Chemical accidents are among the most severe types of industrial incidents, typically triggered by a complex interplay of multiple factors. These factors do not act in isolation; rather, they can initiate a chain reaction, collectively contributing to the occurrence of an accident. Therefore, it is crucial to systematically identify and analyze the dynamic propagation of these factors. This study employs network theory and the cascade failure model to examine the pathways through which causal factors spread in chemical accidents, aiming to deepen the understanding of and develop strategies for prevention. Initially, chemical accident cases were collected and filtered, followed by a statistical analysis of their basic information. Subsequently, a Causal Analysis of Chemical Accidents (CACA) framework was established based on the 24Model, which facilitated the identification of causative factors within accident cases and the construction of a CACA network model. Using various metrics from complex network theory, the importance of causative factors was assessed. Finally, the critical causative factor-accident propagation paths were obtained by analyzing the influence process among factors based on the cascading failure model, which were validated through nine practical cases. The findings reveal that the three most influential factors in the CACA network are operational errors (IA02), physical hazards (IA04), and chemical hazards (IA05). In key propagation pathways, factors such as the primary responsibility for safety (OC02), the degree of leadership accountability (OC05), and the emphasis on safety training (OC08) play major roles. This paper explores the mechanisms of occurrence, key causative factors, and critical propagation pathways in chemical accidents based on case studies, revealing the causes and processes of such accidents. This knowledge can help enterprises learn from incidents, thereby enhancing the safety of their production processes.
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