首页 > 最新文献

Welding in the World最新文献

英文 中文
Feasibility study on machine learning methods for prediction of process-related parameters during WAAM process using SS-316L filler material 使用 SS-316L 填充材料在 WAAM 工艺中预测工艺相关参数的机器学习方法的可行性研究
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-10-31 DOI: 10.1007/s40194-024-01855-w
Sharath P. Subadra, Eduard Mayer, Philipp Wachtel, Shahram Sheikhi

The geometry of objects by means of wire arc additive manufacturing technology (WAAM) is a function of the quality of the deposited layers. The process parameters variation and heat flow affect the geometric precision of the parts, when compared to the actual dimensions. Therefore, in situ geometry monitoring which is integrated in such a way to enable a backward control model is essential in the WAAM process. In this article, an attempt is made to study the effect of four input variables, namely voltage (U), welding current (I), travel speed and wire feed rate on the output function in the form of two geometrical characteristics of a single weld bead. These output functions which are determinant of the weld quality are width of weld bead (BW) and height of weld bead (BH). A machine learning approach is utilised to predict the bead dimensions based on the input parameters and to predict the parameters by assigning suitable scores. For predicting the bead dimensions, two models, namely linear regression and random forest, shall be utilised, whereas for the purpose of classification based on weld parameters, k-nearest neighbours model shall be employed. Through this work, a wide dataset of parameters in the form of input variable and output in the form bead dimensions are generated for 316LSi filler material which shall be used as a training data for a machine learning algorithm. Subsequently, the predicted parameters shall be cross-checked with actual parameters.

利用线弧快速成型技术(WAAM)制造的物体的几何形状是沉积层质量的函数。与实际尺寸相比,工艺参数变化和热流会影响零件的几何精度。因此,在 WAAM 工艺中,必须对原位几何形状进行监控,并将其集成到后向控制模型中。本文尝试研究四个输入变量,即电压 (U)、焊接电流 (I)、移动速度和送丝速率对单个焊珠两个几何特征输出函数的影响。这些决定焊接质量的输出函数是焊缝宽度 (BW) 和焊缝高度 (BH)。利用机器学习方法可根据输入参数预测焊缝尺寸,并通过分配合适的分数来预测参数。在预测焊缝尺寸时,将使用线性回归和随机森林两种模型,而在根据焊接参数进行分类时,将使用 k 近邻模型。通过这项工作,为 316LSi 填充材料生成了一个输入变量形式的参数和输出形式的焊缝尺寸的广泛数据集,该数据集将用作机器学习算法的训练数据。随后,预测参数将与实际参数进行交叉检验。
{"title":"Feasibility study on machine learning methods for prediction of process-related parameters during WAAM process using SS-316L filler material","authors":"Sharath P. Subadra,&nbsp;Eduard Mayer,&nbsp;Philipp Wachtel,&nbsp;Shahram Sheikhi","doi":"10.1007/s40194-024-01855-w","DOIUrl":"10.1007/s40194-024-01855-w","url":null,"abstract":"<div><p>The geometry of objects by means of wire arc additive manufacturing technology (WAAM) is a function of the quality of the deposited layers. The process parameters variation and heat flow affect the geometric precision of the parts, when compared to the actual dimensions. Therefore, in situ geometry monitoring which is integrated in such a way to enable a backward control model is essential in the WAAM process. In this article, an attempt is made to study the effect of four input variables, namely voltage (U), welding current (I), travel speed and wire feed rate on the output function in the form of two geometrical characteristics of a single weld bead. These output functions which are determinant of the weld quality are width of weld bead (BW) and height of weld bead (BH). A machine learning approach is utilised to predict the bead dimensions based on the input parameters and to predict the parameters by assigning suitable scores. For predicting the bead dimensions, two models, namely linear regression and random forest, shall be utilised, whereas for the purpose of classification based on weld parameters, k-nearest neighbours model shall be employed. Through this work, a wide dataset of parameters in the form of input variable and output in the form bead dimensions are generated for 316LSi filler material which shall be used as a training data for a machine learning algorithm. Subsequently, the predicted parameters shall be cross-checked with actual parameters.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"68 12","pages":"3205 - 3214"},"PeriodicalIF":2.4,"publicationDate":"2024-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40194-024-01855-w.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142645683","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Publisher Correction: Novel approach for in-line process monitoring during ultrasonic metal welding of dissimilar wire/terminal joints based on the thermoelectric effect 出版商更正:基于热电效应的异种线材/端子接头超声波金属焊接在线过程监控新方法
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-10-30 DOI: 10.1007/s40194-024-01860-z
Andreas Gester, Toni Sprigode, Guntram Wagner
{"title":"Publisher Correction: Novel approach for in-line process monitoring during ultrasonic metal welding of dissimilar wire/terminal joints based on the thermoelectric effect","authors":"Andreas Gester,&nbsp;Toni Sprigode,&nbsp;Guntram Wagner","doi":"10.1007/s40194-024-01860-z","DOIUrl":"10.1007/s40194-024-01860-z","url":null,"abstract":"","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"68 12","pages":"3235 - 3236"},"PeriodicalIF":2.4,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40194-024-01860-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142645704","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Life cycle assessment in additive manufacturing of copper alloys—comparison between laser and electron beam 铜合金增材制造的生命周期评估--激光和电子束的比较
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-10-23 DOI: 10.1007/s40194-024-01856-9
Julius Raute, Alexander Beret, Max Biegler, Michael Rethmeier

