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Evaluation of circular economy practices for management of the reverse chain of electronic waste in Brazil 评估巴西电子废物逆向链管理的循环经济做法
IF 3.1 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-17 DOI: 10.1007/s10163-024-02071-w
Auro J. C. Correia, Geraldo C. de Oliveira Neto, Rosângela A. P. B. Metato, Sidnei A. de Araújo, Marlene Amorim, Vikas Kumar, João Matias

The increasing production of waste electrical and electronic equipment (WEEE) in Brazil is driving the adoption of circular economy (CE) practices related to the management of the WEEE reverse chain. Thus, the adoption of CE becomes essential for strategic management that promotes environmental preservation, and economic and social development. This study, which employed a survey as the research method, aims to evaluate the importance of CE practices related to the management of the WEEE reverse chain in Brazil. To achieve this, we employed the Kruskal–Wallis and Holm-Sidak multiple comparison tests. Based on the obtained results, the most significant practices are related to legislation and regulations, and effective consumer participation. These are followed by practices related to the management of outsourced recycling companies, and the involvement of logistics operators, treatment, and recycling strategies. The least representative practices were simulations and optimization strategies for logistics transportation, collection centers, and recycling centers. This study contributes to managerial practice by suggesting trends related to environmental management practices and material circularity, as well as compliance with the National Solid Waste Policy. For society, the research highlights the need for consumer education regarding the disposal of WEEE, as well as the necessity for governments and companies to collaborate in forming cooperatives.

巴西废弃电气和电子设备(WEEE)的产量不断增加,推动了与废弃电气和电子设备逆向链管理相关的循环经济(CE)实践的采用。因此,采用循环经济对于促进环境保护、经济和社会发展的战略管理至关重要。本研究采用调查作为研究方法,旨在评估与巴西废弃电子电器设备逆向链管理相关的 CE 实践的重要性。为此,我们采用了 Kruskal-Wallis 和 Holm-Sidak 多重比较测试。根据所得结果,最重要的实践与立法和法规以及消费者的有效参与有关。其次是与外包回收公司的管理、物流运营商的参与、处理和回收战略相关的实践。最不具代表性的做法是物流运输、收集中心和回收中心的模拟和优化策略。本研究通过提出与环境管理实践和材料循环性以及遵守国家固体废物政策相关的趋势,为管理实践做出了贡献。对社会而言,研究强调了在废弃电子电气设备处理方面开展消费者教育的必要性,以及政府和企业合作成立合作社的必要性。
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引用次数: 0
Students’ perceptions and inclination towards solid waste segregation for circular economy in Krobo municipalities of Ghana: awareness, willingness and potential determinants 加纳 Krobo 市学生对固体废物分类促进循环经济的看法和倾向:认识、意愿和潜在决定因素
IF 3.1 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-16 DOI: 10.1007/s10163-024-02068-5
Lloyd Larbi, William K. Heve, Richard Amfo-Otu, Ishmael Lente, Gifty Kumi-Amoah, Maxwell Y. Owusu-Twum, Kofi Sekyere Boateng

This study assessed students’ awareness and inclination towards solid waste segregation for recycling and the potential determinants of student’s willingness to participate in waste segregation initiative in the future. The objective was to obtain vital information that can be used in planning for implementation of solid waste segregation for circular economy in schools in the Yilo Krobo and Lower Manya Krobo Municipals in southeastern Ghana. Using semi-structured questionnaire, 1656 students were randomly selected and interviewed across secondary and tertiary schools in the two municipalities for data collection and analysis. Awareness among students about solid waste segregation, including the benefits associated with the practices, was high. Basically, the majority of the students were willing to participate in any solid waste segregation projects in the future if (i) waste bins are located in their classrooms, (ii) clear instruction is indicated on waste bins and/or (iii) students are educated on waste segregation practices. Almost all the students were willing for their schools to pay for collection and recycling of their segregated solid wastes. However, ordinal logistic regression analysis revealed that placing well-labelled waste bins within schools is the most significant determinant to increase students’ willingness to segregate wastes for the intended initiatives.

