basalt as a Thermal Insulation Material

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-05-01 DOI:10.12911/22998993/184216
Soraya Mercedes Pérez
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Abstract

Finding a thermal insulation material that is naturally available, cheap, and effective for minimising energy losses is a challenge for geotechnical engineers in Jordan. Previous research suggests the use of mineral wool, polyurethane, or air layers as an insulation material but so far, the basalt has not been used as an insulation material in Jordan. The objective of this study was to measure and compare the thermal conductivity ( K ), bulk density (ρ B ), porosity (ɛ) and chemical composition of the basalt from Hashemiah area and Hulial mountain in Jordan in order to evaluate the rock as a thermal insulation material. A total of fourteen samples, seven for each zone, were evaluated. The thermal conductivity was measured using transient plane source technique (TPS) at ambient temperature. Porosity and density were measured by the standards of the American Society of Testing Materials (ASTM). The chemical composition of the samples was analysed by X-Ray diffraction to include the effect of aluminium oxide on thermal conductiv - ity analysis. Experimental values covered the range of ɛ between 0.008–8.7%; ρ B between 2.54–2.93 g/cm 3 and K between 1.62–2.98 W/mK. The experimental K values were compared with allometric fit and theoretical prediction models. In general, thermal conductivity tends to decrease with porosity in basalt samples. This study found increasing conductivity values with ɛ when ferromagnesian-aluminium oxide concentration reached levels above 38% and porosity less than 4% indicating that high percentages of these oxides decrease the insulating effect of the air in the empty spaces of the basalt at reduced porosity levels. Low values of conductivity and percentage of ferromagnesian-aluminium oxides characterise the Jordanian basalt in the Hashemiah area and makes it better for insulation than the Hulial mountain basalt. The experimental values presented in this work are important for predicting the optimum insulation thickness and predicting energy losses in construction buildings where basaltic rocks are used.
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约旦玄武岩作为隔热材料的评估
对于约旦的岩土工程师来说,寻找一种天然、廉价、有效的隔热材料来减少能源损失是一项挑战。以往的研究建议使用矿棉、聚氨酯或空气层作为隔热材料,但迄今为止,约旦尚未使用玄武岩作为隔热材料。本研究的目的是测量和比较约旦哈希米亚地区和胡利亚尔山的玄武岩的导热系数(K)、体积密度(ρ B)、孔隙率(ɛ)和化学成分,以评估玄武岩作为隔热材料的性能。共评估了 14 个样本,每个区域 7 个。热导率是在环境温度下使用瞬态平面源技术(TPS)测量的。孔隙率和密度按照美国材料试验协会(ASTM)的标准进行测量。通过 X 射线衍射分析了样品的化学成分,包括氧化铝对热导率分析的影响。实验值的范围包括:ɛ 在 0.008-8.7% 之间;ρ B 在 2.54-2.93 g/cm 3 之间;K 在 1.62-2.98 W/mK 之间。实验得出的 K 值与异速拟合模型和理论预测模型进行了比较。一般来说,玄武岩样本的导热率会随着孔隙率的增加而降低。本研究发现,当铁镁铝氧化物浓度达到 38% 以上、孔隙率小于 4% 时,电导率值会随着ɛ 的增加而增加,这表明这些氧化物的高比例会降低玄武岩空隙中空气在孔隙率降低时的隔热效果。哈希米亚地区的约旦玄武岩的导电率和铁镁铝氧化物百分比值较低,这使其比胡利亚尔山的玄武岩具有更好的隔热性能。这项工作中提出的实验值对于预测使用玄武岩的建筑中的最佳隔热厚度和预测能量损失非常重要。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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