The role of graphene and molybdenum disulfide in rechargeable energy storage systems: Perspective and challenges

Energy Storage Pub Date : 2024-06-05 DOI:10.1002/est2.635
Preethi A, Dawnee S, Senthilkumar T D, Rushita Atla
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Abstract

To offset the intermittent nature, renewable energy sources must be paired with energy storage systems (ESS) to cater to the demand for clean energy solutions. The performance characteristics requirements of these ESS are application-specific, say batteries are characterized by their high energy capacity while supercapacitors offer greater power density. Currently, the research concentration in this domain is on improving the performance parameters of proven energy storage chemistries. Two-dimensional (2D) materials characterized by high specific surface area, and tunable physical and electrical properties are explored extensively to enhance ESS performance. This review comprehends the progress made by two typical 2D materials, Graphene and Molybdenum disulfide, to enhance the energy/ power capacity, and life span of a few chosen rechargeable storage chemistries, lithium-ion, lithium-sulfur batteries, supercapacitors, and flow batteries. Further the review presents the current state of ESS, the challenges identified so far which restrict their capacity and life span, and the solutions employed to date. Finally, the challenges associated with these solutions are critically analyzed to suggest future directions and research perspectives in this domain.

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石墨烯和二硫化钼在可充电储能系统中的作用:前景与挑战
为了抵消间歇性,可再生能源必须与储能系统(ESS)搭配使用,以满足对清洁能源解决方案的需求。这些 ESS 的性能特征要求因应用而异,例如电池的特点是能量容量大,而超级电容器的功率密度更大。目前,该领域的研究主要集中在改进已证实的储能化学物质的性能参数上。二维(2D)材料具有高比表面积、可调物理和电气特性等特点,为提高 ESS 性能,人们对其进行了广泛的探索。本综述介绍了石墨烯和二硫化钼这两种典型的二维材料在提高能量/功率容量、延长锂离子电池、锂硫电池、超级电容器和液流电池等几种选定的可充电存储化学材料的使用寿命方面所取得的进展。此外,报告还介绍了 ESS 的现状、迄今为止发现的限制其容量和寿命的挑战,以及迄今为止采用的解决方案。最后,对与这些解决方案相关的挑战进行了批判性分析,以提出该领域的未来发展方向和研究前景。
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