Removal of thiophene compounds from model fuel with supported copper on active carbon, adsorption kinetics, and isotherms

Abstract

In this study, the adsorption of thiophene compounds (TCs), including thiophene (T), benzothiophene (BT), and dibenzothiophene (DBT), from model fuels was investigated using modified activated carbon (AC). The model fuel, prepared as a single-solute model at a concentration of 2000 ppm based on a mixture concentration of 3000 ppm, served as the basis for the adsorption experiments. Additionally, an examination of thiophene adsorption from commercial fuels, specifically kerosene, was conducted. Experimental data were used to calculate correlated parameters of adsorption isotherms, kinetic models, and the Fisher factor. The pseudo-second-order model demonstrated the best fit to the experimental data. Notably, the adsorbent consisting of 10% Cu⁺ supported on acid-washed activated carbon (A1CN10) exhibited the highest adsorption capacity for TCs, achieving removal percentages of 78%, 96%, and 100% for T, BT, and DBT, respectively. Various methods were employed to investigate the physicochemical properties of the adsorbents, including N₂ adsorption–desorption surface analysis (BET), scanning electron microscopy (SEM), X-ray diffraction (XRD), and energy dispersive spectroscopy (EDS). Furthermore, the regeneration of the adsorbent was studied using two techniques: agitation and ultrasound.