{"title":"Positive steady states of a class of power law systems with independent decompositions","authors":"Al Jay Lan J. Alamin, Bryan S. Hernandez","doi":"10.1007/s10910-024-01622-8","DOIUrl":null,"url":null,"abstract":"<div><p>Power law systems have been studied extensively due to their wide-ranging applications, particularly in chemistry. In this work, we focus on power law systems that can be decomposed into stoichiometrically independent subsystems. We show that for such systems where the ranks of the augmented matrices containing the kinetic order vectors of the underlying subnetworks sum up to the rank of the augmented matrix containing the kinetic order vectors of the entire network, then the existence of the positive steady states of each stoichiometrically independent subsystem is a necessary and sufficient condition for the existence of the positive steady states of the given power law system. We demonstrate the result through illustrative examples. One of which is a network of a carbon cycle model that satisfies the assumptions, while the other network fails to meet the assumptions. Finally, using the aforementioned result, we present a systematic method for deriving positive steady state parametrizations for the mentioned subclass of power law systems, which is a generalization of our recent method for mass action systems.</p></div>","PeriodicalId":648,"journal":{"name":"Journal of Mathematical Chemistry","volume":"62 7","pages":""},"PeriodicalIF":1.7000,"publicationDate":"2024-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Mathematical Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10910-024-01622-8","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Power law systems have been studied extensively due to their wide-ranging applications, particularly in chemistry. In this work, we focus on power law systems that can be decomposed into stoichiometrically independent subsystems. We show that for such systems where the ranks of the augmented matrices containing the kinetic order vectors of the underlying subnetworks sum up to the rank of the augmented matrix containing the kinetic order vectors of the entire network, then the existence of the positive steady states of each stoichiometrically independent subsystem is a necessary and sufficient condition for the existence of the positive steady states of the given power law system. We demonstrate the result through illustrative examples. One of which is a network of a carbon cycle model that satisfies the assumptions, while the other network fails to meet the assumptions. Finally, using the aforementioned result, we present a systematic method for deriving positive steady state parametrizations for the mentioned subclass of power law systems, which is a generalization of our recent method for mass action systems.
期刊介绍:
The Journal of Mathematical Chemistry (JOMC) publishes original, chemically important mathematical results which use non-routine mathematical methodologies often unfamiliar to the usual audience of mainstream experimental and theoretical chemistry journals. Furthermore JOMC publishes papers on novel applications of more familiar mathematical techniques and analyses of chemical problems which indicate the need for new mathematical approaches.
Mathematical chemistry is a truly interdisciplinary subject, a field of rapidly growing importance. As chemistry becomes more and more amenable to mathematically rigorous study, it is likely that chemistry will also become an alert and demanding consumer of new mathematical results. The level of complexity of chemical problems is often very high, and modeling molecular behaviour and chemical reactions does require new mathematical approaches. Chemistry is witnessing an important shift in emphasis: simplistic models are no longer satisfactory, and more detailed mathematical understanding of complex chemical properties and phenomena are required. From theoretical chemistry and quantum chemistry to applied fields such as molecular modeling, drug design, molecular engineering, and the development of supramolecular structures, mathematical chemistry is an important discipline providing both explanations and predictions. JOMC has an important role in advancing chemistry to an era of detailed understanding of molecules and reactions.