{"title":"Recent Progress and Future Prospects of Metal-Organic Frameworks for Adsorption, Separation and Catalytic Removal of NOx and N2O","authors":"Ming-Wu Liu, Hao Zhang, Jing Li, Xiao-Chen Qi, Yu-Fen Wang, Jiandong Pang","doi":"10.1002/cctc.202400922","DOIUrl":null,"url":null,"abstract":"<p>Nitrogen oxides (NOx) are produced during the high-temperature combustion process of fossil fuels, which are considered as an atmospheric pollutant that can lead to significant environmental issues such as acid rain and photochemical smog. Therefore, it is essential to minimize the concentration of NO<sub>x</sub> in the atmosphere in order to protect the ecological environment upon which human beings depends. The integrated utilization of NO<sub>x</sub> removal technology results in environmentally harmless compounds, such as N<sub>2</sub> and H<sub>2</sub>O, through the processes like adsorption, separation, catalytic reduction and other methods. Metal-organic frameworks (MOFs) are seen as ideal candidates for addressing NO<sub>x</sub> pollution issues in the atmosphere due to their high specific surface area, ultrahigh porosity and unlimited modifiability. Herein, the latest research progress in MOFs and MOFs-derived materials related to NO<sub>x</sub> adsorption, separation and catalytic reduction is presented and summarized. Besides, some opportunities and problems need to be solved in this field are proposed and discussed.</p>","PeriodicalId":141,"journal":{"name":"ChemCatChem","volume":null,"pages":null},"PeriodicalIF":3.8000,"publicationDate":"2024-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemCatChem","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/cctc.202400922","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Nitrogen oxides (NOx) are produced during the high-temperature combustion process of fossil fuels, which are considered as an atmospheric pollutant that can lead to significant environmental issues such as acid rain and photochemical smog. Therefore, it is essential to minimize the concentration of NOx in the atmosphere in order to protect the ecological environment upon which human beings depends. The integrated utilization of NOx removal technology results in environmentally harmless compounds, such as N2 and H2O, through the processes like adsorption, separation, catalytic reduction and other methods. Metal-organic frameworks (MOFs) are seen as ideal candidates for addressing NOx pollution issues in the atmosphere due to their high specific surface area, ultrahigh porosity and unlimited modifiability. Herein, the latest research progress in MOFs and MOFs-derived materials related to NOx adsorption, separation and catalytic reduction is presented and summarized. Besides, some opportunities and problems need to be solved in this field are proposed and discussed.
期刊介绍:
With an impact factor of 4.495 (2018), ChemCatChem is one of the premier journals in the field of catalysis. The journal provides primary research papers and critical secondary information on heterogeneous, homogeneous and bio- and nanocatalysis. The journal is well placed to strengthen cross-communication within between these communities. Its authors and readers come from academia, the chemical industry, and government laboratories across the world. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies, and is supported by the German Catalysis Society.