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Direct determination of turbulent burning velocity during aluminum flame propagation: A comparison of three experimental methods 铝火焰传播过程中湍流燃烧速度的直接测定:三种实验方法的比较
IF 3.6 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-11-28 DOI: 10.1016/j.jlp.2024.105512
Clement Chanut , Farès Saad Al Hadidi , Frédéric Heymes , Ernesto Salzano
Burning velocity is a key parameter of main flame propagation models. However, its experimental determination while studying propagating dust flame is still challenging. In this work, aluminum flame propagation in a vertical tube is studied. Two aluminum powders with median diameters of 6.2 and 20.7 μm are analyzed for different equivalence ratios with air. The main objective of this work is to compare the methods commonly used in the literature to determine the burning velocity in the case of propagating flames. One of these methods is based on the estimation of the thermal expansion coefficient. This article focuses first on the estimation of this coefficient and presents the limits of considering the adiabatic flame temperature for its estimation. As detailed in the paper, these methods have some limitations and are therefore compared with an innovative method based on a local direct determination of the burning velocity. This local method is based on the measurement of the unburned flow velocity just ahead of the propagating flame front by Time-Resolved Particle Image Velocimetry (TR-PIV). The methods commonly used in the literature mainly underestimate the burning velocity when compared with the local method. The local method is then used to study the influence of the particle size distribution and the equivalence ratio on the turbulent burning velocity. Firstly, we observe that the turbulent burning velocity increases while the flame is propagating in the vertical tube. Furthermore, the turbulent burning velocity with the 6-μm powder is higher than with the 20-μm powder.
燃烧速度是主要火焰传播模型的关键参数。然而,在研究粉尘火焰传播的同时,其实验测定仍然具有挑战性。本文对铝火焰在垂直管内的传播进行了研究。分析了中径为6.2 μm和20.7 μm的铝粉与空气的不同等效比。这项工作的主要目的是比较文献中常用的方法,以确定在传播火焰的情况下燃烧速度。其中一种方法是基于热膨胀系数的估计。本文首先讨论了该系数的估计,并指出了在估计该系数时考虑绝热火焰温度的局限性。正如文中详述的那样,这些方法有一些局限性,因此与基于局部直接确定燃烧速度的创新方法进行了比较。该局部方法基于时间分辨粒子图像测速技术(TR-PIV)对火焰传播锋面前方未燃烧气流速度的测量。文献中常用的方法与局部法相比,主要低估了燃烧速度。然后采用局部法研究了颗粒尺寸分布和等效比对湍流燃烧速度的影响。首先,我们观察到火焰在垂直管内传播时湍流燃烧速度增大。此外,6 μm粉末的湍流燃烧速度高于20 μm粉末。
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引用次数: 0
Risk assessment of domino effects under fire and explosion accidents in LNG storage tank farms based on Bayesian network 基于贝叶斯网络的液化天然气储罐区火灾爆炸事故多米诺效应风险评估
IF 3.6 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-11-26 DOI: 10.1016/j.jlp.2024.105507
Jianxing Yu , Hongyu Ding , Shibo Wu , Qingze Zeng , Wentao Ma
With the increase of liquefied natural gas (LNG) storage capacity, the number of storage tanks in LNG tank farms increases, which makes the possibility of domino effect higher, so it is important to analyze the risk of domino effect in LNG tank farms. However, the traditional domino effect risk assessment only considers a single accident type, which is not consistent with reality. Therefore, a Bayesian network-based risk assessment method for the domino effect of fire and explosion accidents in LNG storage tank farm is proposed in this study. The method utilizes the Bayesian network approach to model the propagation of domino accidents and calculate the failure probability of domino effects under fire and explosion accidents. The most likely sequence of accidents and the critical tank in the LNG storage tank farm can also be defined through the Bayesian network inference. Finally, the reliability of the proposed method is proved by a real case. Compared with only considering a single accident type, mixed accident types lead to a more reasonable result in the domino effect probabilistic analysis. It is believed that the developed approach has great theoretical significance for domino accident prevention and control in LNG storage tank farms.
