An ultrafast rechargeable hybrid potassium dual-ion capacitor based on carbon quantum dot@ultrathin carbon film cathode

Abstract

Ultrafast rechargeable hybrid potassium dual-ion capacitors (HPDICs) were designed by employing carbon quantum dot@ultrathin carbon film (CQD@CF) as the cathode material. The designed CQD@CF is self-assembled by a simple catalytic graphitization route followed by an acid leaching process. The special composite features a large adsorption interface, a remarkable anion hybrid storage capability and outstanding structure stability. The electrochemical performance of CQD@CF composite is fully tapped in a half-cell system at the operating voltage between 1.4 and 4.5 V, achieving an admirable specific discharge capacity of 128.5 mAh·g⁻¹ at 50 mA·g⁻¹, an ultra-high capacity retention ratio of 97.97% after cycling 5000 times at 1000 mA·g⁻¹ and a 96.10% high capacity retention ratio after cycling 40,000 times at 5000 mA·g⁻¹, respectively. Besides, with the support of ex situ TEM and XPS, the structural stability principle and anionic hybrid storage mechanism of CQD@CF electrode are investigated deeply. In the full-cell system, HPDICs with the CQD@CF as cathode and nano-graphite powder as anode also present a 141.5 Wh·kg⁻¹ high energy density, a 5850 W·kg⁻¹ power density and a super-long cycle stability (90.2% capacity retention ratio after cycling 30,000 times at 5000 mA·g⁻¹).

Graphical Abstract