{"title":"Physical and Chemical Characteristics of the Chromium and the Cerium Group Lanthanide-Based New Materials","authors":"E. V. Cherkasova, T. G. Cherkasova","doi":"10.1134/S106378502470024X","DOIUrl":null,"url":null,"abstract":"<p>Some physical and chemical characteristics of hexa(thiocyanate-N)chromate complexes of cerium lanthanides with 3-pyridine-3-carboxylic acid are studied. It was shown by IR spectroscopy that the compounds are N-thiocyanate, the organic ligand is bidentate. It was established by X-ray diffraction analysis that substances have an isle structure, crystallize acoording the same structural type, and their crystallographic parameters change regularly in accordance with the change in the radii of Ln<sup>3+</sup> ions. The compositions of the substances differ only in the content of crystallization water in the molecules. The magnetic characteristics and thermal behavior of substances in an inert atmosphere and oxidizing atmospheres are presented.</p>","PeriodicalId":784,"journal":{"name":"Technical Physics Letters","volume":"50 1","pages":"25 - 29"},"PeriodicalIF":0.8000,"publicationDate":"2024-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Technical Physics Letters","FirstCategoryId":"101","ListUrlMain":"https://link.springer.com/article/10.1134/S106378502470024X","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"PHYSICS, APPLIED","Score":null,"Total":0}
引用次数: 0
Abstract
Some physical and chemical characteristics of hexa(thiocyanate-N)chromate complexes of cerium lanthanides with 3-pyridine-3-carboxylic acid are studied. It was shown by IR spectroscopy that the compounds are N-thiocyanate, the organic ligand is bidentate. It was established by X-ray diffraction analysis that substances have an isle structure, crystallize acoording the same structural type, and their crystallographic parameters change regularly in accordance with the change in the radii of Ln3+ ions. The compositions of the substances differ only in the content of crystallization water in the molecules. The magnetic characteristics and thermal behavior of substances in an inert atmosphere and oxidizing atmospheres are presented.
期刊介绍：
Technical Physics Letters is a companion journal to Technical Physics and offers rapid publication of developments in theoretical and experimental physics with potential technological applications. Recent emphasis has included many papers on gas lasers and on lasing in semiconductors, as well as many reports on high Tc superconductivity. The excellent coverage of plasma physics seen in the parent journal, Technical Physics, is also present here with quick communication of developments in theoretical and experimental work in all fields with probable technical applications. Topics covered are basic and applied physics; plasma physics; solid state physics; physical electronics; accelerators; microwave electron devices; holography.
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