Characterization of Intentional Contaminations at the HgCdTe Passivation Interface and Their Effects on Photodiode Performance

IF 2.5 4区 工程技术 Q3 ENGINEERING, ELECTRICAL & ELECTRONIC Journal of Electronic Materials Pub Date : 2024-06-06 DOI:10.1007/s11664-024-11137-2
Steven Bel, Clément Lobre, Sarah Petit, Marc Veillerot, Giacomo Badano
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Abstract

Increasing interest in reducing the size, weight, and power consumption (SWaP) of devices motivates the development of high-operating-temperature (HOT) infrared imaging systems. HgCdTe photodiodes are in a privileged position to produce HOT detectors with background-limited infrared performance (BLIP). However, the proportion of unstable pixel responses tends to rise with increased operating temperature and degrades the detection performance. Multiple studies suggest that this issue is related to the surface states generated and affected by the manufacturing steps. In this work, native oxide and a residual halogen impurity susceptible to being introduced at the interface during passivation processes were investigated. For this purpose, surface contaminations were intentionally amplified to study their impact on the interface behavior of simplified electrical test structures. The chemical environments of the sample surface before insulator deposition were analyzed using x-ray photoelectron spectroscopy (XPS). After passivation deposition, time-of-flight secondary ion mass spectrometry (TOF-SIMS) enabled the evaluation of the contaminants’ presence levels at the interface before and after annealing. The influence of the contaminants on the interface behavior was studied using capacitance–voltage measurements on metal–insulator–semiconductor structures (C(V) MIS). Finally, photoluminescence decay (PLD) enabled the extraction of the minority charge carrier effective lifetime to determine the contaminants’ global impact on the structures. The coupling of physicochemical (XPS, TOF-SIMS) and electro-optical characterization techniques (PLD, C(V) MIS) allowed us to evaluate and discuss the effects of interfacial oxide and halogen impurities on passivation quality and subsequent device electrical behavior.

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碲化镉汞钝化界面的有意污染特征及其对光电二极管性能的影响
人们对减小器件尺寸、重量和功耗(SWaP)的兴趣日益浓厚,这推动了高温红外成像系统的发展。HgCdTe光电二极管在生产具有背景限制红外性能(BLIP)的热探测器方面处于有利地位。然而,不稳定像素响应的比例随着工作温度的升高而上升,从而降低了检测性能。多项研究表明,这一问题与制造步骤所产生和影响的表面状态有关。本文研究了钝化过程中易在界面处引入的天然氧化物和残卤杂质。为此,有意放大表面污染,以研究它们对简化电测试结构界面行为的影响。利用x射线光电子能谱(XPS)分析了绝缘体沉积前样品表面的化学环境。钝化沉积后,飞行时间二次离子质谱(TOF-SIMS)能够评估退火前后界面上污染物的存在水平。利用金属-绝缘体-半导体结构(C(V) MIS)的电容-电压测量研究了污染物对界面行为的影响。最后,通过光致发光衰减(PLD)提取少量载流子有效寿命,确定污染物对结构的整体影响。物理化学(XPS, TOF-SIMS)和电光表征技术(PLD, C(V) MIS)的耦合使我们能够评估和讨论界面氧化物和卤素杂质对钝化质量和随后器件电学行为的影响。图形抽象
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来源期刊
Journal of Electronic Materials
Journal of Electronic Materials 工程技术-材料科学:综合
CiteScore
4.10
自引率
4.80%
发文量
693
审稿时长
3.8 months
期刊介绍: The Journal of Electronic Materials (JEM) reports monthly on the science and technology of electronic materials, while examining new applications for semiconductors, magnetic alloys, dielectrics, nanoscale materials, and photonic materials. The journal welcomes articles on methods for preparing and evaluating the chemical, physical, electronic, and optical properties of these materials. Specific areas of interest are materials for state-of-the-art transistors, nanotechnology, electronic packaging, detectors, emitters, metallization, superconductivity, and energy applications. Review papers on current topics enable individuals in the field of electronics to keep abreast of activities in areas peripheral to their own. JEM also selects papers from conferences such as the Electronic Materials Conference, the U.S. Workshop on the Physics and Chemistry of II-VI Materials, and the International Conference on Thermoelectrics. It benefits both specialists and non-specialists in the electronic materials field. A journal of The Minerals, Metals & Materials Society.
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