随着液化天然气(LNG)储量的增加,LNG 储罐区的储罐数量也随之增加,发生多米诺骨牌效应的可能性也随之增大,因此分析 LNG 储罐区的多米诺骨牌效应风险具有重要意义。然而,传统的多米诺骨牌效应风险评估只考虑了单一的事故类型,与实际情况不符。因此,本研究提出了一种基于贝叶斯网络的 LNG 储罐区火灾爆炸事故多米诺骨牌效应风险评估方法。该方法利用贝叶斯网络方法建立多米诺骨牌事故传播模型,并计算火灾和爆炸事故下多米诺骨牌效应的失效概率。通过贝叶斯网络推理,还可确定 LNG 储罐区最可能发生的事故顺序和关键储罐。最后,通过实际案例证明了所提方法的可靠性。与只考虑单一事故类型相比,混合事故类型在多米诺效应概率分析中得出的结果更为合理。相信所提出的方法对 LNG 储罐区的多米诺事故防控具有重要的理论意义。
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引用次数: 0
Learning from incidents in petrochemical companies in Brazil 从巴西石化公司发生的事故中吸取教训
IF 3.6 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-11-22 DOI: 10.1016/j.jlp.2024.105501
Anastacio Pinto Goncalves Filho , Fernanda de Cássia Borges Freitas , Manoel Rivelino Gomes de Oliveira , Adonias Magdiel Silva Ferreira
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引用次数: 0
Risk assessment of flammable liquid transportation on waterways: An ontology-driven dynamic Bayesian network approach 水路易燃液体运输风险评估:本体驱动的动态贝叶斯网络方法
IF 3.6 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-11-22 DOI: 10.1016/j.jlp.2024.105504
Fan Zhang , Xinrong Pu , Xi Huang , Yuanqiao Wen , Junyu Liu , Zhongyi Sui
Accidents involving the transportation of flammable liquids on waterways often lead to severe consequences, highlighting the importance of effective risk assessment under conditions of uncertainty. This paper presents a novel methodology for evaluating the risk associated with the spatiotemporal evolution of flammable liquid transportation on waterways. By leveraging ontology models and dynamic Bayesian networks, the approach involves analyzing factors that impact risk, constructing a standardized knowledge representation model, and mapping this onto a dynamic Bayesian network for comprehensive risk assessment. The methodology incorporates fuzzy theory and the Best-Worst Method to calculate probabilities within the Bayesian framework, enabling detailed analysis of factor impacts on transportation risk. A practical application is illustrated through the development of a dynamic risk evaluation model for octane transportation in the Yangtze River, demonstrating the model's capability to predict risk under varying conditions. This ontology-driven Bayesian network model provides a robust foundation for making informed management decisions in the transportation of flammable liquids, effectively addressing the challenges of semantic expression and inferencing under uncertainty to enhance safety in waterway transportation.
涉及水路易燃液体运输的事故往往会导致严重后果,这凸显了在不确定条件下进行有效风险评估的重要性。本文介绍了一种新型方法,用于评估与水路易燃液体运输时空演变相关的风险。通过利用本体模型和动态贝叶斯网络,该方法涉及分析影响风险的因素、构建标准化知识表示模型,以及将其映射到动态贝叶斯网络以进行综合风险评估。该方法结合了模糊理论和最佳-最差法,在贝叶斯框架内计算概率,从而能够详细分析各种因素对运输风险的影响。通过开发长江辛烷运输动态风险评估模型,展示了该模型在不同条件下预测风险的能力,并对实际应用进行了说明。本体驱动的贝叶斯网络模型为易燃液体运输的明智管理决策奠定了坚实的基础,有效地解决了语义表达和不确定性下的推理难题,从而提高了水路运输的安全性。
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引用次数: 0
An emergency linkage system of urban gas pipeline network based on Bayesian network 基于贝叶斯网络的城市燃气管网应急联动系统
IF 3.6 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-11-17 DOI: 10.1016/j.jlp.2024.105493
Shi-yi Li , Zong-hou Huang , Fan-liang Ge , Wei-dong Lin , Fu-qiang Yang
The occurrence of urban gas pipeline network accidents will pose a great threat to people's lives and property. To protect the lives and property of urban residents and ensure the normal operation of the city, this paper studied the influencing factors of urban gas pipeline network accidents. Firstly, the influencing factors of urban gas pipeline network accidents were summarized and the corresponding fishbone diagram was constructed following the data from the U.S. Department of Transportation Pipeline and Hazardous Materials Safety Administration. Secondly, based on the determined accident number model, the corresponding Bayesian network model was constructed to calculate the state probability and the sensitivity value. Finally, according to the relevant information of urban gas pipeline network management, combined with the numerical results of priori probability and sensitivity, an emergency linkage system based on the urban gas pipeline network was constructed. The calculation results of state probability and the sensitivity analysis indicate that corrosion is the most influential factor contributing to accidents in the urban gas pipeline network. The temperature change has the greatest influence on the occurrence of urban gas pipeline network accidents. Special attention should be paid to the prevention and management of these two aspects of the emergency linkage system. Besides, in order to verify the effectiveness of the system, this paper also uses AHP to evaluate the application of the system. This study aims to provide valuable insights for enhancing the safety management of urban gas pipeline networks, thereby elevating their safety management standards.