本研究评估了学生对固体废物分类回收的认识和倾向,以及学生未来是否愿意参与垃圾分类活动的潜在决定因素。研究的目的是获取重要信息,用于规划在加纳东南部的 Yilo Krobo 和 Lower Manya Krobo 市的学校实施固体废物分类以促进循环经济。采用半结构式问卷调查法,在这两个市的中学和大学中随机抽取了 1656 名学生进行访谈,以收集和分析数据。学生们对固体废物分类的认识很高,包括这种做法的好处。基本上,如果(i) 在教室里设置废物箱,(ii) 对废物箱进行明确说明和/或(iii) 对学生进行废物分类教育,大多数学生都愿意在未来参与任何固体废物分类项目。几乎所有学生都愿意让学校支付收集和回收已分类固体废物的费用。然而,序数逻辑回归分析表明,在学校内放置有明确标识的废物箱是提高学生为预期举措进行废物分类意愿的最重要决定因素。
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引用次数: 0
Reaching China’s fertilizer reduction goals through nitrogen and phosphorus recovery: a substance flow analysis case study 通过氮磷回收实现中国化肥减量目标:物质流分析案例研究
IF 3.1 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-16 DOI: 10.1007/s10163-024-02067-6
Julia Santolin, Oliver Christopher Larsen, Albrecht Fritze, Bing Xue, Zheng Yang, Vera Susanne Rotter

Linear agricultural nutrient regimes are the principal cause for perturbation of the geochemical cycles for nitrogen (N) and phosphorus (P) and other planetary boundaries. Nutrient cycles are characterized by high spatial disparity and China is a hotspot due to high fertilizer application rates. Using substance flow analysis, this study identified and quantified nutrient flows from agricultural production to residue management of Huangyan tangerines (Citrus reticulata) and water bamboo (Zizania latifolia) in a case study of Huangyan district (Taizhou City, Zhejiang province). About 754 Mg/a of N and 105 Mg/a of P can theoretically be recovered in the tangerines and water bamboo systems from currently untapped material flows. This could replace 59% of the N and 15% of the P currently applied as chemical fertilizer, reducing environmental impacts. Combining the nutrient recovery of both systems and upscaling the results to Taizhou City, the goal from the 14th Five-Year Plan for Agricultural and Rural Modernization to save 1182 Mg of nutrients per year could be exceeded by almost 12 times. This study’s data have varying degrees of uncertainty. The analysis of data representativeness shows potential for improvements, especially in the agricultural production of water bamboo and the nutrient contents of material flows.

线性农业养分制度是扰乱氮(N)和磷(P)地球化学循环及其他地球边界的主要原因。养分循环的特点是空间差异大,而中国因化肥施用量高而成为热点地区。本研究以黄岩区(浙江省台州市)为案例,通过物质流分析,确定并量化了黄岩蜜桔和水竹从农业生产到残留管理的养分流。理论上,柑橘和水竹系统中目前尚未开发的物质流可回收约 754 兆克/年的氮和 105 兆克/年的磷。这可以替代目前作为化肥施用的 59% 的氮和 15% 的磷,从而减少对环境的影响。将这两个系统的养分回收结合起来,并将结果推广到台州市,就能实现《农业和农村现代化第十四个五年规划》提出的每年节约养分 1.182 亿克的目标,超额完成近 12 倍。本研究的数据具有不同程度的不确定性。对数据代表性的分析表明,尤其是在水竹的农业生产和物质流的养分含量方面,有改进的潜力。
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引用次数: 0
Study on the mechanisms of retardation of cement hydration by zinc and acceleration of hardening by sodium aluminate from crystallographic phase analysis 从晶相分析研究锌延缓水泥水化和铝酸钠加速硬化的机理
IF 3.1 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-12 DOI: 10.1007/s10163-024-02059-6
Kazuo Yamada, Tsuneki Ichikawa, Hiroyuki Arai, Takahito Yasukochi, Kazuto Endo

Zinc was focused on as an element causing hardening retardation due to delayed hydration of Ordinary Portland Cement (OPC), and its hardening inhibitory effect and the mechanism of hardening enhancement by sodium aluminate were analyzed by X-ray diffraction and scanning electron microscopy/energy dispersive X-ray spectroscopy. The addition of zinc hydroxide retarded hardening at more than 0.3 mass%, as previously reported, and zinc produced calcium zincate hydrates (qatranaite) and inhibited the hydration of tricalcium silicate (C3S), the main component of hydration of OPC. After the zinc had been fully consumed in qatranaite formation, C3S started normal hydration. The addition of sodium aluminate caused earlier re-hydration of C3S, which was inhibited by hydration, as the hydrates produced appeared to consume zincate anions. The rapid setting effect of sodium aluminate addition was also delayed by zinc hydroxide, but it was estimated that the addition of the same amount of zinc would ensure initial strength through early formation of hydrocalumite. In the longer term, strength was considered to be more enhanced by the onset of C3S hydration.

