Dielectric modulation engineering in hierarchically ordered porous Ti3C2Tx MXene/rhenium disulfide aerogel toward potential electromagnetic wave absorption and infrared stealth

IF 23.2 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Advanced Composites and Hybrid Materials Pub Date : 2024-06-13 DOI:10.1007/s42114-024-00917-3
Jia-Lin Gao, Li Chang, Ben Niu, Xin-Ci Zhang, Lin Li, Mao-Sheng Cao
{"title":"Dielectric modulation engineering in hierarchically ordered porous Ti3C2Tx MXene/rhenium disulfide aerogel toward potential electromagnetic wave absorption and infrared stealth","authors":"Jia-Lin Gao,&nbsp;Li Chang,&nbsp;Ben Niu,&nbsp;Xin-Ci Zhang,&nbsp;Lin Li,&nbsp;Mao-Sheng Cao","doi":"10.1007/s42114-024-00917-3","DOIUrl":null,"url":null,"abstract":"<div><p>Adjusting the impedance of materials by modulating their electromagnetic parameters is an effective strategy for obtaining excellent electromagnetic wave (EMW) absorption performance, but there are still challenges in developing high-performance electromagnetic wave (EMW)-absorbing materials. Herein, a dielectric modulation engineering strategy is proposed, and a lightweight 3D hierarchically ordered porous structure based on an MXene and ReS<sub>2</sub> (3D OPMRs) was fabricated through directional freeze-drying technology. The 3D nanoflower-like structure of ReS<sub>2</sub>, which acts as a dielectric regulator factor, effectively controls the dielectric loss characteristics of the composites. The optimized 3D OPMR with a hierarchically ordered porous structure and a light weight (density as low as 0.04 g cm<sup>−3</sup>) exhibited excellent EMW absorption properties with minimal reflection loss and an effective absorption bandwidth of − 66.20 dB and 4.20 GHz, respectively. The excellent EMW absorption performances originate from the dipole and interfacial polarizations, adjustable conduction loss, and multiple internal reflections. Moreover, computer simulation results validate the attenuation effect of 3D OPMR on electromagnetic energy under real application conditions. Interestingly, the unique hierarchical pore structure endows 3D OPMR with excellent thermal resistance, which expands the application of EMW-absorbing materials in infrared stealth and harsh environments.</p><h3>Graphical Abstract</h3>\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":null,"pages":null},"PeriodicalIF":23.2000,"publicationDate":"2024-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Composites and Hybrid Materials","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s42114-024-00917-3","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, COMPOSITES","Score":null,"Total":0}
引用次数: 0

Abstract

Adjusting the impedance of materials by modulating their electromagnetic parameters is an effective strategy for obtaining excellent electromagnetic wave (EMW) absorption performance, but there are still challenges in developing high-performance electromagnetic wave (EMW)-absorbing materials. Herein, a dielectric modulation engineering strategy is proposed, and a lightweight 3D hierarchically ordered porous structure based on an MXene and ReS2 (3D OPMRs) was fabricated through directional freeze-drying technology. The 3D nanoflower-like structure of ReS2, which acts as a dielectric regulator factor, effectively controls the dielectric loss characteristics of the composites. The optimized 3D OPMR with a hierarchically ordered porous structure and a light weight (density as low as 0.04 g cm−3) exhibited excellent EMW absorption properties with minimal reflection loss and an effective absorption bandwidth of − 66.20 dB and 4.20 GHz, respectively. The excellent EMW absorption performances originate from the dipole and interfacial polarizations, adjustable conduction loss, and multiple internal reflections. Moreover, computer simulation results validate the attenuation effect of 3D OPMR on electromagnetic energy under real application conditions. Interestingly, the unique hierarchical pore structure endows 3D OPMR with excellent thermal resistance, which expands the application of EMW-absorbing materials in infrared stealth and harsh environments.

Graphical Abstract

Abstract Image

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
分层有序多孔 Ti3C2Tx MXene/ 二硫化钼铼气凝胶中的介电调制工程,实现潜在的电磁波吸收和红外隐身功能
通过调制材料的电磁参数来调整材料的阻抗是获得优异电磁波吸收性能的有效策略,但高性能电磁波吸收材料的开发仍面临挑战。本文提出了一种介电调制工程策略,并通过定向冷冻干燥技术制备了一种基于 MXene 和 ReS2 的轻质三维分层有序多孔结构(三维 OPMRs)。ReS2 的三维纳米花状结构可作为介电调节因子,有效控制复合材料的介电损耗特性。优化后的三维 OPMR 具有分层有序的多孔结构,重量轻(密度低至 0.04 g cm-3),具有极佳的电磁波吸收特性,反射损耗极小,有效吸收带宽分别为 - 66.20 dB 和 4.20 GHz。优异的电磁波吸收性能源于偶极和界面极化、可调节的传导损耗和多重内部反射。此外,计算机模拟结果验证了三维 OPMR 在实际应用条件下对电磁能量的衰减效果。有趣的是,独特的分层孔隙结构赋予了三维 OPMR 优异的耐热性,从而拓展了电磁波吸收材料在红外隐身和恶劣环境中的应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
CiteScore
26.00
自引率
21.40%
发文量
185
期刊介绍: Advanced Composites and Hybrid Materials is a leading international journal that promotes interdisciplinary collaboration among materials scientists, engineers, chemists, biologists, and physicists working on composites, including nanocomposites. Our aim is to facilitate rapid scientific communication in this field. The journal publishes high-quality research on various aspects of composite materials, including materials design, surface and interface science/engineering, manufacturing, structure control, property design, device fabrication, and other applications. We also welcome simulation and modeling studies that are relevant to composites. Additionally, papers focusing on the relationship between fillers and the matrix are of particular interest. Our scope includes polymer, metal, and ceramic matrices, with a special emphasis on reviews and meta-analyses related to materials selection. We cover a wide range of topics, including transport properties, strategies for controlling interfaces and composition distribution, bottom-up assembly of nanocomposites, highly porous and high-density composites, electronic structure design, materials synergisms, and thermoelectric materials. Advanced Composites and Hybrid Materials follows a rigorous single-blind peer-review process to ensure the quality and integrity of the published work.
期刊最新文献
Effect of surface grafting on the oil–water mixture passing through a nanoslit: a molecular dynamics simulation study In-situ fabrication of Ni2⁺/Zn2⁺-polydopamine complex derived FeCo@C/Ni@C cubic nanocages towards enhanced electromagnetic performance Computational analysis of the interfacial debonding in polymer composites: research progress and challenges High transmittance, high haze, and UV-harvesting CNNs@CNF/PVA composite film for light management Enhancing flame retardancy of flexible polyurethane foams through one-step coassembled nanocoatings
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1