Combined effects of ignition position and hydrogen ratio on vented CH4/H2/air explosions

IF 3.6 3区 工程技术 Q2 ENGINEERING, CHEMICAL Journal of Loss Prevention in The Process Industries Pub Date : 2024-05-24 DOI:10.1016/j.jlp.2024.105356
Jin Guo, Zexuan Yang, Liang Mei, Shikai Huang, Haozhe Wang
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Abstract

Experiments on the effects of ignition position and hydrogen ratio (χ) on the explosions of CH4/H2/air mixtures were experimentally investigated in a vented cylindrical vessel. Relevant experiments were conducted utilizing ignition sources situated at the rear (rear ignition), the center of the vessel (central ignition), or near the vent (front ignition) with χ varying from 0 to 1.0. Two types of cellular structures on the flame surface, owing to the diffusional-thermal instability and acoustically enhanced combustion, respectively, were observed, and the latter resulted in acoustic oscillations of the overpressure within the vessel and a unique overpressure peak p2 with amplitude sensitive to both ignition position and χ. The effects of ignition position and χ on the build-up of the internal pressure were not significant when χ ≤ 0.15. The maximum explosion overpressure in the vessel (pmax) under the explosions of rear and central ignitions (RI and CI) increased monotonically as χ was increased from 0.3 to 1.0, but a nonmonotonic trend was found in the explosions of front ignition (FI). CI could be regarded as the worst-case scenario when 0.45≤χ ≤ 1.0 except for χ = 0.7, because FI resulted in the highest pmax at χ = 0.7. A pressure peak outside the vent (pext) caused by the combustion expansion of the combustible cloud could be distinguished when χ ≥ 0.45 in the explosions of RI and CI. The amplitude of pext increased with an increase in χ. Rear ignition always led to the highest pext when χ > 0.6.

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点火位置和氢比对排出的 CH4/H2/air 爆炸的综合影响
在一个通风的圆柱形容器中,实验研究了点火位置和氢比(χ)对 CH4/H2/air 混合物爆炸的影响。相关实验利用的点火源分别位于容器后部(后点火)、中心(中心点火)或通风口附近(前点火),χ 在 0 至 1.0 之间变化。在火焰表面观察到两种蜂窝状结构,分别是由于扩散-热不稳定性和声学增强燃烧,后者导致容器内超压的声学振荡和独特的超压峰 p2,其振幅对点火位置和 χ 敏感。当 χ ≤ 0.15 时,点火位置和 χ 对内压增加的影响不明显。当 χ 从 0.3 增加到 1.0 时,后点火和中央点火(RI 和 CI)爆炸下容器内的最大爆炸超压(pmax)单调增加,但在前点火(FI)爆炸中发现了非单调趋势。当 0.45≤χ ≤ 1.0 时,CI 可视为最坏情况,但 χ = 0.7 时除外,因为 FI 在 χ = 0.7 时产生最高 pmax。在 RI 和 CI 的爆炸中,当 χ ≥ 0.45 时,可分辨出由可燃云燃烧膨胀引起的通风口外压力峰值(pext)。pext的振幅随着χ的增大而增大。当 χ > 0.6 时,后点火总是导致最高的 pext。
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来源期刊
CiteScore
7.20
自引率
14.30%
发文量
226
审稿时长
52 days
期刊介绍: The broad scope of the journal is process safety. Process safety is defined as the prevention and mitigation of process-related injuries and damage arising from process incidents involving fire, explosion and toxic release. Such undesired events occur in the process industries during the use, storage, manufacture, handling, and transportation of highly hazardous chemicals.
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