通过 X 射线衍射和扫描电子显微镜/能量色散 X 射线光谱分析了锌的硬化抑制作用和铝酸钠增强硬化的机理。与之前的报道一样,氢氧化锌的添加量超过 0.3 质量%时,会延缓硬化,锌会产生锌酸钙水合物(qatranaite),并抑制 OPC 水化的主要成分硅酸三钙(C3S)的水化。当锌在qatranaite形成过程中消耗殆尽后,C3S开始正常水合。铝酸钠的加入会使 C3S 提前重新水化,而水化会抑制 C3S 的重新水化,因为产生的水合物似乎会消耗锌酸阴离子。氢氧化锌也延迟了铝酸钠的快速凝固效果,但据估计,添加相同数量的锌可通过早期形成氢铝酸盐确保初始强度。从长远来看,C3S 水化的开始更能增强强度。
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引用次数: 0
Poultry litter ash potential as a replacement material in cementitious systems: a state-of-the-art review 禽粪灰作为水泥基系统替代材料的潜力:最新进展综述
IF 3.1 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-11 DOI: 10.1007/s10163-024-02058-7
J. R. Nahuat-Sansores, J. C. Cruz, M. Z. Figueroa-Torres, M. P. Gurrola, C. A. Ramírez-Pinto, K. Garcia-Uitz

Poultry litter (PL) disposal is a major concern for poultry farms around the world, it is estimated that millions of metric tons of this waste are generated globally and as consumption rates increase so does the associated waste; the usual means of disposal include soil fertilization and livestock feeding, however, these disposal strategies are linked with hazardous environmental consequences: eutrophication, ammonia (NH3) emissions and leaching of heavy metals. New environmentally friendly processes have been developed in order to reduce the impact of poultry litter and provide new means of revalorization: proper management and selection, elemental recovery (P, K and N) and its use as biomass for energy generation. One of the most promising revalorization opportunities for this ash residue lies in the development of greener cementitious composites in the pursuit of net-zero energy projects by reducing the carbon footprint of the modified concrete by replacing cement or aggregates, given the typical chemical composition (> 40% CaO) of poultry litter ash (PLA). The present review deals with PLA potential to replace cement or fine aggregates in cementitious composites, how this substitution affects the transport properties of the resultant composite and the effects on strength development and future considerations to be further investigated.

家禽粪便(PL)处理是全球家禽养殖场关注的一个主要问题,据估计,全球产生的家禽粪便达数百万吨,随着消耗量的增加,相关废物也在增加;通常的处理方式包括土壤施肥和牲畜饲养,然而,这些处理策略都会对环境造成危害:富营养化、氨(NH3)排放和重金属浸出。为了减少家禽粪便的影响,人们开发了新的环保工艺,并提供了新的再资源化手段:适当的管理和选择、元素回收(P、K 和 N)以及将其用作生物质能源。鉴于家禽粪便灰烬(PLA)的典型化学成分(CaO 占 40%),这种灰烬残渣最有前景的再利用机会之一在于开发更环保的水泥基复合材料,通过替代水泥或集料来减少改性混凝土的碳足迹,从而实现净零能耗项目。本综述探讨了聚乳酸在水泥基复合材料中替代水泥或细集料的潜力、这种替代如何影响最终复合材料的运输特性、对强度发展的影响以及今后有待进一步研究的问题。
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引用次数: 0
Bottom ash as a solid waste of the palm oil industry turned into a high-value cement replacement for sustainable cement-based materials 作为棕榈油工业固体废物的底灰被转化为高价值水泥替代品,用于生产可持续水泥基材料
IF 3.1 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-11 DOI: 10.1007/s10163-024-02064-9
Kiki Dwi Wulandari, Moh. Najib Rizal, Gati Annisa Hayu, Wahyuniarsih Sutrisno, Priyo Suprobo

