Effects of incident heat flux on heat release rates and temperatures in cone calorimeter tests of polyurethane foam

IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Fire and Materials Pub Date : 2024-05-29 DOI:10.1002/fam.3224
Obiora Ugo-Okeke, David Torvi
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Abstract

There is great interest in developing methods to predict full-scale fire performance of mattresses and upholstered furniture for design and regulatory purposes using cone calorimeter and other small-scale test results. One method used in the past is a model developed during the European Combustion Behavior of Upholstered Furniture (CBUF) project. To support the further development of this model, cone calorimeter tests of polyurethane (PU) foam specimens 5–10 cm thick were conducted using incident heat fluxes between 5 and 35 kW/m2. Temperatures were measured using thermocouples located on the surface and at four depths within 10 cm thick foam specimens to determine the effects of heat flux on heat transfer and foam degradation. Peak and average heat release rate (HRR) values for a particular thickness of foam increased with an increase in heat flux. An increase in heat flux decreased the times to reach the two peaks in the HRR curve, which represent the collapse of foam and burning of liquid products, as well as burning duration. Heat flux had a larger effect on the second HRR peak than the first peak. Significant temperature gradients were initially confined to the top portion of the foam. A surface temperature of 150–200°C was shown to be indicative of the onset of ignition, while a temperature of 150°C at a particular location was indicative of when temperatures began to more rapidly increase at deeper locations within the foam. Infrared video records were also used to examine three-dimensional burning behavior of the foam.

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入射热通量对聚氨酯泡沫锥形量热计测试中热释放率和温度的影响
人们对利用锥形量热计和其他小规模测试结果来预测床垫和软垫家具的全尺寸防火性能的方法非常感兴趣,以便进行设计和监管。过去使用的一种方法是欧洲软垫家具燃烧行为(CBUF)项目开发的模型。为了支持该模型的进一步开发,使用 5 至 35 kW/m2 的入射热通量对 5-10 厘米厚的聚氨酯(PU)泡沫试样进行了锥形量热计测试。使用位于 10 厘米厚泡沫试样表面和四个深度的热电偶测量温度,以确定热通量对传热和泡沫降解的影响。特定厚度泡沫的峰值和平均放热率(HRR)值随着热通量的增加而增加。热通量的增加缩短了达到 HRR 曲线中两个峰值(代表泡沫坍塌和液体产物燃烧)的时间,也缩短了燃烧持续时间。与第一个峰值相比,热通量对第二个 HRR 峰值的影响更大。显著的温度梯度最初仅限于泡沫的顶部。150-200°C 的表面温度表明开始点火,而特定位置 150°C 的温度则表明泡沫内部较深位置的温度开始快速上升。红外线视频记录也用于检查泡沫的三维燃烧行为。
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来源期刊
Fire and Materials
Fire and Materials 工程技术-材料科学:综合
CiteScore
4.60
自引率
5.30%
发文量
72
审稿时长
3 months
期刊介绍: Fire and Materials is an international journal for scientific and technological communications directed at the fire properties of materials and the products into which they are made. This covers all aspects of the polymer field and the end uses where polymers find application; the important developments in the fields of natural products - wood and cellulosics; non-polymeric materials - metals and ceramics; as well as the chemistry and industrial applications of fire retardant chemicals. Contributions will be particularly welcomed on heat release; properties of combustion products - smoke opacity, toxicity and corrosivity; modelling and testing.
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Issue Information Issue Information Analyzing thermal-moisture comfort and thermal protective performance of phase change materials dripped protective clothing Effect of silane coupling agent on mechanical properties, flame retardancy, and ceramifiable behavior of ceramifiable flame-retardant silicone rubber composite Enhancing fire safety and thermal performance: Wood composites with bio-based phase change materials and fire retardants for building applications
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