Microstructures and mechanical properties of TiAl joint brazed with Ti-Mn-Fe-Ni-Zr system medium-entropy filler alloy

IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Welding in the World Pub Date : 2024-05-25 DOI:10.1007/s40194-024-01785-7
Zhiliang Zhai, Xinyu Ren, Yonglai Shang, Yaoyong Cheng, Haishui Ren, Huaping Xiong, Yongjuan Jing
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Abstract

A five-element medium-entropy filler alloy with composition of Ti-(18 ~ 24)Mn-(12 ~ 18)Fe-(3 ~ 8)Ni-(3 ~ 8)Zr (wt.%) was proposed for vacuum brazing of TiAl-based alloy. The filler alloy was mainly composed of Ti-based solid solution and Ti-(Fe, Mn) compound dissolved with elements of Ni and Zr. The filler alloy ingot was ground into powder and then the filler powder was preset into the V-shaped groove butt joint with a gap of 50 μm. The Ti-Mn-Fe-Ni-Zr brazing alloy showed the liquidus temperature of 1060.1 °C, and also presented excellent wettability on TiAl substrate at 1110 °C for 10 min. The brazed joint mainly consisted of γ-TiAl, α2-Ti3Al, and residual brazing filler reaction phase. The brazing condition of 1210 °C/45 min exhibited the maximum joint thickness of 308 μm and the maximum area percentage of γ-TiAl phase of 33.77%, with almost elimination of residual brazing filler reaction phase within the joint, and meanwhile offered the maximum room-temperature tensile strength of 418 MPa, 70.85% of the base alloy. The joint fracture showed a mixed mode of intergranular and transgranular fracture.

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用 Ti-Mn-Fe-Ni-Zr 系中熵填充合金钎焊的 TiAl 接头的微观结构和力学性能
提出了一种用于 TiAl 基合金真空钎焊的五元素中熵填充合金,其成分为 Ti-(18 ~ 24)Mn-(12 ~ 18)Fe-(3 ~ 8)Ni-(3 ~ 8)Zr (重量百分比)。填充合金主要由 Ti 基固溶体和溶解有 Ni 和 Zr 元素的 Ti-(Fe、Mn)化合物组成。将填料合金铸锭研磨成粉末,然后将填料粉末预置到间隙为 50 μm 的 V 形凹槽对接接头中。钛-锰-铁-镍-锆钎焊合金的液相温度为 1060.1 °C,在 1110 °C、10 分钟的温度条件下,在钛铝基底上呈现出极佳的润湿性。钎焊接头主要由 γ-TiAl、α2-Ti3Al 和残余钎料反应相组成。在 1210 °C/45 min 的钎焊条件下,接头的最大厚度为 308 μm,γ-TiAl 相的最大面积百分比为 33.77%,接头内残余的钎焊填料反应相几乎消失,同时室温抗拉强度最大为 418 MPa,是基合金的 70.85%。接头断裂表现出晶间断裂和跨晶断裂的混合模式。
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来源期刊
Welding in the World
Welding in the World METALLURGY & METALLURGICAL ENGINEERING-
CiteScore
4.20
自引率
14.30%
发文量
181
审稿时长
6-12 weeks
期刊介绍: The journal Welding in the World publishes authoritative papers on every aspect of materials joining, including welding, brazing, soldering, cutting, thermal spraying and allied joining and fabrication techniques.
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