{"title":"CMAS corrosion resistance of scandia, ceria, yttria-stabilized zirconia ceramic","authors":"Mina Aflaki, Fatemeh Davar","doi":"10.1111/ijac.14808","DOIUrl":null,"url":null,"abstract":"<p>Sc<sub>2</sub>O<sub>3</sub>–CeO<sub>2</sub>–Y<sub>2</sub>O<sub>3</sub>– stabilized zirconia (ScCeYSZ) nanoparticles with different percentages of stabilizer agents [sample1: 1.8 wt.% (Sc<sub>2</sub>O<sub>3</sub>) 8.3 wt.% (CeO<sub>2</sub>) 1.9 wt.% (Y<sub>2</sub>O<sub>3</sub>), sample 2: 1.1 wt.% (Sc<sub>2</sub>O<sub>3</sub>) 9.0 wt.% (CeO<sub>2</sub>) 1.9 wt.% (Y<sub>2</sub>O<sub>3</sub>), sample 3: .5 wt.% (Sc<sub>2</sub>O<sub>3</sub>) 9.6 wt.% (CeO<sub>2</sub>) 1.9 wt.% (Y<sub>2</sub>O<sub>3</sub>) stabilized zirconia] were synthesized with Pechini method and consolidated by spark plasma sintered method. The results showed that despite the [(sample)<sub>1</sub>: 1.8 wt.% (Sc<sub>2</sub>O<sub>3</sub>) 8.3 wt.% (CeO<sub>2</sub>) 1.9 wt.% (Y<sub>2</sub>O<sub>3</sub>)] had lower density and higher porosity percentage compared to other samples, it had better calcium–magnesium–alumina–silicate (CMAS) corrosion resistance compared to other samples and the yttria-stabilized zirconia nanopowders (nano-YSZ) sample. It was due to the higher acidic nature and tetragonality of the (sample)<sub>1</sub> sintered body compared to other samples and YSZ ceramic in the CMAS corrosive medium. Moreover, the results of phase and microstructural analysis following CMAS corrosion revealed the formation of the monoclinic phase and rod-shaped CaAl<sub>2</sub>Si<sub>2</sub>O<sub>8</sub> particles on the surface of the sampled sintered sample. However, the nano-YSZ sample corroded homogenously and delamination occurred after the CMAS corrosion test.</p>","PeriodicalId":13903,"journal":{"name":"International Journal of Applied Ceramic Technology","volume":"21 5","pages":"3590-3600"},"PeriodicalIF":1.8000,"publicationDate":"2024-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Applied Ceramic Technology","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1111/ijac.14808","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
引用次数: 0
Abstract
Sc2O3–CeO2–Y2O3– stabilized zirconia (ScCeYSZ) nanoparticles with different percentages of stabilizer agents [sample1: 1.8 wt.% (Sc2O3) 8.3 wt.% (CeO2) 1.9 wt.% (Y2O3), sample 2: 1.1 wt.% (Sc2O3) 9.0 wt.% (CeO2) 1.9 wt.% (Y2O3), sample 3: .5 wt.% (Sc2O3) 9.6 wt.% (CeO2) 1.9 wt.% (Y2O3) stabilized zirconia] were synthesized with Pechini method and consolidated by spark plasma sintered method. The results showed that despite the [(sample)1: 1.8 wt.% (Sc2O3) 8.3 wt.% (CeO2) 1.9 wt.% (Y2O3)] had lower density and higher porosity percentage compared to other samples, it had better calcium–magnesium–alumina–silicate (CMAS) corrosion resistance compared to other samples and the yttria-stabilized zirconia nanopowders (nano-YSZ) sample. It was due to the higher acidic nature and tetragonality of the (sample)1 sintered body compared to other samples and YSZ ceramic in the CMAS corrosive medium. Moreover, the results of phase and microstructural analysis following CMAS corrosion revealed the formation of the monoclinic phase and rod-shaped CaAl2Si2O8 particles on the surface of the sampled sintered sample. However, the nano-YSZ sample corroded homogenously and delamination occurred after the CMAS corrosion test.
期刊介绍:
The International Journal of Applied Ceramic Technology publishes cutting edge applied research and development work focused on commercialization of engineered ceramics, products and processes. The publication also explores the barriers to commercialization, design and testing, environmental health issues, international standardization activities, databases, and cost models. Designed to get high quality information to end-users quickly, the peer process is led by an editorial board of experts from industry, government, and universities. Each issue focuses on a high-interest, high-impact topic plus includes a range of papers detailing applications of ceramics. Papers on all aspects of applied ceramics are welcome including those in the following areas:
Nanotechnology applications;
Ceramic Armor;
Ceramic and Technology for Energy Applications (e.g., Fuel Cells, Batteries, Solar, Thermoelectric, and HT Superconductors);
Ceramic Matrix Composites;
Functional Materials;
Thermal and Environmental Barrier Coatings;
Bioceramic Applications;
Green Manufacturing;
Ceramic Processing;
Glass Technology;
Fiber optics;
Ceramics in Environmental Applications;
Ceramics in Electronic, Photonic and Magnetic Applications;