Additive manufacturing is becoming increasingly important for industrial production. In this context, directed energy deposition processes are in demand to achieve high deposition rates. In addition to the well-known laser-based processes, the electron beam has also reached industrial market maturity. The wire electron beam additive manufacturing offers advantages in the processing of copper materials, for example. In the literature, the higher energy efficiency and the resulting improvement in the carbon footprint of the electron beam are highlighted. However, there is a lack of practical studies with measurement data to quantify the potential of the technology. In this work, a comparative life cycle assessment between wire electron beam additive manufacturing (DED-EB) and laser powder additive manufacturing (DED-LB) is carried out. This involves determining the resources for manufacturing, producing a test component using both processes, and measuring the entire energy consumption. The environmental impact is then estimated using the factors global warming potential (GWP100), photochemical ozone creation potential (POCP), acidification potential (AP), and eutrophication potential (EP). It can be seen that wire electron beam additive manufacturing is characterized by a significantly lower energy requirement. In addition, the use of wire ensures greater resource efficiency, which leads to overall better life cycle assessment results.

快速成型制造在工业生产中的重要性与日俱增。在此背景下,为实现高沉积率,定向能沉积工艺备受青睐。除了众所周知的激光工艺外,电子束也已在工业市场上成熟起来。例如,线状电子束增材制造在铜材料加工方面具有优势。文献中强调了电子束更高的能效以及由此带来的碳足迹的改善。然而,目前还缺乏具有测量数据的实际研究来量化该技术的潜力。在这项工作中,对线材电子束增材制造(DED-EB)和激光粉末增材制造(DED-LB)进行了生命周期比较评估。这包括确定制造资源、使用两种工艺生产测试组件以及测量整个能耗。然后使用全球升温潜能值 (GWP100)、光化学臭氧生成潜能值 (POCP)、酸化潜能值 (AP) 和富营养化潜能值 (EP) 对环境影响进行估算。可以看出,线材电子束增材制造的特点是能耗要求低得多。此外,线材的使用可确保更高的资源效率,从而获得更好的整体生命周期评估结果。
{"title":"Life cycle assessment in additive manufacturing of copper alloys—comparison between laser and electron beam","authors":"Julius Raute,&nbsp;Alexander Beret,&nbsp;Max Biegler,&nbsp;Michael Rethmeier","doi":"10.1007/s40194-024-01856-9","DOIUrl":"10.1007/s40194-024-01856-9","url":null,"abstract":"<div><p>Additive manufacturing is becoming increasingly important for industrial production. In this context, directed energy deposition processes are in demand to achieve high deposition rates. In addition to the well-known laser-based processes, the electron beam has also reached industrial market maturity. The wire electron beam additive manufacturing offers advantages in the processing of copper materials, for example. In the literature, the higher energy efficiency and the resulting improvement in the carbon footprint of the electron beam are highlighted. However, there is a lack of practical studies with measurement data to quantify the potential of the technology. In this work, a comparative life cycle assessment between wire electron beam additive manufacturing (DED-EB) and laser powder additive manufacturing (DED-LB) is carried out. This involves determining the resources for manufacturing, producing a test component using both processes, and measuring the entire energy consumption. The environmental impact is then estimated using the factors global warming potential (GWP100), photochemical ozone creation potential (POCP), acidification potential (AP), and eutrophication potential (EP). It can be seen that wire electron beam additive manufacturing is characterized by a significantly lower energy requirement. In addition, the use of wire ensures greater resource efficiency, which leads to overall better life cycle assessment results.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"68 12","pages":"3169 - 3176"},"PeriodicalIF":2.4,"publicationDate":"2024-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40194-024-01856-9.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142645644","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Cr addition on microstructure, mechanical properties, and corrosion behavior of weld metal in weathering steel of high-speed train bogie 添加铬对高速列车转向架耐候钢焊缝金属的微观结构、机械性能和腐蚀行为的影响
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-10-17 DOI: 10.1007/s40194-024-01848-9
Gaojian Wang, Dandan Kang, Yanhong Ye, Dean Deng

The effects of Cr addition on the microstructure, mechanical properties, and corrosion behavior of two weld metals containing Ti or Mo within the Ni-Cu alloys used in high-speed train bogies were investigated. The results show that Cr can increase the acicular ferrite (AF) by about 15%, reduce the primary ferrite (PF) and the ferrite with second phase aligned (FSP), and slightly increase the M-A constituents in the weld containing Ti. Cr addition scarcely alters the AF, leads to a decline in PF and an increase in FSP, and causes a substantial increase in M-A constituents from 0.4 to 2.5% in the as-welded zone containing Mo. Meanwhile, it was found that Cr addition negatively affects weld toughness in the weld containing Mo due to the increase in the proportion and size of M-A constituents and the coarsening of inclusions. Regarding the corrosion resistance, Cr addition can promote the absorption of Cr on the surface of inclusions. This is the main reason for the reduction of the initial corrosion rate of the weld containing Mo, while this effect is attenuated in the welds containing Ti. In addition, Cr addition can densify the inner and outer rust layers, thereby reducing the corrosion rate of the welding rust layer.

