Bio‐inspired hierarchical bamboo‐based air filters for efficient removal of particulate matter and toxic gases

Exploration Pub Date : 2024-06-10 DOI:10.1002/exp.20240012
Qi Gao, Jian Gan, Pixiang Wang, Yuxiang Huang, Daihui Zhang, Wenji Yu
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Abstract

Air pollution is caused by the perilous accumulation of particulate matter (PM) and harmful gas molecules of different sizes. There is an urgent need to develop highly efficient air filtration systems capable of removing particles with a wide size distribution. However, the efficiency of current air filters is compromised by controlling their hierarchical pore size. Inspired by the graded filtration mechanisms in the human respiratory system, microporous ZIF‐67 is in situ synthesized on a 3D interconnected network of bamboo cellulose fibers (BCFs) to fabricate a multiscale porous filter with a comprehensive pore size distribution. The macropores between the BCFs, mesopores formed by the BCF microfibers, and micropores within the ZIF‐67 synergistically facilitate the removal of particulates of different sizes. The filtration capabilities of PM2.5 and PM0.3 could reach 99.3% and 98.6%, respectively, whereas the adsorption of formaldehyde is 88.7% within 30 min. In addition, the filter exhibits excellent antibacterial properties (99.9%), biodegradability (80.1% degradation after 14 days), thermal stability, and skin‐friendly properties (0 irritation). This study may inspire the research of using natural features of renewable resources to design high‐performance air‐filtration materials for various applications.
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基于竹子的生物启发分层空气过滤器,可高效去除颗粒物和有毒气体
空气污染是由不同大小的颗粒物(PM)和有害气体分子的危险积累造成的。目前迫切需要开发能够去除各种大小颗粒的高效空气过滤系统。然而,目前的空气过滤器在控制其分级孔径时,效率会大打折扣。受人体呼吸系统分级过滤机制的启发,在竹纤维素纤维(BCF)的三维互连网络上原位合成了微孔 ZIF-67,从而制造出具有全面孔径分布的多尺度多孔过滤器。竹纤维素纤维之间的大孔、竹纤维素纤维微纤维形成的中孔以及 ZIF-67 内的微孔协同促进了不同尺寸颗粒的去除。对 PM2.5 和 PM0.3 的过滤能力分别达到 99.3% 和 98.6%,而在 30 分钟内对甲醛的吸附率为 88.7%。此外,该过滤器还具有出色的抗菌性(99.9%)、生物降解性(14 天后降解率为 80.1%)、热稳定性和亲肤性(0 刺激)。这项研究可能会启发人们利用可再生资源的天然特性来设计各种应用领域的高性能空气过滤材料。
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