Bottom ash needs a pre-treatment process to produce the finer particles until it is like cement material and has a good reactivity as pozzolanic material. This research investigates the effect of using bottom ash on the durability performance of concrete. The modified process was applied to bottom ash to produce finer particles that can improve the durability performances of concrete. The concrete used in this study is self-compacting concrete (SCC) due to its convenience. The bottom ash was pretreated by mechanical grinding before being used as supplementary cement materials (SCM), later called ground bottom ash, and applied from 10% to 50% as the partial replacement by the weight of cement. BA30 showed the highest compressive strength with an increasing percentage of 32% and had a similar value to BA0. The porosity of all mixtures was under 15%. The water absorption of all mixtures was under 10%. BA10, BA20, and BA30 reduced the permeability of the SCC, while BA50 increased the permeability of the SCC. BA30 had the lowest value of RCPT as 916.22 C. The results show that bottom ash positively affects the durability performance of SCC and can be used as an SCM to produce more sustainable cement-based construction materials.

底灰需要经过预处理过程,以产生更细的颗粒,直至其与水泥材料相似,并具有良好的反应活性,可作为一种混合材料。本研究调查了使用底灰对混凝土耐久性能的影响。对底层灰进行了改良处理,以产生更细的颗粒,从而提高混凝土的耐久性能。本研究中使用的混凝土是自密实混凝土(SCC),因为它非常方便。在用作水泥补充材料(SCM)(后称磨细底灰)之前,底灰经过机械研磨预处理,以水泥重量的 10%至 50%作为部分替代物。BA30 的抗压强度最高,抗压强度百分比增加到 32%,与 BA0 相近。所有混合物的孔隙率都低于 15%。所有混合物的吸水率都低于 10%。BA10、BA20 和 BA30 降低了 SCC 的渗透性,而 BA50 增加了 SCC 的渗透性。BA30 的 RCPT 值最低,为 916.22 C。结果表明,底灰对 SCC 的耐久性能有积极影响,可作为一种 SCM 用于生产更具可持续性的水泥基建筑材料。
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引用次数: 0
Sustainability performance indicators: improving waste picker organizations in a Brazilian region 可持续性绩效指标:改善巴西一个地区的拾荒者组织
IF 3.1 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-10 DOI: 10.1007/s10163-024-02065-8
Ricardo César da Silva Guabiroba, Pedro Roberto Jacobi, Gina Rizpah Besen, Marcelino Aurélio Vieira da Silva

In low- and middle-income countries, waste pickers organized in cooperatives and associations face legal, operational, and management challenges. This article proposes a method to assess the performance of waste picker organizations based on sustainability indicators, as well as suggesting relevant measures to improve the formal recycling and solid waste source-separated collection. The method was applied to evaluate ten organizations in a region comprising 12 municipalities in the state of Rio de Janeiro, Brazil. The sustainability indices indicated low performance of the organizations, highlighting the lack of investment resulting in low monthly income for waste pickers, low recovery rates of recyclable waste, and poor working, health and safety conditions. The size of the municipality and existence of a contract between the municipal governments and waste picker organizations were not decisive factors for achieving favorable performance. Additionally, in the study region, there is no evidence that favorable performance of an individual organization leads to higher rate of recyclable waste recovery. However, there is evidence suggesting that it leads to higher income for waste pickers. To improve performance, a set of measures that can support formation of waste picker organizations in Brazil and other countries was proposed and validated through participatory means.

在中低收入国家,以合作社和协会形式组织起来的拾荒者面临着法律、运营和管理方面的挑战。本文提出了一种基于可持续发展指标评估拾荒者组织绩效的方法,并提出了相关措施,以改善正规回收和固体废物源头分类收集。该方法被用于评估巴西里约热内卢州一个由 12 个城市组成的地区中的 10 个组织。可持续性指数表明,这些组织的绩效较低,突出表现为缺乏投资,导致拾荒者月收入低,可回收废物回收率低,工作、健康和安全条件差。城市的规模以及市政府与拾荒者组织之间是否存在合同并不是取得良好绩效的决定性因素。此外,在研究地区,没有证据表明单个组织的良好表现会提高可回收废物的回收率。不过,有证据表明,良好的绩效会提高拾荒者的收入。为了提高绩效,我们提出了一套能够支持在巴西和其他国家成立拾荒者组织的措施,并通过参与式方法进行了验证。
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引用次数: 0
Biofilms on microplastic surfaces and their effect on pollutant adsorption in the aquatic environment 微塑料表面的生物膜及其对水生环境中污染物吸附的影响
IF 3.1 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-10 DOI: 10.1007/s10163-024-02066-7
Yan Qin, Yangping Tu, Congcong Chen, Fang Wang, Yanmei Yang, Ying Hu