研究了高速列车转向架使用的 Ni-Cu 合金中添加铬对含有 Ti 或 Mo 的两种焊接金属的微观结构、机械性能和腐蚀行为的影响。结果表明,在含 Ti 的焊缝中,铬能使针状铁素体 (AF) 增加约 15%,减少原生铁素体 (PF) 和第二相排列的铁素体 (FSP),并略微增加 M-A 成分。添加铬几乎不会改变 AF,但会导致 PF 下降和 FSP 增加,并使含 Mo 的焊缝区中的 M-A 成分从 0.4% 大幅增加到 2.5%。同时还发现,由于 M-A 成分比例和尺寸的增加以及夹杂物的粗化,铬的添加对含 Mo 焊缝的焊接韧性产生了负面影响。在耐腐蚀性方面,铬的添加会促进夹杂物表面对铬的吸收。这是含 Mo 的焊缝初始腐蚀速率降低的主要原因,而这种影响在含 Ti 的焊缝中有所减弱。此外,添加 Cr 还能使内外锈层致密化,从而降低焊接锈层的腐蚀速率。
{"title":"Effect of Cr addition on microstructure, mechanical properties, and corrosion behavior of weld metal in weathering steel of high-speed train bogie","authors":"Gaojian Wang,&nbsp;Dandan Kang,&nbsp;Yanhong Ye,&nbsp;Dean Deng","doi":"10.1007/s40194-024-01848-9","DOIUrl":"10.1007/s40194-024-01848-9","url":null,"abstract":"<div><p>The effects of Cr addition on the microstructure, mechanical properties, and corrosion behavior of two weld metals containing Ti or Mo within the Ni-Cu alloys used in high-speed train bogies were investigated. The results show that Cr can increase the acicular ferrite (AF) by about 15%, reduce the primary ferrite (PF) and the ferrite with second phase aligned (FSP), and slightly increase the M-A constituents in the weld containing Ti. Cr addition scarcely alters the AF, leads to a decline in PF and an increase in FSP, and causes a substantial increase in M-A constituents from 0.4 to 2.5% in the as-welded zone containing Mo. Meanwhile, it was found that Cr addition negatively affects weld toughness in the weld containing Mo due to the increase in the proportion and size of M-A constituents and the coarsening of inclusions. Regarding the corrosion resistance, Cr addition can promote the absorption of Cr on the surface of inclusions. This is the main reason for the reduction of the initial corrosion rate of the weld containing Mo, while this effect is attenuated in the welds containing Ti. In addition, Cr addition can densify the inner and outer rust layers, thereby reducing the corrosion rate of the welding rust layer.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"68 12","pages":"3115 - 3128"},"PeriodicalIF":2.4,"publicationDate":"2024-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142645408","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of travel speed on porosity and liquation cracking in cold wire pulsed gas metal arc welding of aa7075-t651 aluminum alloy 行进速度对 aa7075-t651 铝合金冷丝脉冲气体金属弧焊中气孔和液化裂纹的影响
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-10-08 DOI: 10.1007/s40194-024-01844-z
A. A. C. Filho, C. R. L. Loayza, P. D. C. Assunção, E. M. Braga

This study investigates the impact of travel speed on the weld quality of AA7075-T651 aluminum alloy using the cold wire pulsed gas metal arc welding (CW-PGMAW) process. By maintaining a constant heat input of 0.4 kJ/mm while varying travel speed between 90 and 100 cm/min, the study examines the process’s influence on microstructure, porosity, and liquation cracking. Results demonstrate that CW-PGMAW effectively refines microstructure and reduces defect formation compared to conventional GMAW. While mechanical properties showed improvement, further optimization is necessary to achieve base metal equivalent properties. The findings contribute to the understanding of CW-PGMAW for challenging aluminum alloys and provide a foundation for future process enhancements.

Graphical Abstract

本研究探讨了冷丝脉冲气体金属弧焊(CW-PGMAW)工艺的行进速度对 AA7075-T651 铝合金焊接质量的影响。通过保持 0.4 kJ/mm 的恒定热输入,同时在 90 厘米/分钟和 100 厘米/分钟之间改变移动速度,该研究考察了该工艺对微观结构、气孔和液化裂纹的影响。结果表明,与传统的 GMAW 相比,CW-PGMAW 能有效细化微观结构并减少缺陷的形成。虽然机械性能有所改善,但仍需进一步优化才能达到与基体金属相当的性能。这些研究结果有助于理解 CW-PGMAW 如何用于具有挑战性的铝合金,并为未来的工艺改进奠定了基础。
{"title":"Influence of travel speed on porosity and liquation cracking in cold wire pulsed gas metal arc welding of aa7075-t651 aluminum alloy","authors":"A. A. C. Filho,&nbsp;C. R. L. Loayza,&nbsp;P. D. C. Assunção,&nbsp;E. M. Braga","doi":"10.1007/s40194-024-01844-z","DOIUrl":"10.1007/s40194-024-01844-z","url":null,"abstract":"<div><p>This study investigates the impact of travel speed on the weld quality of AA7075-T651 aluminum alloy using the cold wire pulsed gas metal arc welding (CW-PGMAW) process. By maintaining a constant heat input of 0.4 kJ/mm while varying travel speed between 90 and 100 cm/min, the study examines the process’s influence on microstructure, porosity, and liquation cracking. Results demonstrate that CW-PGMAW effectively refines microstructure and reduces defect formation compared to conventional GMAW. While mechanical properties showed improvement, further optimization is necessary to achieve base metal equivalent properties. The findings contribute to the understanding of CW-PGMAW for challenging aluminum alloys and provide a foundation for future process enhancements.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"68 12","pages":"3099 - 3113"},"PeriodicalIF":2.4,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142645603","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microstructure and properties of additive manufacturing by gas-shielded arc welding with hydrogen-resistant steel wires 用耐氢钢焊丝通过气体保护电弧焊进行增材制造的微观结构和性能
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-10-07 DOI: 10.1007/s40194-024-01835-0
Guo Chun, Zhang XinYu, Li WenQing, Li Yun, Chen YanYan, Huang GuangCan, Lin QingCheng

