Christelle Virolle, David Evrard and Olivier Reynes
{"title":"A diazonium-functionalized silver electrode for the sensitive amperometric detection of p-nitrophenol in water over a wide range of concentrations","authors":"Christelle Virolle, David Evrard and Olivier Reynes","doi":"10.1039/D4AN00696H","DOIUrl":null,"url":null,"abstract":"<p >This work presents a novel approach for the electrochemical detection of <em>p</em>-nitrophenol (pNP) focusing on the development of a simple and efficient strategy to overcome pNP adsorption. The proposed method involves the functionalization of a silver (Ag) electrode with an electrografted, thin diazonium film. After characterization by electrochemical impedance spectroscopy (EIS) and cyclic voltammetry, the as-functionalized electrode allowed a wide linear detection range to be established in aqueous solutions, spanning from 1 to 500 μM pNP. This outcome indicates that the diazonium film effectively addresses any issues related to adsorption with good repeatability and reproducibility. Furthermore, the sensor's analytical performances were evaluated yielding a sensitivity and a limit of detection of 0.3819 μA cm<small><sup>−2</sup></small> μM<small><sup>−1</sup></small> and 600 nM, respectively. The sensor was also found to exhibit a good selectivity towards pNP and phenolic compounds and was successfully tested on a real water sample.</p>","PeriodicalId":63,"journal":{"name":"Analyst","volume":null,"pages":null},"PeriodicalIF":3.6000,"publicationDate":"2024-06-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Analyst","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/an/d4an00696h","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
引用次数: 0
Abstract
This work presents a novel approach for the electrochemical detection of p-nitrophenol (pNP) focusing on the development of a simple and efficient strategy to overcome pNP adsorption. The proposed method involves the functionalization of a silver (Ag) electrode with an electrografted, thin diazonium film. After characterization by electrochemical impedance spectroscopy (EIS) and cyclic voltammetry, the as-functionalized electrode allowed a wide linear detection range to be established in aqueous solutions, spanning from 1 to 500 μM pNP. This outcome indicates that the diazonium film effectively addresses any issues related to adsorption with good repeatability and reproducibility. Furthermore, the sensor's analytical performances were evaluated yielding a sensitivity and a limit of detection of 0.3819 μA cm−2 μM−1 and 600 nM, respectively. The sensor was also found to exhibit a good selectivity towards pNP and phenolic compounds and was successfully tested on a real water sample.