Xianyu Qiang , Dali Hou , Shijie Liang , Jie Su , Bo Chen
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引用次数: 0
Abstract
The calculation of three-phase equilibrium in CO2-hydrocarbon-water mixtures holds significant importance within numerical simulations, particularly in applications such as CO2-enhanced oil recovery and carbon dioxide sequestration. However, due to the non-ideality of CO2 and the polarity of water, three-phase equilibrium calculations often encounter convergence challenges. The augmented free-water flash algorithm [6], specifically focusing on CO2 dissolution in the aqueous phase, addresses the convergence challenges encountered by traditional three-phase flash algorithms. Despite its accuracy diminishes under conditions of high pressure and high CO2 concentrations, limiting its capability to accurately describe CO2 dissolution in oil-gas-water multiphase systems. The GE (excess Gibbs free energy) type mixing rule can be effectively integrated with equations of state, including PR and SRK, by utilizing activity models like NRTL and UNIFAC, which can be applied to the calculation of thermodynamic parameters for both nonpolar and polar systems and high-pressure complex systems. In this study, based on the augmented free-water assumption, we have developed a new augmented free-water three-phase flash algorithm for CO2/hydrocarbon/water mixtures. This algorithm integrates the PR equation of state with the NRTL activity model, employing the HV mixing rule for CO2-water interactions and the Van der Waals rule for other non-polar components. Furthermore, to enhance computational efficiency, the algorithm incorporates the simulated annealing global optimization algorithm, replacing Newton iteration to more effectively identify the global minima of the complex objective function. The example calculations show that the improved augmented free-water flash algorithm has higher accuracy and efficiency than the traditional augmented free-water flash algorithm. The augmented free-water three-phase flash algorithm proposed in this paper offers a precise model for phase equilibrium calculations essential for numerical simulations in CO2-enhanced oil recovery and carbon dioxide sequestration.
期刊介绍：
Fluid Phase Equilibria publishes high-quality papers dealing with experimental, theoretical, and applied research related to equilibrium and transport properties of fluids, solids, and interfaces. Subjects of interest include physical/phase and chemical equilibria; equilibrium and nonequilibrium thermophysical properties; fundamental thermodynamic relations; and stability. The systems central to the journal include pure substances and mixtures of organic and inorganic materials, including polymers, biochemicals, and surfactants with sufficient characterization of composition and purity for the results to be reproduced. Alloys are of interest only when thermodynamic studies are included, purely material studies will not be considered. In all cases, authors are expected to provide physical or chemical interpretations of the results.
Experimental research can include measurements under all conditions of temperature, pressure, and composition, including critical and supercritical. Measurements are to be associated with systems and conditions of fundamental or applied interest, and may not be only a collection of routine data, such as physical property or solubility measurements at limited pressures and temperatures close to ambient, or surfactant studies focussed strictly on micellisation or micelle structure. Papers reporting common data must be accompanied by new physical insights and/or contemporary or new theory or techniques.
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