The hydrogen steel gas-shielded welding wire was utilized in the WAAM technique, and the microstructure, crystal structure, and properties of the parts generated by layer-wise deposition were analyzed and evaluated. The study revealed that the components exhibit good quality, devoid of significant defects, and demonstrate robust internal metallurgical bonding. The metallographic structure mainly consists of pearlite and ferrite. The distribution of microhardness in the parts is fairly consistent, with mean microhardness values of 196.6 HV0.1 (transverse) and 196.7 HV0.1 (longitudinal). The parts exhibit exceptional mechanical properties, with a transverse yield strength of 406 MPa, an elongation rate of 14.2%, and a longitudinal yield strength of 380 MPa, an elongation rate of 18.9%. At − 30 °C, the average transverse Charpy impact value is 95.7 J, and the average longitudinal is 117 J.

在 WAAM 技术中使用了氢钢气体保护焊丝,并对分层沉积生成的部件的微观结构、晶体结构和性能进行了分析和评估。研究结果表明,部件质量良好,无明显缺陷,内部冶金结合牢固。金相结构主要由珠光体和铁素体组成。部件的显微硬度分布相当一致,平均显微硬度值为 196.6 HV0.1(横向)和 196.7 HV0.1(纵向)。零件具有优异的机械性能,横向屈服强度为 406 兆帕,伸长率为 14.2%,纵向屈服强度为 380 兆帕,伸长率为 18.9%。在零下 30 °C,平均横向夏比冲击值为 95.7 J,平均纵向为 117 J。
{"title":"Microstructure and properties of additive manufacturing by gas-shielded arc welding with hydrogen-resistant steel wires","authors":"Guo Chun,&nbsp;Zhang XinYu,&nbsp;Li WenQing,&nbsp;Li Yun,&nbsp;Chen YanYan,&nbsp;Huang GuangCan,&nbsp;Lin QingCheng","doi":"10.1007/s40194-024-01835-0","DOIUrl":"10.1007/s40194-024-01835-0","url":null,"abstract":"<div><p>The hydrogen steel gas-shielded welding wire was utilized in the WAAM technique, and the microstructure, crystal structure, and properties of the parts generated by layer-wise deposition were analyzed and evaluated. The study revealed that the components exhibit good quality, devoid of significant defects, and demonstrate robust internal metallurgical bonding. The metallographic structure mainly consists of pearlite and ferrite. The distribution of microhardness in the parts is fairly consistent, with mean microhardness values of 196.6 HV<sub>0.1</sub> (transverse) and 196.7 HV<sub>0.1</sub> (longitudinal). The parts exhibit exceptional mechanical properties, with a transverse yield strength of 406 MPa, an elongation rate of 14.2%, and a longitudinal yield strength of 380 MPa, an elongation rate of 18.9%. At − 30 °C, the average transverse Charpy impact value is 95.7 J, and the average longitudinal is 117 J.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"68 12","pages":"3085 - 3097"},"PeriodicalIF":2.4,"publicationDate":"2024-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142645720","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A comprehensive study on laser welding of stainless steel 301LN in lap joint configuration 搭接结构不锈钢 301LN 激光焊接综合研究
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-10-01 DOI: 10.1007/s40194-024-01840-3
Thierry Adrien, Shayan Dehghan, Asim Iltaf, Noureddine Barka

Laser welding offers distinct advantages over traditional methods: less heat impact, no filler metal needed, and strong weld penetration. It is efficient and cost-effective, perfect for joining materials like the stainless steel 301LN, and ideal for industries addressing climate change. This study delves into the impact of various operating parameters on weld quality, specifically focusing on microstructure and microhardness. Using the Taguchi method, it is designed an experimental setup to systematically analyze these factors. The microstructure analysis shows a unique grain structure in the weld bead and a small heat-affected zone (HAZ), indicating precise welding control. Weld penetration measurements correlated with specific operating parameters using microstructure imaging. The microhardness analysis further underlined the control over HAZ thickness, crucial for ensuring the integrity of the welded joint. Through analysis of variance (ANOVA), it is identified significant factors affecting physical properties, help to construct a mathematical model to quantify parameter influences accurately. Findings suggest that minimizing the focal spot diameter is key to optimizing weld penetration, albeit in a delicate balance with welding speed and laser power settings. Adjusting these parameters can also influence the chemical composition match between the weld bead and base material, crucial for structural integrity. For achieving the desired hardness close to the base material, specific parameter ranges are recommended: a beam oscillation amplitude of 1.45 mm, a beam oscillation amplitude between 2.82 and 2.97 kW, and a focal spot diameter above 0.34 mm. Findings offer practical insights for improving weld quality and efficiency in industrial applications.