城市燃气管网事故的发生将对人民生命财产安全造成极大威胁。为了保护城市居民的生命财产安全,保障城市的正常运行,本文对城市燃气管网事故的影响因素进行了研究。首先,根据美国运输部管道和危险品安全管理局的数据,总结了城市燃气管网事故的影响因素,并构建了相应的鱼骨图。其次,根据确定的事故数量模型,构建相应的贝叶斯网络模型,计算状态概率和灵敏度值。最后,根据城市燃气管网管理的相关信息,结合先验概率和灵敏度的数值结果,构建了基于城市燃气管网的应急联动系统。状态概率的计算结果和敏感性分析表明,腐蚀是城市燃气管网事故的最大影响因素。温度变化对城市燃气管网事故发生的影响最大。在应急联动系统中应特别注意这两方面的预防和管理。此外,为了验证系统的有效性,本文还利用 AHP 对系统的应用进行了评估。本研究旨在为加强城市燃气管网的安全管理提供有价值的见解,从而提升城市燃气管网的安全管理水平。
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引用次数: 0
Investigations on different distribution systems for dusts inside the 20L-sphere 对 20L 球内不同粉尘分布系统的研究
IF 3.6 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-11-15 DOI: 10.1016/j.jlp.2024.105492
Stefan H. Spitzer , Adrián Pandal , Manuel Velasco Rodríguez , Martin Schmidt , Enrico Danzi , Olivier Dufaud , Bretislav Janovsky
The determination of several safety characteristics for dusts requires the dispersion of it in air. This is normally conducted using two vessels, one with an overpressure holding the dust and dispersing it into the second one, where the explosion takes place, through a nozzle. This procedure has the disadvantage that some dusts cannot be conveyed through the nozzle properly. Another disadvantage is that the pressure balancing between the two vessels depends on the dust loading and especially for heavy dusts and high loadings the initial pressure inside the explosion vessel might be reduced.
Flocky dusts or dusts that might be dangerous to convey through a thin nozzle with an overpressure (nanopowders, zirconium) are also difficult to test according to the extisting standards andmay not be tested with the standard nozzles, that are so far used for the determination of safety characteristics. One very recent example, testing nitrocellulose, raised the question, whether some dusts even pose a risk being distributed and pressed through a nozzle for the testing device and, in worst case, for the operator.
Previous researchers have developed alternative types of nozzles for specific types of dust, but provide limited evaluation of their performance relative to standard nozzles. Additionally researchers have not provided sufficient geometry so that they can be reproduced by others. One alternative nozzle for the dispersion of flocky or coarse dusts is stated in the ISO standard but not described there either.
This article investigates four types of nozzles: The two standard ones that are widely used already, an alternative type, that got introduced into the international standard in 2016 but is still seldomly used and one that was constructed to overcome some of the observed disadvantages. The injection curves are compared with and without dust loadings as well as the explosion characteristics. Eventually, a suggestion is given for different types of dusts.
