Degradation Behavior of Zn–Cu Stents with Different Coatings in Sodium Chloride Solution

IF 2.9 2区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Acta Metallurgica Sinica-English Letters Pub Date : 2024-06-06 DOI:10.1007/s40195-024-01721-0
Xingpeng Liao, Jialuo Huang, Zhilin Liu, Jingru Guo, Dajiang Zheng, Pengbo Chen, Fuyong Cao
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Abstract

The Zn0.6Cu wires are fabricated into stents for the potential biodegradable application of nasal wound healing. The degradation behavior of Zn0.6Cu stents in 0.9 wt% NaCl at 36.5 °C is evaluated. It shows that the untreated Zn0.6Cu stent experiences severe crevice corrosion with acceleration and autocatalytic effects within the micro-cracks and ruptures at 4.67 ± 1.15 d, with the average corrosion rate of 0.28 mm y−1. Fortunately, the anodic polarization (AP) + hydrothermal (H) conversion coating, consisting of ZnCO3, Zn(OH)2 and ZnO, could inhibit the crevice corrosion significantly by reducing the cathode/anode ratio, extending the rupture time up to 16.50 ± 2.95 d, with the average corrosion rate of 0.14 mm y−1. This research indicates that the biodegradable Zn-based stent has some potential applications in nasal wound recovery area.

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不同涂层的锌铜支架在氯化钠溶液中的降解行为
将 Zn0.6Cu 金属丝制成支架,用于鼻腔伤口愈合的潜在生物降解应用。评估了 Zn0.6Cu 支架在 0.9 wt% NaCl 溶液(36.5 °C)中的降解行为。结果表明,未经处理的 Zn0.6Cu 支架经历了严重的缝隙腐蚀,在微裂缝内产生加速和自催化作用,并在 4.67 ± 1.15 d 破裂,平均腐蚀速率为 0.28 mm y-1。幸运的是,由 ZnCO3、Zn(OH)2 和 ZnO 组成的阳极极化 (AP) + 水热 (H) 转换涂层可通过降低阴阳极比显著抑制缝隙腐蚀,将断裂时间延长至 16.50 ± 2.95 d,平均腐蚀速率为 0.14 mm y-1。这项研究表明,可生物降解锌基支架在鼻腔伤口恢复领域具有一定的应用潜力。
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来源期刊
Acta Metallurgica Sinica-English Letters
Acta Metallurgica Sinica-English Letters METALLURGY & METALLURGICAL ENGINEERING-
CiteScore
6.60
自引率
14.30%
发文量
122
审稿时长
2 months
期刊介绍: This international journal presents compact reports of significant, original and timely research reflecting progress in metallurgy, materials science and engineering, including materials physics, physical metallurgy, and process metallurgy.
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