与传统方法相比,激光焊接具有明显的优势:热影响小,无需填充金属,焊接穿透力强。它效率高、成本低,是连接不锈钢 301LN 等材料的理想选择,也是应对气候变化的行业的理想选择。本研究深入探讨了各种操作参数对焊接质量的影响,特别是对微观结构和显微硬度的影响。采用田口方法设计了一个实验装置,对这些因素进行系统分析。微观结构分析表明,焊缝的晶粒结构独特,热影响区(HAZ)较小,表明焊接控制精确。通过微观结构成像,焊接熔透测量结果与特定的操作参数相关联。显微硬度分析进一步强调了对热影响区厚度的控制,这对确保焊接接头的完整性至关重要。通过方差分析(ANOVA),确定了影响物理性质的重要因素,有助于构建数学模型,准确量化参数影响因素。研究结果表明,尽管要与焊接速度和激光功率设置保持微妙的平衡,但尽量减小焦斑直径是优化焊接渗透的关键。调整这些参数还能影响焊缝和母材之间的化学成分匹配,这对结构完整性至关重要。为达到接近母材的理想硬度,建议采用特定的参数范围:光束振幅为 1.45 毫米,光束振幅在 2.82 至 2.97 千瓦之间,焦斑直径大于 0.34 毫米。研究结果为提高工业应用中的焊接质量和效率提供了实用见解。
{"title":"A comprehensive study on laser welding of stainless steel 301LN in lap joint configuration","authors":"Thierry Adrien,&nbsp;Shayan Dehghan,&nbsp;Asim Iltaf,&nbsp;Noureddine Barka","doi":"10.1007/s40194-024-01840-3","DOIUrl":"10.1007/s40194-024-01840-3","url":null,"abstract":"<div><p>Laser welding offers distinct advantages over traditional methods: less heat impact, no filler metal needed, and strong weld penetration. It is efficient and cost-effective, perfect for joining materials like the stainless steel 301LN, and ideal for industries addressing climate change. This study delves into the impact of various operating parameters on weld quality, specifically focusing on microstructure and microhardness. Using the Taguchi method, it is designed an experimental setup to systematically analyze these factors. The microstructure analysis shows a unique grain structure in the weld bead and a small heat-affected zone (HAZ), indicating precise welding control. Weld penetration measurements correlated with specific operating parameters using microstructure imaging. The microhardness analysis further underlined the control over HAZ thickness, crucial for ensuring the integrity of the welded joint. Through analysis of variance (ANOVA), it is identified significant factors affecting physical properties, help to construct a mathematical model to quantify parameter influences accurately. Findings suggest that minimizing the focal spot diameter is key to optimizing weld penetration, albeit in a delicate balance with welding speed and laser power settings. Adjusting these parameters can also influence the chemical composition match between the weld bead and base material, crucial for structural integrity. For achieving the desired hardness close to the base material, specific parameter ranges are recommended: a beam oscillation amplitude of 1.45 mm, a beam oscillation amplitude between 2.82 and 2.97 kW, and a focal spot diameter above 0.34 mm. Findings offer practical insights for improving weld quality and efficiency in industrial applications.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"68 12","pages":"3141 - 3168"},"PeriodicalIF":2.4,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142645409","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Monitoring the gas metal arc additive manufacturing process using unsupervised machine learning 利用无监督机器学习监控气体金属弧快速成型制造过程
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-09-23 DOI: 10.1007/s40194-024-01836-z
Giulio Mattera, Joseph Polden, John Norrish

The study aimed to assess the performance of several unsupervised machine learning (ML) techniques in online anomaly (The term “anomaly” is used here to indicate a departure from expected process behavior which may indicate a quality issue which requires further investigation. The term “defect detection” has often been used previously but the specific imperfection is often indirectly inferred.) detection during surface tension transfer (STT)-based wire arc additive manufacturing. Recent advancements in quality monitoring for wire arc manufacturing were reviewed, followed by a comparison of unsupervised ML techniques using welding current and welding voltage data collected during a defect-free deposition process. Both time domain and frequency domain feature extraction techniques were applied and compared. Three analysis methodologies were adopted: ML algorithms such as isolation forest, local outlier factor, and one-class support vector machine. The results highlight that incorporating frequency analysis, such as fast Fourier transform (FFT) and discrete wavelet transform (DWT), for feature extraction based on general frequency response and defined bandwidth frequency response, significantly improves performance, reflected in a 14% increase in F2 score, compared with time-domain features extraction. Additionally, a deep learning approach employing a convolutional autoencoder (CAE) demonstrated superior performance by processing time-frequency domain data stored as spectrograms obtained through short-time Fourier transform (STFT) analysis. The CAE method outperformed frequency domain analysis and traditional ML approaches, achieving an additional 5% improvement in F2-score. Notably, the F2-score (The F2 score is the weighted harmonic mean of the precision and recall (given a threshold value). Unlike the F1 score, which gives equal weight to precision and recall, the F2 score gives more weight to recall than to precision.) increased significantly from 0.78 in time domain analysis to 0.895 in time-frequency analysis. The study emphasizes the potential of utilizing low-cost sensors to develop anomaly detection modules with enhanced accuracy. These findings underscore the importance of incorporating advanced data processing techniques in wire arc additive manufacturing for improved quality control and process optimization.