要确定粉尘的若干安全特性,需要将其分散在空气中。通常使用两个容器,一个超压容器容纳粉尘,并通过喷嘴将粉尘分散到第二个容器中,在第二个容器中发生爆炸。这种方法的缺点是有些粉尘无法正常通过喷嘴。另一个缺点是,两个容器之间的压力平衡取决于粉尘的装载量,特别是对于重粉尘和高装载量,爆炸容器内的初始压力可能会降低。絮状粉尘或通过超压薄喷嘴输送可能有危险的粉尘(纳米粉体、锆)也很难根据现有标准进行测试,并且可能无法使用标准喷嘴进行测试,这些喷嘴目前用于确定安全特性。最近的一个测试硝化纤维素的例子提出了这样一个问题,即某些粉尘通过喷嘴的分布和挤压是否会对测试设备造成危险,在最坏的情况下,是否会对操作者造成危险。此外,研究人员也没有提供足够的几何形状,以便其他人可以复制。ISO 标准中提到了一种用于分散絮状或粗粒粉尘的替代喷嘴,但也没有对其进行描述:本文研究了四种类型的喷嘴:两种已被广泛使用的标准喷嘴、一种在 2016 年被引入国际标准但仍很少使用的替代类型喷嘴,以及一种为克服一些观察到的缺点而设计的喷嘴。比较了有粉尘负载和无粉尘负载时的喷射曲线以及爆炸特性。最后,针对不同类型的粉尘提出了建议。
{"title":"Investigations on different distribution systems for dusts inside the 20L-sphere","authors":"Stefan H. Spitzer ,&nbsp;Adrián Pandal ,&nbsp;Manuel Velasco Rodríguez ,&nbsp;Martin Schmidt ,&nbsp;Enrico Danzi ,&nbsp;Olivier Dufaud ,&nbsp;Bretislav Janovsky","doi":"10.1016/j.jlp.2024.105492","DOIUrl":"10.1016/j.jlp.2024.105492","url":null,"abstract":"<div><div>The determination of several safety characteristics for dusts requires the dispersion of it in air. This is normally conducted using two vessels, one with an overpressure holding the dust and dispersing it into the second one, where the explosion takes place, through a nozzle. This procedure has the disadvantage that some dusts cannot be conveyed through the nozzle properly. Another disadvantage is that the pressure balancing between the two vessels depends on the dust loading and especially for heavy dusts and high loadings the initial pressure inside the explosion vessel might be reduced.</div><div>Flocky dusts or dusts that might be dangerous to convey through a thin nozzle with an overpressure (nanopowders, zirconium) are also difficult to test according to the extisting standards andmay not be tested with the standard nozzles, that are so far used for the determination of safety characteristics. One very recent example, testing nitrocellulose, raised the question, whether some dusts even pose a risk being distributed and pressed through a nozzle for the testing device and, in worst case, for the operator.</div><div>Previous researchers have developed alternative types of nozzles for specific types of dust, but provide limited evaluation of their performance relative to standard nozzles. Additionally researchers have not provided sufficient geometry so that they can be reproduced by others. One alternative nozzle for the dispersion of flocky or coarse dusts is stated in the ISO standard but not described there either.</div><div>This article investigates four types of nozzles: The two standard ones that are widely used already, an alternative type, that got introduced into the international standard in 2016 but is still seldomly used and one that was constructed to overcome some of the observed disadvantages. The injection curves are compared with and without dust loadings as well as the explosion characteristics. Eventually, a suggestion is given for different types of dusts.</div></div>","PeriodicalId":16291,"journal":{"name":"Journal of Loss Prevention in The Process Industries","volume":"92 ","pages":"Article 105492"},"PeriodicalIF":3.6,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142661591","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Consequence of high-pressure CO2 pipeline failure: Full-scale burst test and numerical simulation 高压二氧化碳管道故障的后果:全尺寸爆裂试验和数值模拟
IF 3.6 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-11-13 DOI: 10.1016/j.jlp.2024.105489
Jun Wang , He Li , Hui Feng , Xiong Liu , Cheng Lu
Carbon Capture and Storage (CCS) is a widely acknowledged technique for mitigating global warming. High-pressure pipelines emerge as the most efficient and economical means to transport Carbon Dioxide (CO2) from source to storage sites. Given the hazardous nature of CO2 and the potential for catastrophic consequences in an unplanned release, ensuring safe operation of CO2 pipelines is paramount. This necessitates a comprehensive understanding of the potential consequences of CO2 pipeline failures. This paper presents experimental measurements of CO2 dispersion profiles following a full-scale burst test, simulating a real-world CO2 pipeline failure scenario. The experimental setup comprised an 82.7 m buried pipeline test section with a diameter of 324 mm, connected at both ends to 60 m reservoirs. The rupture of the pipeline was initiated at the middle of the test section using an explosive charge. Measurements were carried out for the transient downwind CO2 concentrations and temperatures following the explosive release. Computational Fluid Dynamics (CFD) models employing proposed numerical methods were used to simulate the experimental scenario. The performance of these methods was validated through comparisons with experimental measurements. The validated numerical methods were then employed to predict consequence distances for full-scale CO2 pipeline failures in real-world scenarios.