The extensive use of plastics has led to the widespread presence of a new type of pollutant called “microplastics (MPs)” in aquatic environments. MPs have large specific surface areas and strong hydrophobicity. In particular, MPs provide a new ecological niche for microorganisms in aquatic environments, which attach to and subsequently form biofilms on microplastic (MP) surfaces. This paper reviews the factors affecting biofilm growth on MP surfaces and the effect of biofilms on the adsorption of other environmental pollutants onto MPs as well as difference analysis. Biofilm formation is influenced by many factors related to the environment, MPs (e.g., type, particle size, and additives), and properties of microorganisms; environmental factors play an especially important role. Crucially, biofilms change the density of MPs and hydrophobicity of the surface of MPs and can attach new functional groups, charged sites, and other additives to MP surfaces. Primarily owing to this, biofilms affect the adsorption of environmental pollutants such as heavy metals, POPs, and pathogenic microorganisms. Notably, such adsorption is affected by MP particle size and additives. In particular, biofilms have a considerable effect on the interactions between MPs and pollutants. Further, this article suggests directions for revealing the influence of biofilms on pollutant adsorption to MPs. This review provides a reference for studying the formation of biofilms on MPs surfaces in aquatic environments and the effect of biofilms on contaminant adsorption onto MPs.

塑料的广泛使用导致水生环境中广泛存在一种新型污染物,即 "微塑料(MPs)"。微塑料具有较大的比表面积和较强的疏水性。尤其是,微塑料为水生环境中的微生物提供了一个新的生态位,这些微生物附着在微塑料(MP)表面并随后形成生物膜。本文综述了影响微塑料表面生物膜生长的因素、生物膜对微塑料吸附其他环境污染物的影响以及差异分析。生物膜的形成受环境、MPs(如类型、粒度和添加剂)和微生物特性等多种因素的影响;其中环境因素的作用尤为重要。最重要的是,生物膜会改变 MP 的密度和 MP 表面的疏水性,并能在 MP 表面附着新的功能基团、带电位点和其他添加剂。主要由于这一点,生物膜会影响重金属、持久性有机污染物和病原微生物等环境污染物的吸附。值得注意的是,这种吸附会受到 MP 颗粒大小和添加剂的影响。特别是,生物膜对 MP 与污染物之间的相互作用有相当大的影响。此外,本文还提出了揭示生物膜对 MPs 吸附污染物的影响的方向。本综述为研究水生环境中 MPs 表面生物膜的形成以及生物膜对 MPs 吸附污染物的影响提供了参考。
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引用次数: 0
Quantification and prediction of solid waste generation based on socio-economical parameters 根据社会经济参数量化和预测固体废物产生量
IF 3.1 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-09 DOI: 10.1007/s10163-024-02046-x
Arun Kumar Patel, Varun Singh Bundela

Rapid scio-economic expansion in Bhopal city, with population growth from 14.35 lakhs in 2001 to 26 lakhs in 2023— roughly twice as much—during this time. If we compare with solid waste generation (SWG) in present and expected increase in years 2001, 2023, and 2035, it is 500 t/d, 800 t/d, and 2735 t/d, respectively, which shows almost three times higher from present generation. This led to the problem of solid waste management due to limited availability resources. This paper gives correlation between development aspects based on life index such as physical quality of life Index and SWG. The present study quantifies the SWG of Bhopal city using the socio-economic data such as per capita income, gross domestic product, physical quality of life index, population, and SWG of Bhopal city that forecast the future status. Abovementioned socio-economical parameters were used for forecast model and for this, multiple linear regression analysis was used for study. Based on the study and after correlation with SWG, it is found that population is in highest correlation than gross domestic production at current price, per capita income at current price, and physical quality of life index, respectively. The high value of R2 is 0.99638 in the models which is near 1. This will help the urban municipal solid waste management bodies to effectively manage solid waste in a sustainable manner.

