Exploring Eco-Friendly Green Synthesis of Calcium Silicate and its Derivatives for Diverse Applications

IF 3.3 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Silicon Pub Date : 2024-06-11 DOI:10.1007/s12633-024-03034-4
Pooja Yadav, Sushil Patel, Gangadhar Mahar, Krishnam Raju, P. Abdul Azeem
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Abstract

Calcium oxide and silicon oxide are combined to form calcium silicate. Since calcium silicate materials offer tuneable physical, chemical, mechanical, and optical characteristics, these materials have found uses in various applications such as luminescence, batteries, bioimaging, supercapacitors, and concrete materials. In the majority of applications, high-purity calcium silicate is produced from chemical precursors such as calcium/silicate oxides or nitrites, even though this method could be expensive, environmentally harmful, and non-biocompatible. As an alternative, natural calcium and silica from biomass are usually economical and abundant, yet they contain impurities but sometimes the trace impurities influence the properties of material in positive ways. Silica can be extracted from wheat husk, rice husk, and sugarcane bagasse, which are frequently dumped in rivers, ponds, and other water bodies, contributing to ecological and health problems, likewise, calcium oxide can be extracted from eggshells, marble waste, snail shell. The trash may recycle or utilized to create marketable, value-added items with significant ecological and financial benefits rather than being dumped. The purpose of this review paper is to discuss the composition, processing, and applications of calcium silicate derivatives. The analysis shows that calcium silicate derivatives have enormous potential for using waste as a replacement of organic precursor materials.

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探索用于多种应用的硅酸钙及其衍生物的生态友好型绿色合成方法
氧化钙和氧化硅结合形成硅酸钙。由于硅酸钙材料具有可调节的物理、化学、机械和光学特性,这些材料已被广泛应用于发光、电池、生物成像、超级电容器和混凝土材料等领域。在大多数应用中,高纯度硅酸钙是由钙/硅酸盐氧化物或亚硝酸盐等化学前体生产出来的,尽管这种方法可能成本高昂、对环境有害且不具有生物相容性。作为替代方法,从生物质中提取天然钙和二氧化硅通常既经济又丰富,但它们含有杂质,但有时这些微量杂质会对材料的特性产生积极影响。硅石可以从麦壳、稻壳和甘蔗渣中提取,这些物质经常被倾倒在河流、池塘和其他水体中,造成生态和健康问题;同样,氧化钙也可以从蛋壳、大理石废料、蜗牛壳中提取。这些垃圾可以回收利用,也可以用来制造适销对路的高附加值物品,从而带来显著的生态和经济效益,而不是被随意丢弃。本综述旨在讨论硅酸钙衍生物的成分、加工和应用。分析表明,硅酸钙衍生物在利用垃圾替代有机前体材料方面潜力巨大。
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来源期刊
Silicon
Silicon CHEMISTRY, PHYSICAL-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
5.90
自引率
20.60%
发文量
685
审稿时长
>12 weeks
期刊介绍: The journal Silicon is intended to serve all those involved in studying the role of silicon as an enabling element in materials science. There are no restrictions on disciplinary boundaries provided the focus is on silicon-based materials or adds significantly to the understanding of such materials. Accordingly, such contributions are welcome in the areas of inorganic and organic chemistry, physics, biology, engineering, nanoscience, environmental science, electronics and optoelectronics, and modeling and theory. Relevant silicon-based materials include, but are not limited to, semiconductors, polymers, composites, ceramics, glasses, coatings, resins, composites, small molecules, and thin films.
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