{"title":"Shaping of metal–organic framework using chitosan and triphosphate cross-linker","authors":"Aditya Irfan Witono, Xin Zheng, Yuki Saito, Shin-ichiro Noro","doi":"10.1093/chemle/upae050","DOIUrl":null,"url":null,"abstract":"<jats:title>Abstract</jats:title> The Zr metal–organic framework (MOF) UiO-66 was shaped into beads using chitosan and P3O105− as a cross-linker. The obtained UiO-66–chitosan beads showed decreases in pore size and Brunauer–Emmett–Teller (BET) surface area but enhanced N2 adsorption energy with retention of Zr-ligand connectivity. This finding will provide an important insight into the practical application of MOFs.","PeriodicalId":9862,"journal":{"name":"Chemistry Letters","volume":"20 1","pages":""},"PeriodicalIF":1.4000,"publicationDate":"2024-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry Letters","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1093/chemle/upae050","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
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Abstract The Zr metal–organic framework (MOF) UiO-66 was shaped into beads using chitosan and P3O105− as a cross-linker. The obtained UiO-66–chitosan beads showed decreases in pore size and Brunauer–Emmett–Teller (BET) surface area but enhanced N2 adsorption energy with retention of Zr-ligand connectivity. This finding will provide an important insight into the practical application of MOFs.
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