碳捕集与封存(CCS)是一项广受认可的减缓全球变暖的技术。高压管道是将二氧化碳(CO2)从源头输送到储存地点的最高效、最经济的手段。鉴于二氧化碳的危险性以及意外泄漏可能造成的灾难性后果,确保二氧化碳管道的安全运行至关重要。这就需要全面了解二氧化碳管道故障的潜在后果。本文介绍了模拟真实世界二氧化碳管道故障情景的全尺寸爆裂试验后二氧化碳扩散剖面的实验测量结果。实验装置包括一个 82.7 米长、直径为 324 毫米的埋地管道试验段,两端与 60 米长的储气罐相连。使用炸药在试验段的中间位置引爆管道破裂。对爆炸释放后瞬时下风二氧化碳浓度和温度进行了测量。计算流体动力学 (CFD) 模型采用了建议的数值方法来模拟实验场景。通过与实验测量结果进行比较,验证了这些方法的性能。经过验证的数值方法随后被用于预测真实世界场景中全规模二氧化碳管道故障的后果距离。
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引用次数: 0
Quantitative risk analysis of domino effect and natech accidents triggered by flood in liquor storage tank farms 白酒储罐区洪水引发多米诺效应和耐特奇事故的定量风险分析
IF 3.6 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-11-13 DOI: 10.1016/j.jlp.2024.105490
Jiajun Zou , Tianming Ma , Yuan He , Hong Zhao , Yanyu Chu , Dongyao Zhang , Chuyuan Huang
Damage to atmospheric storage tanks from flooding may lead to severe natural-technological (Natech) accidents. In addition, subjected to escalation vectors such as thermal radiation or overpressure, neighboring tanks may fail and even cause new fire and explosion accidents, known as domino accidents. In this study, a new procedure is developed to quantify the risk of flood-induced Natech accidents on storage tanks by incorporating the potential domino effect into the same quantitative risk assessment (QRA) framework. The computational fluid dynamics (CFD) simulation of the flow velocity field by numerical software effectively corrected the flood loads imposed on the storage tanks at different locations. The developed whole-process procedure was applied in a liquor storage tank farm. The propagation rule of domino effects for a single primary accident storage tank versus multiple primary accident storage tanks were discussed separately in the case study. The results showed that the scenario with two storage tanks as primary accidents required less cascades and a shorter time to end the domino propagation than a single storage tank. Moreover, in all scenarios discussed, the accident risk indices with domino effects considered were always higher than when it was not.
洪水对常压储罐的破坏可能导致严重的自然-技术(Natech)事故。此外,受到热辐射或超压等升级矢量的影响,相邻储罐可能会发生故障,甚至引发新的火灾和爆炸事故,即多米诺骨牌事故。本研究开发了一种新程序,通过将潜在的多米诺效应纳入同一定量风险评估(QRA)框架,量化洪水引发的储罐 Natech 事故风险。通过数值软件对流速场进行计算流体动力学(CFD)模拟,有效修正了不同位置储罐所承受的洪水负荷。开发的全过程程序被应用于一个白酒储罐区。案例研究分别讨论了单个一级事故储罐与多个一级事故储罐的多米诺效应传播规律。结果表明,与单个储罐相比,两个储罐作为主要事故储罐的情况下所需的级联更少,结束多米诺骨牌传播的时间更短。此外,在讨论的所有方案中,考虑多米诺效应的事故风险指数总是高于不考虑多米诺效应的方案。
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引用次数: 0
Synergistic inhibition characteristics and kinetics of hydrogen explosion by two-phase suppressant N2-KHCO3 两相抑制剂 N2-KHCO3 对氢气爆炸的协同抑制特性和动力学作用
IF 3.6 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-11-13 DOI: 10.1016/j.jlp.2024.105487
Jiao Qu , Rong Wang , Jun Deng , Zhenmin Luo , Fangming Cheng , Tao Wang , Ting Zhou , Huali Zhao
Hydrogen energy has a promising future as a novel energy source in the 21st century. Resource exploitation and utilization of hydrogen energy are considered as crucial methods to achieve the medium and long-term goals of carbon peaking and carbon neutrality. However, hydrogen explosions are extremely destructive and can lead to severe consequences, making the effective suppression of hydrogen explosions a focal point in the field of hydrogen safety technology research. In this paper, the research equipment was a 20 L spherical explosion device used to analyze the hydrogen explosion characteristics under the synergistic effect of N2-KHCO3. Based on this, CHEMKIN was utilized to study the kinetic parameters of hydrogen explosion under the influence of suppressants. The results showed that single-phase N2 suppressed hydrogen explosion. With the increase of N2 volume fraction, the explosion pressure decreased. Specifically speaking, 30 vol% N2 reduced the hydrogen explosion pressure by 32.51%. Besides, single-phase KHCO3 had an inhibitory impact, but it had little effect on the reduction of explosion pressure. In the study of synergistic effect, 25 vol% N2 and 750 g/m3 KHCO3 could completely suppress hydrogen explosion, and 30 vol% N2 combined with 250 g/m3 KHCO3 could also completely suppress hydrogen explosion. Therefore, the synergistic effect of N2-KHCO3 in the experiment remarkably inhibited hydrogen explosion. In the study of kinetic parameters in this paper, N2-KHCO3 significantly reduced the formation rate and sensitivity of H and OH, and reduced the explosion temperature sensitivity coefficient. Taken together, the two-phase synergistic effect of N2-KHCO3 effectively reduced the sensitivity and intensity of hydrogen explosion and inhibited the chain reaction of hydrogen explosion. This paper provides the theoretical basis for broadening the direction of potassium salt development. Furthermore, it offered technical guidance for the application of gas-solid two-phase explosion suppression technology. The future research direction is to optimize the type and ratio of two-phase explosion suppressants, achieve the reduction purpose and efficiency of explosion suppressants, and enhance their practical application effect.
