Preparation of High-performance Multicrystalline Silicon Ingot Based on Innovative Seeding Strategy for Recycled Seeds

IF 4.6 Q2 MATERIALS SCIENCE, BIOMATERIALS ACS Applied Bio Materials Pub Date : 2024-06-14 DOI:10.1007/s12633-024-03064-y
Runguang Hu, Qi Lei, Liang He, Jianmin Li, Yunfei Xu, Dongli Hu, Jinbing Zhang
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Abstract

In the preparation of high-performance multicrystalline silicon (HPM-Si) wafers, it is usually necessary to use costly polycrystalline silicon (Poly-Si) as the seed layer. In order to reduce cost and simplify process control, this paper presents an innovative strategy for the preparation of HPM-Si wafers using recycled multicrystalline silicon (mc-Si) seeds, aiming to reduce cost and simplify the production process. HPM-Si ingots were successfully prepared by using the substandard region at the ingot bottom as the seed layer combined with an intentional seed arrangement and seeding process. The results show that the Si ingots prepared from recycled seeds do not differ significantly from the conventional method in terms of yield, crystal quality and solar cell performance, while remarkably reducing the preparation cost. In particular, the height, grain morphology and defect distribution of the red zone at the bottom of the silicon brick grown by laying the bottom region of the ingot upside down as seeds are comparable to those of common HPM-Si. In addition, the efficiency of the fabricated solar cells is also comparable to that of common HPM-Si wafers, which provides a new idea for the industrialized production of low-cost HPM-Si wafers.

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基于回收种子创新播种策略制备高性能多晶硅锭
在制备高性能多晶硅(HPM-Si)晶片时,通常需要使用成本高昂的多晶硅(Poly-Si)作为种子层。为了降低成本和简化流程控制,本文提出了一种使用回收多晶硅(mc-Si)种子制备 HPM-Si 硅片的创新策略,旨在降低成本和简化生产流程。利用硅锭底部的次标准区域作为种子层,并结合有意的种子排列和播种工艺,成功制备了高纯锗硅锭。结果表明,利用回收种子制备的硅锭在产量、晶体质量和太阳能电池性能方面与传统方法没有明显差异,同时显著降低了制备成本。特别是,将硅锭底部区域倒置作为种子生长的硅砖底部红色区域的高度、晶粒形态和缺陷分布与普通 HPM-Si 相当。此外,制备的太阳能电池的效率也与普通 HPM-Si 硅片相当,这为低成本 HPM-Si 硅片的工业化生产提供了新思路。
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来源期刊
ACS Applied Bio Materials
ACS Applied Bio Materials Chemistry-Chemistry (all)
CiteScore
9.40
自引率
2.10%
发文量
464
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