该研究旨在评估几种无监督机器学习(ML)技术在在线异常(此处使用的术语 "异常 "表示与预期工艺行为的偏离,可能预示着需要进一步调查的质量问题。在基于表面张力传递(STT)的线弧增材制造过程中,"缺陷检测 "一词以前经常被使用,但具体的缺陷往往是间接推断出来的。在回顾了线弧制造质量监控的最新进展后,利用在无缺陷沉积过程中收集到的焊接电流和焊接电压数据,对无监督 ML 技术进行了比较。应用并比较了时域和频域特征提取技术。采用了三种分析方法:ML 算法,如隔离林、局部离群因子和单类支持向量机。结果表明,与时域特征提取相比,结合频率分析(如快速傅立叶变换(FFT)和离散小波变换(DWT))进行基于一般频率响应和定义带宽频率响应的特征提取,可显著提高性能,体现为 F2 分数提高了 14%。此外,一种采用卷积自动编码器(CAE)的深度学习方法通过处理以频谱图形式存储的时频域数据(通过短时傅里叶变换(STFT)分析获得),也表现出了卓越的性能。CAE 方法的性能优于频域分析和传统的 ML 方法,使 F2 分数提高了 5%。值得注意的是,F2 分数(F2 分数是精确度和召回率(给定阈值)的加权谐波平均值。与精确度和召回率权重相等的 F1 分数不同,F2 分数对召回率的权重高于精确度。)从时域分析中的 0.78 显著提高到时频分析中的 0.895。这项研究强调了利用低成本传感器开发具有更高精度的异常检测模块的潜力。这些发现强调了在线弧快速成型制造中采用先进数据处理技术以改进质量控制和流程优化的重要性。
{"title":"Monitoring the gas metal arc additive manufacturing process using unsupervised machine learning","authors":"Giulio Mattera,&nbsp;Joseph Polden,&nbsp;John Norrish","doi":"10.1007/s40194-024-01836-z","DOIUrl":"10.1007/s40194-024-01836-z","url":null,"abstract":"<div><p>The study aimed to assess the performance of several unsupervised machine learning (ML) techniques in online anomaly (The term “anomaly” is used here to indicate a departure from expected process behavior which may indicate a quality issue which requires further investigation. The term “defect detection” has often been used previously but the specific imperfection is often indirectly inferred.) detection during surface tension transfer (STT)-based wire arc additive manufacturing. Recent advancements in quality monitoring for wire arc manufacturing were reviewed, followed by a comparison of unsupervised ML techniques using welding current and welding voltage data collected during a defect-free deposition process. Both time domain and frequency domain feature extraction techniques were applied and compared. Three analysis methodologies were adopted: ML algorithms such as isolation forest, local outlier factor, and one-class support vector machine. The results highlight that incorporating frequency analysis, such as fast Fourier transform (FFT) and discrete wavelet transform (DWT), for feature extraction based on general frequency response and defined bandwidth frequency response, significantly improves performance, reflected in a 14% increase in F2 score, compared with time-domain features extraction. Additionally, a deep learning approach employing a convolutional autoencoder (CAE) demonstrated superior performance by processing time-frequency domain data stored as spectrograms obtained through short-time Fourier transform (STFT) analysis. The CAE method outperformed frequency domain analysis and traditional ML approaches, achieving an additional 5% improvement in F2-score. Notably, the F2-score (The F2 score is the weighted harmonic mean of the precision and recall (given a threshold value). Unlike the F1 score, which gives equal weight to precision and recall, the F2 score gives more weight to recall than to precision.) increased significantly from 0.78 in time domain analysis to 0.895 in time-frequency analysis. The study emphasizes the potential of utilizing low-cost sensors to develop anomaly detection modules with enhanced accuracy. These findings underscore the importance of incorporating advanced data processing techniques in wire arc additive manufacturing for improved quality control and process optimization.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"68 11","pages":"2853 - 2867"},"PeriodicalIF":2.4,"publicationDate":"2024-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40194-024-01836-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142438768","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of holding time on microstructure evolution and properties of T2Cu/Al1060 diffusion bonding layer 保温时间对 T2Cu/Al1060 扩散接合层微观结构演变和性能的影响
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-09-23 DOI: 10.1007/s40194-024-01838-x
Yunlong Ding, Wenjie Shao, Zhiguo Zhuang, Bingyang Liu, Bing Han

In this paper, the welding of T2 copper and Al1060 was realized by vacuum diffusion welding process. The microstructure evolution, mechanical properties, and corrosion resistance of Cu/Al diffusion bonding layer were explored. The results show that intermetallic compounds Al2Cu, AlCu, and Al4Cu9 generate at the joint under the welding condition of holding for 60 min at 530 °C. When the holding time reaches 90 min, a new phase of Al2Cu3 generates, and the diffusion bonding layer evolves into a four-layer structure. The thickness of diffusion layer increases with the extension of holding time and is affected by the body diffusion. The shear strength of the joint increases first and then decreases with the extension of holding time. The maximum shear strength of 20.91 MPa can be obtained under the holding time condition of 60 min, and fracture mainly occurs between Al2Cu and AlCu phases. Nanoindentation hardness and elastic modulus of intermetallic compound phase are much higher than those of copper and aluminum matrix. Specifically, Al4Cu9 phase exhibits the largest nanoindentation hardness and elastic modulus of 11.062 GPa and 132.8 GPa. The corrosion resistance of diffusion bonding layers is significantly different from that of the base material. Compared with copper, the corrosion potential of each diffusion layer and aluminum matrix is relatively lower. The corrosion rates of diffusion layers and base materials are in descending order of Al > Al2Cu > AlCu > Al4Cu9 > Cu.

