Recycling of waste crushed stone powder for alkali-activated material production

IF 2.7 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Journal of Material Cycles and Waste Management Pub Date : 2024-05-30 DOI:10.1007/s10163-024-01973-z
Zhuguo Li, Gökhan Kaplan
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Abstract

The growing use of crushed stone and manufactured sand poses a major challenge to the recycling of their by-product known as crushed stone powder (CSP). To establish an effective recycling method for CSP, the authors conducted a detailed investigation on the setting, strength, and durability of alkali-activated materials (AAMs) with slag (GGBFS) and CSP as precursors, and examined their chemical and microstructural characteristics by X-ray diffraction (XRD) and scanning electron microscope (SEM) analysis. Experimental results clarified in detail the performance features and influencing factors of AAM made from a blend of CSP and slag, and indicated that CSP can be utilized as an inactive precursor in a large blending ratio (50–80%) to produce AAMs with high strength and excellent durability. The GGBFS/CSP-based AAMs have high flexural strength, reaching up to 1/5 ~ 1/6 of the compressive strength, surpassing 15.0 MPa. The AAMs using CSP almost retain the crystals from CSP within them, and the presence of CSP particles fragments C-A-S-H gels of polymerization reaction product, making them granular and discontinuous. Compared to the siliceous CSP, the limestone CSP slightly enhanced the strength properties of AAM.

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回收利用废碎石粉生产碱活性材料
碎石和人造砂的使用量不断增加,这对其副产品碎石粉(CSP)的回收利用提出了重大挑战。为了建立一种有效的 CSP 回收方法,作者对以矿渣(GGBFS)和 CSP 为前体的碱活性材料(AAM)的凝结、强度和耐久性进行了详细研究,并通过 X 射线衍射(XRD)和扫描电子显微镜(SEM)分析检查了它们的化学和微观结构特征。实验结果详细阐明了由 CSP 和矿渣混合制成的 AAM 的性能特征和影响因素,并表明 CSP 可作为非活性前驱体以较大的混合比例(50%-80%)用于生产具有高强度和优异耐久性的 AAM。基于 GGBFS/CSP 的 AAMs 具有很高的抗折强度,可达到抗压强度的 1/5 ~ 1/6,超过 15.0 兆帕。使用 CSP 的 AAM 几乎保留了 CSP 中的晶体,CSP 颗粒的存在使聚合反应产物的 C-A-S-H 凝胶破碎,使其呈颗粒状且不连续。与硅质 CSP 相比,石灰石 CSP 稍微提高了 AAM 的强度性能。
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来源期刊
CiteScore
5.30
自引率
16.10%
发文量
205
审稿时长
4.8 months
期刊介绍: The Journal of Material Cycles and Waste Management has a twofold focus: research in technical, political, and environmental problems of material cycles and waste management; and information that contributes to the development of an interdisciplinary science of material cycles and waste management. Its aim is to develop solutions and prescriptions for material cycles. The journal publishes original articles, reviews, and invited papers from a wide range of disciplines related to material cycles and waste management. The journal is published in cooperation with the Japan Society of Material Cycles and Waste Management (JSMCWM) and the Korea Society of Waste Management (KSWM).
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