氢能作为一种新型能源,在 21 世纪前景广阔。氢能的资源开发和利用被认为是实现中长期碳调峰和碳中和目标的重要方法。然而,氢气爆炸具有极大的破坏性,可导致严重后果,因此有效抑制氢气爆炸成为氢气安全技术研究领域的焦点。本文的研究设备为 20 L 球形爆炸装置,用于分析 N2-KHCO3 协同作用下的氢气爆炸特性。在此基础上,利用 CHEMKIN 研究了抑制剂影响下氢气爆炸的动力学参数。结果表明,单相 N2 可抑制氢气爆炸。随着 N2 体积分数的增加,爆炸压力降低。具体而言,30 vol% 的 N2 可使氢气爆炸压力降低 32.51%。此外,单相 KHCO3 也有抑制作用,但对降低爆炸压力影响不大。在协同效应研究中,25 vol% N2 和 750 g/m3 KHCO3 可完全抑制氢爆,30 vol% N2 与 250 g/m3 KHCO3 结合使用也可完全抑制氢爆。因此,实验中 N2-KHCO3 的协同作用显著抑制了氢气爆炸。在本文的动力学参数研究中,N2-KHCO3 显著降低了 H 和 OH 的形成速率和敏感性,降低了爆炸温度敏感系数。综合来看,N2-KHCO3 的两相协同效应有效降低了氢气爆炸的敏感性和强度,抑制了氢气爆炸的链式反应。本文为拓宽钾盐的发展方向提供了理论依据。此外,还为气固两相抑爆技术的应用提供了技术指导。未来的研究方向是优化两相抑爆剂的种类和配比,实现抑爆剂的减量目的和效率,提高其实际应用效果。
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引用次数: 0
Bunkering reliability index for LNG bunkering operations considering uncertainty 考虑不确定性的液化天然气加注作业可靠性指数
IF 3.6 3区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-11-12 DOI: 10.1016/j.jlp.2024.105485
Antonio Miranda , Ana Sánchez , Isabel Martón , Sebastián Martorell
Liquified Natural Gas (LNG) has recently been used as a new fuel in the maritime sector. Besides the preceptive studies related to the safety in the use of LNG and its consequences on people, infrastructure, and the environment, recent studies have addressed the reliability of bunkering operations. These studies do not include aspects which influence the reliability of the bunkering operation such as the effect of environmental conditions and human behavior as key factors for the reliability of the whole process. This paper presents a reliability model for bunkering operations which includes both effects. A sensitivity and uncertainty analysis of the results obtained is also included. Results and important findings are supported by an application example focused on bunkering truck to ship operation performed in a Spanish port. The results show that BURI is normally high close to 97% but it can decrease to a value close to 25% for adverse environmental conditions or 68% depending on human stress, experience and motivation.
液化天然气(LNG)最近已作为一种新燃料应用于海洋领域。除了与液化天然气的使用安全及其对人员、基础设施和环境的影响有关的前瞻性研究外,最近的研究还涉及加气操作的可靠性。这些研究并不包括影响燃料加注操作可靠性的方面,如环境条件和人类行为对整个过程可靠性的关键因素的影响。本文提出了一个包括这两种影响的加油作业可靠性模型。本文还对所得结果进行了敏感性和不确定性分析。结果和重要发现得到了一个应用实例的支持,该应用实例侧重于在西班牙港口执行的加油车到船操作。结果表明,BURI 通常高达 97%,但在不利的环境条件下,BURI 可降至 25%或 68%,这取决于人的压力、经验和动力。
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引用次数: 0
期刊
Journal of Loss Prevention in The Process Industries
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