本文采用真空扩散焊接工艺实现了 T2 铜和 Al1060 的焊接。研究了铜/铝扩散结合层的微观结构演变、力学性能和耐腐蚀性能。结果表明,在 530 °C 保温 60 分钟的焊接条件下,接头处会产生金属间化合物 Al2Cu、AlCu 和 Al4Cu9。当保温时间达到 90 分钟时,会产生新的 Al2Cu3 相,扩散结合层演变成四层结构。扩散层的厚度随着保温时间的延长而增加,并受到体扩散的影响。随着保温时间的延长,接头的剪切强度先增大后减小。在保持时间为 60 分钟的条件下,可获得 20.91 MPa 的最大剪切强度,断裂主要发生在 Al2Cu 和 AlCu 相之间。金属间化合物相的纳米压痕硬度和弹性模量远高于铜和铝基体。具体来说,Al4Cu9 相的纳米压痕硬度和弹性模量最大,分别为 11.062 GPa 和 132.8 GPa。扩散结合层的耐腐蚀性与基体材料的耐腐蚀性有很大不同。与铜相比,各扩散层和铝基体的腐蚀电位相对较低。扩散层和基体材料的腐蚀速率从大到小依次为 Al > Al2Cu > AlCu > Al4Cu9 > Cu。
{"title":"Effect of holding time on microstructure evolution and properties of T2Cu/Al1060 diffusion bonding layer","authors":"Yunlong Ding,&nbsp;Wenjie Shao,&nbsp;Zhiguo Zhuang,&nbsp;Bingyang Liu,&nbsp;Bing Han","doi":"10.1007/s40194-024-01838-x","DOIUrl":"10.1007/s40194-024-01838-x","url":null,"abstract":"<div><p>In this paper, the welding of T2 copper and Al1060 was realized by vacuum diffusion welding process. The microstructure evolution, mechanical properties, and corrosion resistance of Cu/Al diffusion bonding layer were explored. The results show that intermetallic compounds Al<sub>2</sub>Cu, AlCu, and Al<sub>4</sub>Cu<sub>9</sub> generate at the joint under the welding condition of holding for 60 min at 530 °C. When the holding time reaches 90 min, a new phase of Al<sub>2</sub>Cu<sub>3</sub> generates, and the diffusion bonding layer evolves into a four-layer structure. The thickness of diffusion layer increases with the extension of holding time and is affected by the body diffusion. The shear strength of the joint increases first and then decreases with the extension of holding time. The maximum shear strength of 20.91 MPa can be obtained under the holding time condition of 60 min, and fracture mainly occurs between Al<sub>2</sub>Cu and AlCu phases. Nanoindentation hardness and elastic modulus of intermetallic compound phase are much higher than those of copper and aluminum matrix. Specifically, Al<sub>4</sub>Cu<sub>9</sub> phase exhibits the largest nanoindentation hardness and elastic modulus of 11.062 GPa and 132.8 GPa. The corrosion resistance of diffusion bonding layers is significantly different from that of the base material. Compared with copper, the corrosion potential of each diffusion layer and aluminum matrix is relatively lower. The corrosion rates of diffusion layers and base materials are in descending order of Al &gt; Al<sub>2</sub>Cu &gt; AlCu &gt; Al<sub>4</sub>Cu<sub>9</sub> &gt; Cu.</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"68 11","pages":"2975 - 2984"},"PeriodicalIF":2.4,"publicationDate":"2024-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142438767","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Linear and cylindrical friction stir additive manufacturing (FSAM) of AA6061-T6 by consumable rods: metallurgical structure, wear, and corrosion properties 用消耗棒对 AA6061-T6 进行直线和圆柱形摩擦搅拌快速成型 (FSAM):冶金结构、磨损和腐蚀特性
IF 2.4 4区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-09-21 DOI: 10.1007/s40194-024-01839-w
Soheil Kiani, Seyyed Ehsan Mirsalehi, Amirhossein Sahraei

In the present research, the possibility of using friction stir deposition (FSD) for the additive manufacturing (AM) of aluminum parts has been evaluated and checked. For this purpose, consumable tool technique was used for depositing bulk samples in the shape of linear and cylindrical parts. The current friction stir additive manufacturing (FSAM) process was carried out through the deposition of AA6061-T6 consumable rods on a substrate of the same material. For each of the linear and cylindrical types, six samples were deposited in three layers using different production parameters. FSD tool speeds including rotational, linear, and vertical were the production parameters. To evaluate the additive manufactured parts, appearance, microstructure, hardness, wear properties, and corrosion resistance were inquired. The apparent appearance characteristics for both linear and cylindrical samples were continuous layers with sufficient thickness without cracks and cavities. In terms of microstructure characteristics, the hot plastic deformation during FSAM caused enormous grain refinement (~ 560%) through the dynamic recrystallization and decreasing the precipitate size (~ 31%) by the dissolution of precipitates in the matrix, compared with the AA6061-T6 consumable rods. These microstructural changes and production parameters were correlated with the amount of frictional heat generated during the process. In order to find this correlation, the change in amount of heat input by changing the production parameters and its effect on the microstructural characteristics were discussed. For both linear/cylindrical samples, by increasing the consumable tool rotational speed and decreasing its linear/vertical speed (increase in deposition time), the heat input increased, which led to more dissolution of precipitates (decreasing their size) and grain growth (reduction of grain boundaries as the preferred precipitation sites). Decreasing the precipitate size and precipitate content reduced the three-body wear mechanism and lowered the corrosion prone areas, which improved the wear and corrosion properties, respectively. Although the dissolution of precipitates reduced the hardness of samples compared to the hardness of consumable rods (AA6061-T6), the enormous grain refinement caused by FSAM compensated this deficiency. Finally, the properties of additive manufactured parts are as follows: relatively good hardness (~ 60 HV), excellent wear rate (about 3 µgr/N.m), low friction coefficient (0.6–0.8), and excellent corrosion rate (less than 5 mpy).

