Recent Advances in Metal–Organic Framework Electrode Materials for all-Metal-Ion Batteries

IF 2.5 4区工程技术 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Journal of Electronic Materials Pub Date : 2024-05-20 DOI:10.1007/s11664-024-11126-5

Brindha Ramasubramanian, Goutam Kumar Dalapati, Seeram Ramakrishna

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Abstract

This study presents a collective review of the latest developments in the application of metal–organic frameworks (MOFs) in various metal-ion batteries (MIBs), including lithium-ion batteries (LIBs) and multivalent-ion batteries, from 2015 to 2023. First, the types of MOFs, standard fabrication methods, and electrochemical properties required for building efficient batteries are discussed. Next, MOFs suitable for specific MIBs and their electrode features, underlying mechanisms, and device performance are discussed. ZIF-8, UiO-66, and MIL-101 are primarily studied in LIBs, while Na₂Zn₂(BDC)₂(DMF)₂ and MIL-101 are the main MOFs examined as cathode materials in SIBs due to their structural stability and favorable ion diffusion characteristics. However, MOFs are limited in magnesium- and aluminum-ion batteries due to the complex electrochemical redox reactions and interfacial stability issues involved. MOFs based on Fe, Mn, and Li show potential as cathodes, and MOF-derived carbon anodes are commonly used in all MIBs. The article further explores the three-dimensional (3D) electrode structure of MOFs, which favors faster ion diffusion within the electrolyte and external electron transport. MOF use in all-metal batteries still needs to be explored, and the article highlights the complexities involved.

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全金属离子电池金属有机框架电极材料的最新进展

本研究综述了2015年至2023年金属有机框架（mof）在各种金属离子电池（MIBs）中应用的最新进展，包括锂离子电池（LIBs）和多价离子电池。首先，讨论了MOFs的类型、标准制造方法和构建高效电池所需的电化学性能。接下来，讨论了适用于特定mib的mof及其电极特征、潜在机制和器件性能。ZIF-8、UiO-66和MIL-101主要在LIBs中进行研究，而Na2Zn2(BDC)2(DMF)2和MIL-101由于其结构稳定和良好的离子扩散特性是SIBs中主要作为正极材料的mof。然而，由于复杂的电化学氧化还原反应和涉及的界面稳定性问题，mof在镁离子和铝离子电池中的应用受到限制。基于Fe， Mn和Li的mof显示出作为阴极的潜力，并且mof衍生的碳阳极通常用于所有的mof。本文进一步探讨了mof的三维（3D）电极结构，该结构有利于离子在电解质内更快的扩散和外部电子的传递。MOF在全金属电池中的应用仍有待探索，这篇文章强调了其中的复杂性。图形抽象

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来源期刊

Journal of Electronic Materials 工程技术-材料科学：综合

CiteScore

4.10

自引率

4.80%

发文量

693

审稿时长

3.8 months

期刊介绍： The Journal of Electronic Materials (JEM) reports monthly on the science and technology of electronic materials, while examining new applications for semiconductors, magnetic alloys, dielectrics, nanoscale materials, and photonic materials. The journal welcomes articles on methods for preparing and evaluating the chemical, physical, electronic, and optical properties of these materials. Specific areas of interest are materials for state-of-the-art transistors, nanotechnology, electronic packaging, detectors, emitters, metallization, superconductivity, and energy applications. Review papers on current topics enable individuals in the field of electronics to keep abreast of activities in areas peripheral to their own. JEM also selects papers from conferences such as the Electronic Materials Conference, the U.S. Workshop on the Physics and Chemistry of II-VI Materials, and the International Conference on Thermoelectrics. It benefits both specialists and non-specialists in the electronic materials field. A journal of The Minerals, Metals & Materials Society.