博帕尔市的科学经济迅速发展,人口从 2001 年的 1435 万增长到 2023 年的 2600 万--大约是 2001 年的两倍。如果将目前的固体废物产生量(SWG)与 2001 年、2023 年和 2035 年的预期增长量进行比较,则分别为 500 吨/天、800 吨/天和 2735 吨/天,几乎是目前产生量的三倍。由于可用资源有限,这导致了固体废物管理问题。本文给出了基于生活指数(如物质生活质量指数)的发展方面与 SWG 之间的相关性。本研究利用博帕尔市的人均收入、国内生产总值、物质生活质量指数、人口等社会经济数据,对博帕尔市的 SWG 进行了量化,并对未来状况进行了预测。上述社会经济参数被用于预测模型,为此研究采用了多元线性回归分析。根据研究并与 SWG 相关后发现,人口分别比按当前价格计算的国内生产总值、按当前价格计算的人均收入和物质生活质量指数的相关性最高。模型的 R2 值为 0.99638,接近 1。这将有助于城市固体废物管理机构以可持续的方式有效管理固体废物。
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引用次数: 0
Recycling and optimization of poultry manure incineration ash as a source of phosphorus and balanced mineral fertilization 回收和优化家禽粪便焚烧灰烬,将其作为磷和平衡矿物质肥料的来源
IF 3.1 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2024-09-09 DOI: 10.1007/s10163-024-02062-x
Aydin Gunes, Selver Kan, Mehmet Burak Taskin, Fatma Gokmen Yilmaz, Kiymet Deniz Yagcioglu, Yusuf Kagan Kadioglu, Hanife Akca, Sait Gezgin

The growing importance of repurposing waste ash from biomass power plants as a fertilizer material is evident. This study systematically investigates the feasibility of employing manure ash obtained from a biomass power plant for applications in fertilizer production. In this study, initially, waste poultry manure ash (PMA) was attempted to be modified by HCl, H2SO4, and HNO3 to enhance the solubility of plant nutrients in its composition. SEM and XRD were used for the molecular and chemical characterization of the ash samples. The ash samples modified with acid were comparatively tested with triple superphosphate fertilizer (TSP) to determine their effects on the growth and nutrition of lettuce plants. The long-term use of ash and ash-derived fertilizer materials and whether they create a negative impact on soils have been determined through a simulation study. The most effective modification on the water solubility of nutrient elements, especially P, in PMA samples is achieved through modification with H2SO4. Similarly, in the plant experiment, PMA + H2SO4 treatment is superior to TSP. In the simulation study, it has been observed that the direct application of PMA in the long term further increases the pH in calcareous and high-pH soils, and the PMA + H2SO4 application is the most suitable for maintaining soil pH stability. It is well understood that effective recycling of PMA can provide an economical and alternative source of phosphorus. Additionally, PMA serves as a significant fertilizer due to the presence of other essential plant nutrients in its composition.

将生物质发电厂产生的废灰重新用作肥料材料的重要性与日俱增。本研究系统地探讨了利用生物质发电厂产生的粪便灰生产肥料的可行性。在这项研究中,首先尝试用 HCl、H2SO4 和 HNO3 对废弃家禽粪便灰烬(PMA)进行改性,以提高其成分中植物养分的溶解度。扫描电镜和 XRD 被用于灰烬样品的分子和化学特性分析。用酸改性的草木灰样品与三过磷酸钙(TSP)进行了比较试验,以确定它们对莴苣植物生长和营养的影响。通过模拟研究确定了草木灰和草木灰衍生肥料材料的长期使用及其是否会对土壤产生负面影响。使用 H2SO4 对 PMA 样品中的营养元素(尤其是磷元素)的水溶性进行改良是最有效的方法。同样,在植物实验中,PMA + H2SO4 处理优于 TSP 处理。模拟研究发现,长期直接施用 PMA 会进一步提高石灰性土壤和高 pH 土壤的 pH 值,而施用 PMA + H2SO4 最适合保持土壤 pH 值的稳定性。众所周知,有效回收利用 PMA 可提供经济的磷替代来源。此外,PMA 还是一种重要的肥料,因为其成分中含有其他植物必需的营养元素。
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引用次数: 0
期刊
Journal of Material Cycles and Waste Management
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