在本研究中,对使用摩擦搅拌沉积(FSD)进行铝零件增材制造(AM)的可能性进行了评估和检查。为此,使用了消耗性工具技术来沉积线形和圆柱形零件的块状样品。当前的摩擦搅拌增材制造(FSAM)工艺是通过在相同材料的基底上沉积 AA6061-T6 耗材棒来实现的。对于每种线性和圆柱形类型,均使用不同的生产参数在三层中沉积了六个样品。生产参数包括 FSD 工具的旋转、线性和垂直速度。为了评估添加剂制造的零件,对其外观、微观结构、硬度、磨损性能和耐腐蚀性进行了调查。线形和圆柱形样品的外观特征均为厚度足够的连续层,无裂纹和空洞。在微观结构特征方面,与 AA6061-T6 焊条相比,FSAM 过程中的热塑性变形通过动态再结晶使晶粒细化(约 560%),并通过析出物在基体中的溶解使析出物尺寸减小(约 31%)。这些微观结构变化和生产参数与加工过程中产生的摩擦热量有关。为了找到这种相关性,我们讨论了通过改变生产参数来改变输入热量及其对微观结构特征的影响。对于线性/圆柱形样品,通过提高耗材工具的旋转速度和降低其线性/垂直速度(增加沉积时间),输入的热量增加,从而导致更多沉淀物溶解(减小其尺寸)和晶粒生长(减少作为首选沉淀点的晶界)。析出物尺寸和析出物含量的减小减少了三体磨损机制,降低了易腐蚀区域,从而分别改善了磨损和腐蚀特性。虽然与易耗棒材(AA6061-T6)的硬度相比,析出物的溶解降低了样品的硬度,但 FSAM 带来的巨大晶粒细化弥补了这一不足。最后,添加剂制造零件的特性如下:相对较好的硬度(约 60 HV)、出色的磨损率(约 3 µgr/N.m)、较低的摩擦系数(0.6-0.8)和出色的腐蚀率(小于 5 mpy)。
{"title":"Linear and cylindrical friction stir additive manufacturing (FSAM) of AA6061-T6 by consumable rods: metallurgical structure, wear, and corrosion properties","authors":"Soheil Kiani,&nbsp;Seyyed Ehsan Mirsalehi,&nbsp;Amirhossein Sahraei","doi":"10.1007/s40194-024-01839-w","DOIUrl":"10.1007/s40194-024-01839-w","url":null,"abstract":"<div><p>In the present research, the possibility of using friction stir deposition (FSD) for the additive manufacturing (AM) of aluminum parts has been evaluated and checked. For this purpose, consumable tool technique was used for depositing bulk samples in the shape of linear and cylindrical parts. The current friction stir additive manufacturing (FSAM) process was carried out through the deposition of AA6061-T6 consumable rods on a substrate of the same material. For each of the linear and cylindrical types, six samples were deposited in three layers using different production parameters. FSD tool speeds including rotational, linear, and vertical were the production parameters. To evaluate the additive manufactured parts, appearance, microstructure, hardness, wear properties, and corrosion resistance were inquired. The apparent appearance characteristics for both linear and cylindrical samples were continuous layers with sufficient thickness without cracks and cavities. In terms of microstructure characteristics, the hot plastic deformation during FSAM caused enormous grain refinement (~ 560%) through the dynamic recrystallization and decreasing the precipitate size (~ 31%) by the dissolution of precipitates in the matrix, compared with the AA6061-T6 consumable rods. These microstructural changes and production parameters were correlated with the amount of frictional heat generated during the process. In order to find this correlation, the change in amount of heat input by changing the production parameters and its effect on the microstructural characteristics were discussed. For both linear/cylindrical samples, by increasing the consumable tool rotational speed and decreasing its linear/vertical speed (increase in deposition time), the heat input increased, which led to more dissolution of precipitates (decreasing their size) and grain growth (reduction of grain boundaries as the preferred precipitation sites). Decreasing the precipitate size and precipitate content reduced the three-body wear mechanism and lowered the corrosion prone areas, which improved the wear and corrosion properties, respectively. Although the dissolution of precipitates reduced the hardness of samples compared to the hardness of consumable rods (AA6061-T6), the enormous grain refinement caused by FSAM compensated this deficiency. Finally, the properties of additive manufactured parts are as follows: relatively good hardness (~ 60 HV), excellent wear rate (about 3 µgr/N.m), low friction coefficient (0.6–0.8), and excellent corrosion rate (less than 5 mpy).</p></div>","PeriodicalId":809,"journal":{"name":"Welding in the World","volume":"68 11","pages":"2869 - 2889"},"PeriodicalIF":2.4,"publicationDate":"2024-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142438691","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Welding in the World
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1